Search Results - "López Ortiz, Fernando"

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  1. 1

    Crystal, Solution, and Computational Study of the Structure of Ortho‐Lithium N,N‐Diisopropyl‐P,P‐Diphenylphosphinothioic Amide by Belmonte‐Sánchez, Eva, García‐López, Jesús, Navarro, Yolanda, Iglesias, María José, Fernández, Ignacio, LópezOrtiz, Fernando

    Published in Chemistry : a European journal (20-03-2024)
    “…The first crystal structure of an ortho‐lithium phosphinothioic amide complexed with tetramethylethylenediamine 12 is reported. The complex consists of a…”
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    Domino Reactions with Dicyanoalkenes and Fluorinated Conjugated Sulfinyl Imines. A Convenient Strategy for the Generation of Structural Diversity by Gaviña, Daniel, Escolano, Marcos, Sotorríos, Lía, Gómez‐Bengoa, Enrique, LópezOrtiz, Fernando, Sánchez‐Roselló, María, Pozo, Carlos

    Published in Advanced synthesis & catalysis (20-02-2024)
    “…Dicyanoalkenes are versatile reagents in organic synthesis and they have been extensively used in a wide variety of organic transformations. However, their…”
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    Immobilized Gold Nanoparticles Prepared from Gold(III)-Containing Ionic Liquids on Silica: Application to the Sustainable Synthesis of Propargylamines by Soengas, Raquel, Navarro, Yolanda, Iglesias, María José, López-Ortiz, Fernando

    Published in Molecules (Basel, Switzerland) (14-11-2018)
    “…A cycloaurated phosphinothioic amide gold(III) complex was supported on amorphous silica with the aid of an imidazolium ionic liquid (IL) physisorbed in the…”
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    π-Insertion Reactions of Benzynes into P=N and P=S Double Bonds by Lopez-Leonardo, Carmen, Raja, Rosalia, López-Ortiz, Fernando, Ángel del Águila-Sánchez, Miguel, Alajarin, Mateo

    Published in European journal of organic chemistry (01-02-2014)
    “…The π‐insertion reactions of in situ generated benzynes into the P=N bonds of N‐benzyl and N‐aryl iminophosphoranes and the P=S bonds of phosphane sulfides…”
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    Enantioselective Desymmetrization of Diphenylphosphinamides via (−)-Sparteine-Mediated Ortho-Lithiation. Synthesis of P-Chiral Ligands by Popovici, Cristinel, Oña-Burgos, Pascual, Fernández, Ignacio, Roces, Laura, García-Granda, Santiago, Iglesias, María José, Ortiz, Fernando López

    Published in Organic letters (05-02-2010)
    “…Asymmetric ortho-lithiation of N-dialkyl-P,P-diphenylphosphinamides using [n-BuLi·(−)-sparteine] is described as an efficient method for the synthesis of…”
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    Solution and Computed Structure of o-Lithium N,N-Diisopropyl-P,P-diphenylphosphinic Amide. Unprecedented Li−O−Li−O Self-Assembly of an Aryllithium by Fernández, Ignacio, Oña-Burgos, Pascual, Oliva, Josep M, Ortiz, Fernando López

    Published in Journal of the American Chemical Society (14-04-2010)
    “…The structural characterization of an ortho-lithiated diphenylphosphinic amide is described for the first time. Multinuclear magnetic resonance (1H, 7Li, 13C,…”
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    Asymmetric Deprotonation−Substitution of N-Pop-benzylamines Using [RLi/(−)-Sparteine]. Enantioselective Sequential Reactions and Synthesis of N-Heterocycles by Oña-Burgos, Pascual, Fernández, Ignacio, Roces, Laura, Torre-Fernández, Laura, García-Granda, Santiago, López-Ortiz, Fernando

    Published in Organic letters (07-08-2008)
    “…Pop-directed asymmetric deprotonation of benzylic amines using [n-BuLi/(−)-sparteine] provides an efficient method for the synthesis of chiral NCα and NCα,α′…”
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  10. 10

