Search Results - "Liyanage, O Tara"
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Applying an Internal Standard to Improve the Repeatability of In-electrospray H/D Exchange of Carbohydrate-Metal Adducts
Published in Journal of the American Society for Mass Spectrometry (01-08-2019)“…In-electrospray (ESI) hydrogen/deuterium exchange–mass spectrometry (HDX-MS) has been used to characterize solvated carbohydrate structures. However, the rapid…”
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2
Mass Spectral Detection of Forward- and Reverse-Hydrogen/Deuterium Exchange Resulting from Residual Solvent Vapors in Electrospray Sources
Published in Journal of the American Society for Mass Spectrometry (01-10-2018)“…Characterizing glycans is analytically challenging since glycans are heterogeneous, branched polymers with different three-dimensional conformations…”
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Characterization of Electrospray Ionization (ESI) Parameters on In-ESI Hydrogen/Deuterium Exchange of Carbohydrate-Metal Ion Adducts
Published in Journal of the American Society for Mass Spectrometry (01-02-2019)“…The conformations of glycans are crucial for their biological functions. In-electrospray ionization (ESI) hydrogen/deuterium exchange-mass spectrometry…”
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Diverse Reactivity of Dienes with Pentaphenylborole and 1‐Phenyl‐2,3,4,5‐Tetramethylborole Dimer
Published in Chemistry : a European journal (28-01-2019)“…The reactions of a monomeric borole and a dimeric borole with 2,3‐dimethyl‐1,3‐butadiene and 1,3‐cyclohexadiene were investigated. The monomeric borole reacted…”
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Defining the Ceramide Composition of Bovine and Human Milk Gangliosides by Direct Infusion ESI-CID Tandem Mass Spectrometry of Native and Permethylated Molecular Species
Published in Analytical chemistry (Washington) (14-11-2023)“…Gangliosides are glycosphingolipids composed of an oligosaccharide that contains one or more sialic acid residues and is linked to a ceramide, a lipid composed…”
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Effect of pH on In-Electrospray Hydrogen/Deuterium Exchange of Carbohydrates and Peptides
Published in Journal of the American Society for Mass Spectrometry (06-03-2024)“…Carbohydrates are critical for cellular functions as well as an important class of metabolites. Characterizing carbohydrate structures is a difficult…”
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Characterizing the Dynamics of Solvated Disaccharides with In-Electrospray Ionization Hydrogen/Deuterium Exchange-Mass Spectrometry
Published in Analytical chemistry (Washington) (06-08-2024)“…Carbohydrates have various biological functions that are based on their structures. However, the composition and the glycosidic-bond linkage and configuration…”
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Formation of Carbohydrate–Metal Adducts from Solvent Mixtures during Electrospray: A Molecular Dynamics and ESI-MS Study
Published in Journal of the American Society for Mass Spectrometry (01-12-2021)“…Electrospray ionization (ESI) is frequently used to produce gas-phase ions for mass spectrometry (MS)-based techniques. The composition of solvents used in…”
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Distinguishing Carbohydrate Isomers with Rapid Hydrogen/Deuterium Exchange-Mass Spectrometry
Published in Journal of the American Society for Mass Spectrometry (06-01-2021)“…Carbohydrates play key roles in facilitating cellular functions, yet characterizing their structures is analytically challenging due to the presence of…”
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Release of Carbohydrate–Metal Adducts from Electrospray Droplets: Insight into Glycan Ionization by Electrospray
Published in The journal of physical chemistry. B (23-01-2020)“…Glycans have an immense number of biological activities, necessitating increased efforts to characterize glycan structures. Mass spectrometry has been coupled…”
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11
Characterization of Electrospray Ionization (ESI) Parameters on In-ESI Hydrogen/Deuterium Exchange of Carbohydrate-Metal Ion Adducts
Published in Journal of the American Society for Mass Spectrometry (23-10-2018)“…The conformations of glycans are crucial for their biological functions. In-electrospray ionization (ESI) hydrogen/deuterium exchange-mass spectrometry…”
Get full text
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