Search Results - "Loye, Hans‐Conrad"
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Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides
Published in Angewandte Chemie (International ed.) (16-04-2012)“…This Review highlights the application of high‐temperature solutions for exploratory crystal growth and materials discovery of novel complex oxides. It…”
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Covalency in Actinide Compounds
Published in Chemistry : a European journal (01-04-2021)“…Covalency in actinides has emerged as a resounding research topic on account of the technological importance in separating minor actinides from lanthanides for…”
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Supramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations
Published in Journal of the American Chemical Society (13-05-2020)“…Superatoms are nanometer-sized molecules or particles that form ordered lattices, mimicking their atomic counterparts. Hierarchical assembly of superatoms…”
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Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations
Published in Crystal growth & design (02-02-2022)“…Single crystals of four new uranyl titanate silicates were grown from mixed halide fluxes. Cs6(UO2)2Ti3Si5O21 (1) crystallizes in the Cs6(UO2)2Ge8O21 structure…”
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f‐block MOFs: A Pathway to Heterometallic Transuranics
Published in Angewandte Chemie International Edition (26-01-2023)“…A novel series of heterometallic f‐block‐frameworks including the first examples of transuranic heterometallic 238U/239Pu‐metal–organic frameworks (MOFs) and a…”
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Polymer Composite and Nanocomposite Dielectric Materials for Pulse Power Energy Storage
Published in Materials (29-10-2009)“…This review summarizes the current state of polymer composites used as dielectric materials for energy storage. The particular focus is on materials: polymers…”
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Synthesis of Mixed‐Valent Lanthanide Sulfide Nanoparticles
Published in Angewandte Chemie International Edition (18-10-2021)“…In targeting reduced valent lanthanide chalcogenides, we report the first nanoparticle synthesis of the mixed‐valent ferromagnets Eu3S4 and EuSm2S4. Using…”
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Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates
Published in Inorganic chemistry (04-09-2018)“…Six new uranium thiophosphates, Cs5Na6[U(PS4)4](PS4) (1), Rb5Na3[U(PS4)4] (2), CsNa[U(PS4)2] (3), Cs1.67Na0.52I0.19[U(PS4)2] (4),…”
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NaGaS2: An Elusive Layered Compound with Dynamic Water Absorption and Wide‐Ranging Ion‐Exchange Properties
Published in Angewandte Chemie (International ed.) (26-06-2020)“…Most ternary sulfides belonging to the MGaS2 structure‐type have been known for many years and are well‐characterized. Surprisingly, there have been no reports…”
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Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards
Published in Journal of solid state chemistry (01-01-2015)“…An increased focus on magnetic measurements of oriented single crystals, thin films, and magnetically dilute systems has led to a demand for the measurement of…”
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Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method
Published in Inorganic chemistry (15-05-2023)“…Nine new rare earth magnesium-containing thiosilicates of the formula RE3Mg0.5SiS7 (Ln = Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er) were synthesized in an alkali…”
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Synthesis, structure, and scintillation of Rb4Ta2Si8O23
Published in Solid state sciences (01-05-2022)“…A new tantalum silicate, Rb4Ta2Si8O23, was synthesized as high-quality single crystals by the high temperature flux growth method. Rb4Ta2Si8O23 was found to…”
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Structure and stability of alkali gallates structurally reminiscent of hollandite
Published in Journal of the American Ceramic Society (01-11-2020)“…Single crystals of CsGa7O11, RbGa7O11, and RbGa4In5O14 were grown from alkali halide melts and their structures were characterized by single crystal and powder…”
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Composition Based Oxidation State Prediction of Materials Using Deep Learning Language Models
Published in Advanced science (01-10-2023)“…Oxidation states (OS) are the charges on atoms due to electrons gained or lost upon applying an ionic approximation to their bonds. As a fundamental property,…”
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DFT-guided flux synthesis of a family of layered titanates crystallizing in the lepidocrocite structure type
Published in Solid state sciences (01-05-2023)“…K0.72Fe0.72Ti1.28O4, a layered mixed-metal oxide belonging to the lepidocrocite structure type, was grown out of a molten KCl-KF mixture at 800 °C. The…”
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New Rubidium-Containing Mixed-Metal Titanium Hollandites
Published in Crystal growth & design (01-04-2020)“…A family of rubidium-containing mixed-metal titanates, Rb x M y Ti8‑y O16 (M = Mg, Mn, Fe, Ni, and Cu) was prepared as high-quality single crystals employing a…”
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Flux Crystal Growth of the Extended Structure Pu(V) Borate Na2(PuO2)(BO3)
Published in Journal of the American Chemical Society (10-05-2023)“…As part of our exploration of plutonium-containing materials as potential nuclear waste forms, we report the first extended structure Pu(V) material and the…”
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3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials
Published in Journal of the American Chemical Society (06-03-2019)“…Uranium(IV) 5f2 magnetism is dominated by a transition from a triplet to a singlet ground state at low temperatures. For the first time, we achieved magnetic…”
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Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks
Published in Journal of the American Chemical Society (22-11-2017)“…Growing necessity for efficient nuclear waste management is a driving force for development of alternative architectures toward fundamental understanding of…”
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Investigation of Metastable Low Dimensional Halometallates
Published in Molecules (Basel, Switzerland) (03-01-2022)“…The solvothermal synthesis, structure determination and optical characterization of five new metastable halometallate compounds, [1,10-phenH][Pb I ] ( ),…”
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