Search Results - "Liu, Shih‐Yuan"
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The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications
Published in Journal of the American Chemical Society (31-01-2018)“…Boron–nitrogen heteroarenes hold great promise for practical application in many areas of chemistry. Enduring interest in realizing this potential has in turn…”
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Pd‐Senphos Catalyzed trans‐Selective Cyanoboration of 1,3‐Enynes
Published in Angewandte Chemie International Edition (07-09-2020)“…The first trans‐selective cyanoboration reaction of an alkyne, specifically a 1,3‐enyne, is described. The reported palladium‐catalyzed cyanoboration of…”
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3
Recent Advances in Azaborine Chemistry
Published in Angewandte Chemie International Edition (18-06-2012)“…The chemistry of organoboron compounds has been primarily dominated by their use as powerful reagents in synthetic organic chemistry. Recently, the…”
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Boron‐Nitrogen‐Containing Benzene Valence Isomers
Published in Chemistry : a European journal (01-10-2024)“…Benzene is one of the most ubiquitous structural motifs in chemistry. The valence isomers of benzene have also attracted synthetic chemists’ attention due to…”
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5
Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex
Published in Journal of the American Chemical Society (09-11-2016)“…A concise synthesis of monobenzofused 1,4-azaborine phosphine ligands (Senphos) is described. These Senphos ligands uniquely support Pd-catalyzed…”
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6
Accessing 1,2‐Substituted Cyclobutanes through 1,2‐Azaborine Photoisomerization
Published in Angewandte Chemie International Edition (19-12-2019)“…We provide a seminal example of the utility of the 1,2‐azaborine motif as a 4C+1N+1B synthon in organic synthesis. Specifically, conditions for the practically…”
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Regioregular Synthesis of Azaborine Oligomers and a Polymer with a syn Conformation Stabilized by NH⋅⋅⋅π Interactions
Published in Angewandte Chemie International Edition (14-09-2015)“…The regioregular synthesis of the first azaborine oligomers and a corresponding conjugated polymer was accomplished by Suzuki–Miyaura coupling methods. An…”
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C−Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3‐Enynes
Published in Angewandte Chemie International Edition (20-09-2021)“…A new family of carbon‐bound boron enolates, generated by a kinetically controlled halogen exchange between chlorocatecholborane and silylketene acetals, is…”
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9
A BN‐Doped Cycloparaphenylene Debuts
Published in Angewandte Chemie International Edition (18-01-2021)“…The first example of a BN‐doped cycloparaphenylene BN‐[10]CPP was synthesized and characterized. Its reactivity and photophysical properties were evaluated in…”
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10
Cation-π binding ability of BN indole
Published in Chemical communications (Cambridge, England) (31-03-2020)“…A BN indole-containing aromatic scaffold has been synthesized and the cation-π binding ability characterized by nuclear magnetic resonance (NMR) monitored…”
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11
Exploring the strength of a hydrogen bond as a function of steric environment using 1,2-azaborine ligands and engineered T4 lysozyme receptors
Published in Organic & biomolecular chemistry (07-08-2019)“…A congeneric series of 1,2-azaborine ligands was used to study the relationship between the steric demand of the ligand and hydrogen bonding strength in the…”
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12
Homogeneous metal catalysis for conversion between aromatic and saturated compounds
Published in Coordination chemistry reviews (01-05-2016)“…•Homogeneous catalytic arene and heteroarene hydrogenation is broadly reviewed.•Various hydrogenation mechanistic studies are discussed.•Most recent research…”
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13
The Least Stable Isomer of BN Naphthalene: Toward Predictive Trends for the Optoelectronic Properties of BN Acenes
Published in Journal of the American Chemical Society (03-05-2017)“…The least stable isomer of the parental BN naphthalene series has been synthesized in a simple four-step sequence. Its experimental electronic structure…”
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14
Monobenzofused 1,4-Azaborines: Synthesis, Characterization, and Discovery of a Unique Coordination Mode
Published in Angewandte Chemie International Edition (23-06-2014)“…We report the first general synthesis of boron‐substituted monobenzofused 1,4‐azaborines using ring‐closing metathesis of an enamine‐containing diene as a key…”
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15
Medicinal Chemistry Profiling of Monocyclic 1,2‐Azaborines
Published in ChemMedChem (07-03-2017)“…The first examples of biologically active monocyclic 1,2‐azaborines have been synthesized and demonstrated to exhibit not only improved in vitro aqueous…”
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The Dewar Isomer of 1,2‐Dihydro‐1,2‐azaborinines: Isolation, Fragmentation, and Energy Storage
Published in Angewandte Chemie International Edition (04-05-2018)“…The photochemistry of 1,2‐dihydro‐1,2‐azaborinine derivatives was studied under matrix isolation conditions and in solution. Photoisomerization occurs…”
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17
Decentralized control of multi-robot partially observable Markov decision processes using belief space macro-actions
Published in The International journal of robotics research (01-02-2017)“…This work focuses on solving general multi-robot planning problems in continuous spaces with partial observability given a high-level domain description…”
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18
BN Tetracene: Extending the Reach of BN/CC Isosterism in Acenes
Published in Organometallics (24-07-2017)“…The first synthesis of a tetracene BN isostere is reported. Comparison with its direct, all-carbon analogue reveals that the BN tetracene isostere exhibits a…”
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Diels-Alder Reactions of 1,2-Azaborines
Published in Angewandte Chemie International Edition (26-06-2015)“…Diels–Alder reactions employing 1,2‐azaborine heterocycles as 1,3‐dienes are reported. Carbocyclic compounds with high stereochemical and functional complexity…”
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20
A Boron Protecting Group Strategy for 1,2-Azaborines
Published in Journal of the American Chemical Society (25-10-2017)“…Upon reaction with either molecular oxygen or di-tert-butylperoxide in the presence of a simple copper(I) salt and an alcohol, a range of 1,2-azaborines…”
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