Search Results - "Luigi Cavallo"
-
1
Efficient and simultaneous capture of iodine and methyl iodide achieved by a covalent organic framework
Published in Nature communications (24-05-2022)“…Radioactive molecular iodine (I 2 ) and organic iodides, mainly methyl iodide (CH 3 I), coexist in the off-gas stream of nuclear power plants at low…”
Get full text
Journal Article -
2
Towards the online computer-aided design of catalytic pockets
Published in Nature chemistry (01-10-2019)“…The engineering of catalysts with desirable properties can be accelerated by computer-aided design. To achieve this aim, features of molecular catalysts can be…”
Get full text
Journal Article -
3
Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes
Published in Angewandte Chemie International Edition (20-05-2019)“…A magnesium‐catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal…”
Get full text
Journal Article -
4
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO2 to CO
Published in ACS catalysis (06-05-2016)“…We report a selective and stable electrocatalyst utilizing non-noble metals consisting of Cu and Sn for the efficient and selective reduction of CO2 to CO over…”
Get full text
Journal Article -
5
Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids
Published in Nature materials (01-12-2020)“…The combination of well-defined molecular cavities and chemical functionality makes crystalline porous solids attractive for a great number of technological…”
Get full text
Journal Article -
6
Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
Published in Nature communications (29-04-2019)“…Transition-metal-catalyzed cross-couplings have been extensively used in the pharmaceutical and agrochemical industries for the construction of diverse C–C…”
Get full text
Journal Article -
7
Selectivity descriptors for the direct hydrogenation of CO2 to hydrocarbons during zeolite-mediated bifunctional catalysis
Published in Nature communications (08-10-2021)“…Cascade processes are gaining momentum in heterogeneous catalysis. The combination of several catalytic solids within one reactor has shown great promise for…”
Get full text
Journal Article -
8
The 3F (Fat, Flap, and Flash) Technique For Skull Base Reconstruction After Endoscopic Endonasal Suprasellar Approach
Published in World neurosurgery (01-06-2019)“…Endoscopic endonasal surgery is a rapidly evolving field that offers the possibility of treating a wide variety of skull base lesions. Reconstruction of the…”
Get full text
Journal Article -
9
A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO2 to CO
Published in Angewandte Chemie International Edition (09-02-2015)“…The challenge in the electrochemical reduction of aqueous carbon dioxide is in designing a highly selective, energy‐efficient, and non‐precious‐metal…”
Get full text
Journal Article -
10
Understanding the M (NHC) (NHC = N-heterocyclic carbene) bond
Published in Coordination chemistry reviews (01-03-2009)“…N-heterocyclic carbenes (NHC) is a well established class of new ligands in organometallic chemistry. Their use as ligands in many reactions catalyzed by…”
Get full text
Journal Article -
11
The Comparison between Single Atom Catalysis and Surface Organometallic Catalysis
Published in Chemical reviews (22-01-2020)“…Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a single atom on a surface is able to carry out various catalytic…”
Get full text
Journal Article -
12
Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer
Published in Nature communications (18-05-2022)“…Various methods that use a photocatalyst for electron transfer between an organic substrate and a transition metal catalyst have been established. While…”
Get full text
Journal Article -
13
Hydrogenation of CO2‐Derived Carbonates and Polycarbonates to Methanol and Diols by Metal–Ligand Cooperative Manganese Catalysis
Published in Angewandte Chemie International Edition (08-10-2018)“…The first base‐metal‐catalysed hydrogenation of CO2‐derived carbonates to alcohols is presented. The reaction proceeds under mild conditions in the presence of…”
Get full text
Journal Article -
14
Structure and phase regulation in MoxC (α-MoC1-x/β-Mo2C) to enhance hydrogen evolution
Published in Applied catalysis. B, Environmental (15-06-2019)“…[Display omitted] •Monodisperse inverse opal-like MoxC nanospheres were synthesized.•The structure and phase of MoxC can be controlled by changing the amount…”
Get full text
Journal Article -
15
COCOMAPS: a web application to analyze and visualize contacts at the interface of biomolecular complexes
Published in Bioinformatics (15-10-2011)“…Herein we present COCOMAPS, a novel tool for analyzing, visualizing and comparing the interface in protein-protein and protein-nucleic acids complexes…”
Get full text
Journal Article -
16
Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)–C(sp3) Cross-Couplings
Published in Journal of the American Chemical Society (14-03-2018)“…A ligand-controlled and site-selective nickel catalyzed Suzuki–Miyaura cross-coupling reaction with aromatic esters and alkyl organoboron reagents as coupling…”
Get full text
Journal Article -
17
Oxidative Addition to Palladium(0) Made Easy through Photoexcited‐State Metal Catalysis: Experiment and Computation
Published in Angewandte Chemie International Edition (11-03-2019)“…Visible‐light induced, palladium catalyzed alkylations of α,β‐unsaturated acids with unactivated alkyl bromides are described. A variety of primary, secondary,…”
Get full text
Journal Article -
18
Nickel-catalyzed C-N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling
Published in Chemical science (Cambridge) (2019)“…Nickel-catalyzed reductive cross coupling of activated primary amines with aryl halides under mild reaction conditions has been achieved for the first time…”
Get full text
Journal Article -
19
Endoscopic Endonasal Transsphenoidal Surgery: History and Evolution
Published in World neurosurgery (01-07-2019)“…In previous decades, extensive and disfiguring transfacial and/or transcranial approaches were used to reach the sellar and parasellar areas. However, these…”
Get full text
Journal Article -
20
Toward a Unified Model Explaining Heterogeneous Ziegler–Natta Catalysis
Published in ACS catalysis (04-09-2015)“…We propose a model for MgCl2-supported Ziegler–Natta catalysts, which is capable to reconcile the discrepancies emerging in the last 20 years, in which…”
Get full text
Journal Article