Search Results - "Liu, Guosheng"
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Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles
Published in Organic & biomolecular chemistry (21-08-2012)“…Transition metal catalysts have been developed for introducing fluorine into organic compounds. Recent progress in this area is reviewed with an emphasis on…”
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2
Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations
Published in Accounts of chemical research (18-09-2018)“…Conspectus The direct transformation of C–H bonds into diverse functional groups represents one of the most atom- and step-economical strategies for organic…”
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3
Deriving snow cloud characteristics from CloudSat observations
Published in Journal of Geophysical Research - Atmospheres (27-04-2008)“…There has been so far no global estimate of snowfall. CloudSat has, for the first time, provided an opportunity for us to conduct such an estimate. The present…”
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Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center
Published in Accounts of chemical research (15-11-2016)“…Difunctionalization of alkenes to incorporate two functional groups across a double bond has emerged as a powerful transformation to greatly increase molecular…”
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5
Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis
Published in Journal of the American Chemical Society (08-11-2017)“…The merger of photoredox catalysis with asymmetric copper catalysis have been realized to convert achiral carboxylic acids into enantiomerically enriched alkyl…”
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6
Enantioselective Arylation of Benzylic C−H Bonds by Copper‐Catalyzed Radical Relay
Published in Angewandte Chemie International Edition (06-05-2019)“…A novel enantioselective copper‐catalyzed arylation of benzylic C−H bonds, using alkylarenes as a limiting reagent, has been developed. A chiral bisoxazoline…”
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Enantioselective Copper-Catalyzed Alkynylation of Benzylic C–H Bonds via Radical Relay
Published in Journal of the American Chemical Society (15-07-2020)“…The first enantioselective alkynylation of benzylic C–H bonds via copper-catalyzed radical relay has been established herein, which provides an easy access to…”
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8
The Characteristics of Ice Cloud Properties Derived from CloudSat and CALIPSO Measurements
Published in Journal of climate (01-05-2015)“…Abstract The characteristics of ice clouds with a wide range of optical depths are studied based on satellite retrievals and radiative transfer modeling…”
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Enantioselective Copper‐Catalyzed Intermolecular Amino‐ and Azidocyanation of Alkenes in a Radical Process
Published in Angewandte Chemie International Edition (13-02-2017)“…Asymmetric copper‐catalyzed intermolecular amino‐ and azidocyanation reactions of alkenes have been developed that proceed via a radical process in which a key…”
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10
Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process
Published in Journal of the American Chemical Society (07-12-2016)“…A novel enantioselective copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes has been developed, in which a variety of CF -containing…”
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Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides
Published in Angewandte Chemie International Edition (10-02-2014)“…A novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF3‐containing…”
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12
Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual CH Bond Cleavage of an Arene and Acetonitrile
Published in Angewandte Chemie International Edition (23-12-2011)“…Not one but two: The title reaction proceeds through the dual CH bond cleavage of both aniline and acetonitrile (see scheme). The reaction affords a variety…”
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13
Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
Published in Journal of the American Chemical Society (23-12-2015)“…The first catalytic trifluoromethoxylation of unactivated alkenes has been developed, in which Pd(CH3CN)2Cl2 was used as catalyst, AgOCF3 as…”
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14
Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3 + Reagent
Published in Journal of the American Chemical Society (23-07-2014)“…A novel copper-catalyzed intermolecular trifluoromethylarylation of alkenes is developed using less active ether-type Togni’s reagent under mild reaction…”
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Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals
Published in Journal of the American Chemical Society (01-03-2017)“…A novel asymmetric radical trifluoromethyl-arylation of alkenes has been developed, which provides an efficient approach to access chiral CF3-containing…”
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16
Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
Published in Science (American Association for the Advancement of Science) (02-09-2016)“…Direct methods for stereoselective functionalization of sp³-hybridized carbon-hydrogen [C(sp³)-H] bonds in complex organic molecules could facilitate much more…”
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Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines
Published in Journal of the American Chemical Society (24-05-2017)“…We have developed a copper-catalyzed enantioselective intermolecular aminoarylation of alkenes using a novel N-fluoro-N-alkylsulfonamide as the amine…”
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18
Palladium(II)‐Catalyzed Enantioselective Azidation of Unactivated Alkenes
Published in Angewandte Chemie International Edition (21-09-2020)“…The first Pd‐catalyzed enantioselective azidation of unactivated alkenes has been established by using readily accessible 1‐azido‐1,2‐benziodoxol‐3(1H)‐one…”
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Recent Advances and Perspectives in Transition Metal‐Catalyzed 1,4‐Functionalizations of Unactivated 1,3‐Enynes for the Synthesis of Allenes
Published in Chinese journal of chemistry (01-01-2020)“…Classic methods for the synthesis of allenes usually introduce only one functional group into products. In this review, we highlight the recent advances and…”
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Palladium-Catalyzed Cascade CH Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes
Published in Angewandte Chemie International Edition (15-09-2014)“…A palladium‐catalyzed selective CH bond trifluoroethylation of aryl iodides has been explored. The reaction allows for the efficient synthesis of a variety of…”
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