    Deuterium-Labeling and NMR Study of the Dearomatization of N-Alkyl-N-benzyldiphenylphosphinamides through Anionic Cyclization:  Ortho and Benzylic Lithiation Directed by Complex-Induced Proximity Effects by FERNANDEZ, Ignacio, GONZALEZ, Javier, LOPEZ-ORTIZ, Fernando

    Published in Journal of the American Chemical Society (06-10-2004)
    “…The mechanism of the anionic cyclization dearomatizing reaction of N-benzyl-N-methyldiphenylphosphinamide (1) upon treatment with s-BuLi in tetrahydrofuran…”
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  11. 11

    Dearomatizing Anionic Cyclization of Phosphonamides. A Route to Phosphonic Acid Derivatives with Antitumor Properties by Ruiz-Gómez, Gloria, Francesch, Andrés, José Iglesias, María, López-Ortiz, Fernando, Cuevas, Carmen, Serrano-Ruiz, Manuel

    Published in Organic letters (18-09-2008)
    “…Deprotonation of bis(N-benzyl-N-methyl)-P-arylphosphonic diamides with s-BuLi in THF at −90 °C takes place selectively at the benzylic position. The anions…”
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  12. 12

    Nucleophilic Dearomatizing (DNAr) Reactions of Aromatic C,H-Systems. A Mature Paradigm in Organic Synthesis by López Ortiz, Fernando, Iglesias, María José, Fernández, Ignacio, Andújar Sánchez, Carmen M, Ruiz Gómez, Gloria

    Published in Chemical reviews (01-05-2007)
    “…A review of nucleophilic dearomatizing reactions of aromatic C,H-systems is presented. The use of aromatic rings as a particular type of Michael acceptor for…”
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    Mechanism of Anionic Dearomatizing Reactions of Diphenylphosphinamide Derivatives: A Theoretical and Experimental Study by Ramallal, Antonio Morán, Fernández, Ignacio, López Ortiz, Fernando, González, Javier

    Published in Chemistry : a European journal (06-05-2005)
    “…The mechanism of the anionic dearomatisation of phosphinamide derivatives has been investigated both theoretically and experimentally. The potential‐energy…”
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    Differential response to environmental and nutritional factors of high-quality tomato varieties by Iglesias, María José, García-López, Jesús, Collados-Luján, Juan Fernando, López-Ortiz, Fernando, Díaz, Manuel, Toresano, Fernando, Camacho, Francisco

    Published in Food chemistry (01-06-2015)
    “…•Harvest day affects tomato quality more than increasing EC and/or silicon addition.•Taste index calculated through NMR increases from December to…”
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  17. 17

    Use of NMR for the Analysis and Quantification of the Sugar Composition in Fresh and Store-Bought Fruit Juices by Navarro, Yolanda, Soengas, Raquel, Iglesias, María José, Ortiz, Fernando López

    Published in Journal of chemical education (10-03-2020)
    “…NMR spectroscopy is traditionally taught to students during Organic Chemistry as a tool used for the determination of structures after synthesis. However,…”
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    A C ∧ S-Cyclometallated Gold(III) Complex as a Novel Antibacterial Candidate Against Drug-Resistant Bacteria by Ratia, Carlos, Cepas, Virginio, Soengas, Raquel, Navarro, Yolanda, Velasco-de Andrés, María, Iglesias, María José, Lozano, Francisco, López-Ortiz, Fernando, Soto, Sara M

    Published in Frontiers in microbiology (03-03-2022)
    “…The worldwide emergence and spread of infections caused by multidrug-resistant bacteria endangers the efficacy of current antibiotics in the clinical setting…”
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    Chemotaxonomic Profiling Through NMR1 by Iglesias, María José, Soengas, Raquel, Martins, Clara B., Correia, Maria João, Ferreira, Joana D., Santos, Lilia M. A., Ortiz, Fernando López, Li, Y.

    Published in Journal of phycology (01-04-2020)
    “…A metabolite screening of cyanobacteria was performed by nuclear magnetic resonance (NMR) analysis of the soluble material obtained through sequential…”
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