Search Results - "Luca Gonsalvi"

Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications by Guerriero, Antonella, Peruzzini, Maurizio, Gonsalvi, Luca

“…[Display omitted] •Recent modifications of PTA (1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) are reviewed.•Reactions of PTA and analogues with transition…”
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P4 Activation by Late-Transition Metal Complexes by Caporali, Maria, Gonsalvi, Luca, Rossin, Andrea, Peruzzini, Maurizio

“…The coordination chemistry of white phosphorus using late-transition metal complexes is examined. Revived interest in these reactions is due to a need for new…”
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Homogeneous Catalysis and Mechanisms in Water and Biphasic Media by Luca Gonsalvi

“…After its discovery in the early 1980s and successful application on an industrial scale (Ruhrchemie/Rhone-Poulenc process) [...]…”
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Iron(II) Complexes of the Linear rac-Tetraphos‑1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation by Bertini, Federica, Mellone, Irene, Ienco, Andrea, Peruzzini, Maurizio, Gonsalvi, Luca

“…The linear tetraphosphine 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane (tetraphos-1, P4) was used as its rac and meso isomers for the synthesis of both…”
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Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold by Mellone, Irene, Gorgas, Nikolaus, Bertini, Federica, Peruzzini, Maurizio, Kirchner, Karl, Gonsalvi, Luca

“…Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous,…”
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Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex by Kostera, Sylwia, Weber, Stefan, Peruzzini, Maurizio, Veiros, Luis F, Kirchner, Karl, Gonsalvi, Luca

“…The catalytic reduction of carbon dioxide is a process of growing interest for the use of this simple and abundant molecule as a renewable building block in…”
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Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications by Bravo, Jorge, Bolaño, Sandra, Gonsalvi, Luca, Peruzzini, Maurizio

“…This review paper covers the recent developments (2004–2009) on the tailored synthetic modifications and related coordination chemistry of the water-soluble…”
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Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands by Bertini, Federica, Gorgas, Nikolaus, Stöger, Berthold, Peruzzini, Maurizio, Veiros, Luis F, Kirchner, Karl, Gonsalvi, Luca

“…Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were found to promote the catalytic hydrogenation…”
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Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions by Bertini, Federica, Glatz, Mathias, Stöger, Berthold, Peruzzini, Maurizio, Veiros, Luis F, Kirchner, Karl, Gonsalvi, Luca

“…Well-defined Mn­(I) hydrido carbonyl PNP pincer-type complexes were tested as efficient and selective nonprecious transition metal catalysts for the reduction…”
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Novel Synthetic Pathways for Bis(acyl)phosphine Oxide Photoinitiators by Gonsalvi, Luca, Peruzzini, Maurizio

“…Photoactive: A cheap, safe, and widely functional‐group‐tolerant synthetic protocol to an important class of photoinitiators, bis(acyl)phosphine oxides…”
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Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives by Sylwia Kostera, Maurizio Peruzzini, Luca Gonsalvi

“…The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and…”
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New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent by Guerriero, Antonella, Oberhauser, Werner, Riedel, Tina, Peruzzini, Maurizio, Dyson, Paul J, Gonsalvi, Luca

“…Ruthenium­(II) arene complexes of 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]­tridecane (CAP) were obtained. Cytotoxicity studies against cancer cell lines reveal…”
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A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process by Jumde, Varsha R., Gonsalvi, Luca, Guerriero, Antonella, Peruzzini, Maurizio, Taddei, Maurizio

“…The alkylation of arylamines using stoichiometric amounts of aliphatic and benzylic alcohols in the presence of tBuOK was carried out at 55 °C using a low…”
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Coordination chemistry and functionalization of white phosphorus via transition metal complexes by Peruzzini, Maurizio, Gonsalvi, Luca, Romerosa, Antonio

“…The chemistry of phosphorus is nowadays rivaling that of carbon in terms of complexity and diversity. This tutorial review highlights the state-of-the-art in…”
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Ruthenium(II)-Arene Complexes of the Water-Soluble Ligand CAP as Catalysts for Homogeneous Transfer Hydrogenations in Aqueous Phase by Antonella Guerriero, Maurizio Peruzzini, Luca Gonsalvi

“…The neutral Ru(II) complex κP-[RuCl2(η6-p-cymene)(CAP)] (1), and the two ionic complexes κP-[RuCl(η6-p-cymene)(MeCN)(CAP)]PF6 (2) and…”
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Synthesis and Characterization of Terminal [Re(XCO)(CO)2(triphos)] (X=N, P): Isocyanate versus Phosphaethynolate Complexes by Alidori, Simone, Heift, Dominikus, Santiso-Quinones, Gustavo, Benkő, Zoltán, Grützmacher, Hansjörg, Caporali, Maria, Gonsalvi, Luca, Rossin, Andrea, Peruzzini, Maurizio

“…The terminal rhenium(I) phosphaethynolate complex [Re(PCO)(CO)2(triphos)] has been prepared in a salt metathesis reaction from Na(OCP) and…”
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Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry” by Kotohiro Nomura, Raffaella Mancuso, Zhengguo Cai, Samuel Dagorne, Moris S. Eisen, Luca Gonsalvi, Martin Kotora, Bun Yeoul Lee, Shaofeng Liu, Luísa Margarida Martins, Takeshi Ohkuma, Armando Pombeiro, Fabio Ragaini, Carl Redshaw, Marc Visseaux, Zongquan Wu, Hiroto Yoshida, Masamichi Ogasawara

“…Herein, I would like to provide an overview of this Special Issue, published in the Organic and Polymer Chemistry Section of Catalysis, comprising…”
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New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation by Mellone, Irene, Bertini, Federica, Gonsalvi, Luca, Guerriero, Antonella, Peruzzini, Maurizio

“…Recent developments in the coordination chemistry and applications of Ru-triphos [triphos = 1,1,1-tris-(diphenylphosphinomethyl)ethane] systems are reviewed,…”
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The Bimetallic Activation of White Phosphorus by trans-[RhCl(CO)(dppm)]2 Results in a Tetrahedro-Rh2P2 Moiety by Caporali, Maria, Gonsalvi, Luca, Mirabello, Vincenzo, Ienco, Andrea, Manca, Gabriele, Zanobini, Fabrizio, Peruzzini, Maurizio

“…The reaction of trans‐[RhCl(CO)(dppm)]2 with P4 carried out at room temperature showed that bimetallic cooperation resulted in the cleavage of P4, giving a…”
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Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties? by Servin, Paul, Laurent, Régis, Dib, Hanna, Gonsalvi, Luca, Peruzzini, Maurizio, Majoral, Jean-Pierre, Caminade, Anne-Marie

“…We report the synthesis of a dense dendrimer ended by the PTA ligand (1,3,5-triaza-7-phosphaadamantane), and the use of the corresponding Rh and Ru complexes…”
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