Search Results - "Llinares, José M."
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Anion coordination chemistry in aqueous solution of polyammonium receptors
Published in Coordination chemistry reviews (01-12-2006)“…The behavior of polyamines as receptors of selected families of anions in water is explored. First metallocyanide interaction with saturated polyammonium hosts…”
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Coordination Chemistry of Cu2+ Complexes of Small N‑Alkylated Tetra-azacyclophanes with SOD Activity
Published in Inorganic chemistry (04-09-2018)“…A new tetraaza-pyridinophane macrocycle (L1) N-alkylated with two isopropyl and one methyl groups symmetrically disposed has been prepared and its behavior…”
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3
Identification of Aryl Polyamines Derivatives as Anti- Trypanosoma cruzi Agents Targeting Iron Superoxide Dismutase
Published in Pharmaceutics (31-12-2022)“…Chagas disease (CD) is a tropical and potentially fatal infection caused by . Although CD was limited to Latin America as a silent disease, CD has become…”
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4
Anion Detection by Fluorescent Zn(II) Complexes of Functionalized Polyamine Ligands
Published in Inorganic chemistry (21-07-2008)“…The Zn2+ coordination chemistry and luminescent behavior of two ligands constituted by an open 1,4,7-triazaheptane chain functionalized at both ends with…”
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Stabilization of Supramolecular Networks of Polyiodides with Protonated Small Tetra-azacyclophanes
Published in Inorganics (01-04-2019)“…Polyiodide chemistry is among the first historically reported examples of supramolecular forces at work. To date, owing to the increasingly recognized role of…”
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The size of the aryl linker between two polyaza-cyclophane moieties controls the binding selectivity to ds-RNA vs. ds-DNA
Published in Organic & biomolecular chemistry (07-04-2013)“…Aryl-linked (pyridine- vs. phenanthroline-) bis-polyaza pyridinophane scorpiands PYPOD and PHENPOD strongly bind to the double stranded DNA and RNA, whereby…”
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Multiple Hydrogen Bond Stabilization of a Sandwich Complex of Sulfate between Two Macrocyclic Tetraamides
Published in Inorganic chemistry (18-06-2001)Get full text
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Nitrate Encapsulation within the Cavity of Polyazapyridinophane. Considerations on Nitrate−Pyridine Interactions
Published in Crystal growth & design (04-08-2010)“…Interaction of nitrate anions with a cyclophane (L) containing two pyridine units connected to two diethylenetriamine bridges through methylene positions is…”
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Elite New Anion Ligands: Polythioamide Macrocycles
Published in Inorganic chemistry (25-08-2003)“…Prototypes for a new class of polythioamide-based macrocycles have been synthesized and anion-binding capabilities assessed. Results indicate higher anion…”
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10
An antioxidant boehmite amino-nanozyme able to disaggregate Huntington's inclusion bodies
Published in Chemical communications (Cambridge, England) (19-04-2022)“…A novel amino-nanozyme, based on boehmite nanoparticles (BNPs) functionalised with a tetra-azapyridinophane (L1), has been designed to undermine some of the…”
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A step forward in the development of superoxide dismutase mimetic nanozymes: the effect of the charge of the surface on antioxidant activity
Published in RSC advances (16-12-2019)“…Two binucleating hezaaza macrocycles containing a pyridinol spacer have been prepared and characterised. Protonation studies indicate the deprotonation of the…”
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Coordination Chemistry of Cu 2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity
Published in Inorganic chemistry (04-09-2018)“…A new tetraaza-pyridinophane macrocycle (L1) N-alkylated with two isopropyl and one methyl groups symmetrically disposed has been prepared and its behavior…”
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13
New Polyamide Cryptand for Anion Binding
Published in Journal of the American Chemical Society (27-08-2003)“…An anion receptor derived from a tren-based amide cryptand with pyridine spacers has been synthesized and characterized. Two crystal structures are reported: …”
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N-(2-methyl-indol-1H-5-yl)-1-naphthalenesulfonamide: A novel reversible antimitotic agent inhibiting cancer cell motility
Published in Biochemical pharmacology (01-09-2016)“…[Display omitted] A series of compounds containing the sulfonamide scaffold were synthesized and screened for their in vitro anticancer activity against a…”
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Intermolecular Binding Modes in a Novel [1 + 1] Condensation 1H‑Pyrazole Azamacrocycle: A Solution and Solid State Study with Evidence for CO2 Fixation
Published in Inorganic chemistry (07-10-2013)“…The synthesis of a novel cyclophane (L1) consisting of a 1H-pyrazole moiety linked through methylene groups to a 1,5,9,13-tetraazadecane chain is described. As…”
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CO2 Fixation by Cu2+ and Zn2+ Complexes of a Terpyridinophane Aza Receptor. Crystal Structures of Cu2+ Complexes, pH-Metric, Spectroscopic, and Electrochemical Studies
Published in Inorganic chemistry (01-05-2006)“…The synthesis of the terpyridinophane-type polyamine 2,6,9,12,16-pentaaza[17]-(5,5‘ ‘)-cyclo-(2,2‘:6‘,2‘ ‘)-terpyridinophane heptahydrobromide tetrahydrate…”
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Parallels in Cation and Anion Coordination: A New Class of Cascade Complexes
Published in Angewandte Chemie International Edition (03-07-2002)“…Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion‐based cascade complex, which…”
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Acid-base properties of functionalised tripodal polyamines and their interaction with nucleotides and nucleic acids
Published in Organic & biomolecular chemistry (01-01-2010)“…Novel, highly positively charged tripodal polyamines with appended heterocyclic moieties revealed an intriguing panel of protonation species within the…”
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Structural reorganisation in polytopic receptors revealed by kinetic studies
Published in Chemical communications (Cambridge, England) (07-09-2010)“…One of the first kinetic studies of metal ion reorganisation between the different sites of a tritopic polyaza ligand reveals well defined pathways for the…”
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Geometric Isomerism in Pentacoordinate Cu2+ Complexes: Equilibrium, Kinetic, and Density Functional Theory Studies Reveal the Existence of Equilibrium between Square Pyramidal and Trigonal Bipyramidal Forms for a Tren-Derived Ligand
Published in Inorganic chemistry (02-02-2009)“…A ligand (L1) (bis(aminoethyl)[2-(4-quinolylmethyl)aminoethyl]amine) containing a 4-quinolylmethyl group attached to one of the terminal amino groups of…”
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