Search Results - "Lokare, Kapil S."
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Synthesis, Properties, and Structure of Tethered Molybdenum Alkylidenes
Published in Organometallics (13-10-2008)“…A new class of molybdenum alkylidenes has been prepared where the alkylidene is tethered to an imido ancillary ligand. The amine required for the synthesis is…”
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Acidity of Al–O(H)–Al Sites in Molecular Aluminosilicate Models Enables Alcohol Dehydration Reactions
Published in Journal of physical chemistry. C (19-08-2021)“…Molecular aluminosilicate models having a cyclic trimeric [Al(OH)]3 core unit have recently been shown to catalyze olefin isomerization via acid catalysis…”
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Carbonyl Olefination Using Readily Prepared Tungsten Metallacycles
Published in Inorganic chemistry (01-12-2008)“…Treating the bis(imido) W(NAr)2Cl2(DME) with 2 equiv of cyclooctyne in pentane results in precipitation of a yellow complex containing a 6-membered…”
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Synthesis of osmium and ruthenium complexes bearing dimethyl (S,S)-2,2′-(pyridine-2,6-diyl)-bis-(4,5-dihydrooxazol-4-carboxylate) ligand and application to catalytic H/D exchange
Published in Journal of molecular catalysis. A, Chemical (01-04-2011)“…Using tridentate, neutral PyBox ligands, several new osmium and ruthenium complexes [M(PyBox)Cl 2(C 2H 4), where M = Ru, Os] have been prepared, all thermally…”
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Group-6 Imido Activation by a Ring-Strained Alkyne
Published in Organometallics (08-11-2004)“…Treatment of M(NAr)2(Cl)2(DME), where Ar = 2,6-diisopropylphenyl, with cyclooctyne results in the formation of M(C8H12C8H12NAr)(Cl)2(NAr), where M = Mo (1)…”
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A readily-prepared and efficient solid-supported scavenger for molybdenum alkoxides and a structurally characterized model complex
Published in Journal of organometallic chemistry (15-01-2009)“…The sequential addition of H 2NBu, 2-hydroxy-5-(chloromethyl)benzaldehyde, and p-toluidine to Merrifield’s resin provides a scavenger for molybdenum metathesis…”
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