Nanostructured and nanoporous LiFePO sub(4) and LiNi sub(0.5)Mn sub(1.5)O sub(4- delta ) as cathode materials for lithium-ion batteries

Recent developments in the synthesis of nanostructured cathode materials are reviewed for the two prominent compounds LiFePO sub(4) and LiNi sub(0.5)Mn sub(1.5)O sub(4), and own results on LiFePO sub(4) and LiNi sub(0.5)Mn sub(1.5)O sub(4) with different microstructure are presented. The synthesis o...

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Published in:Progress in solid state chemistry Vol. 42; no. 4; pp. 218 - 241
Main Authors: Kraas, Sebastian, Vijn, Annalena, Falk, Mareike, Ufer, Boris, Luersen, Bjoern, Janek, Juergen, Froba, Michael
Format: Journal Article
Language:English
Published: 01-12-2014
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Summary:Recent developments in the synthesis of nanostructured cathode materials are reviewed for the two prominent compounds LiFePO sub(4) and LiNi sub(0.5)Mn sub(1.5)O sub(4), and own results on LiFePO sub(4) and LiNi sub(0.5)Mn sub(1.5)O sub(4) with different microstructure are presented. The synthesis of LiFePO sub(4) composites with porous carbons and the scale up of their synthesis is reported, as well as of nanoporous materials. In the case of LiNi sub(0.5)Mn sub(1.5)O sub(4) the formation of deteriorating cathode surface films is studied with thin film electrodes and ToF-SIMS depth profiling.
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ISSN:0079-6786
DOI:10.1016/j.progsolidstchem.2014.04.014