Search Results - "Linder, David"
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High entropy alloys: Substituting for cobalt in cutting edge technology
Published in Applied materials today (01-09-2018)“…•Metal cutting tools made of cemented carbide are a strong pillar to today's industry.•A key ingredient in cemented carbide is cobalt, but it needs to be…”
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ICME guided property design: Room temperature hardness in cemented carbides
Published in Materials & design (05-01-2019)“…The potential change in EU regulations may affect the traditional W-C-Co based cemented carbides industry and a methodology is required to accelerate the…”
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Enantioselective and Regioselective Ruthenium-Catalyzed Decarboxylative Etherification of Allyl Aryl Carbonates
Published in Chemistry : a European journal (27-06-2008)“…Simple ligand, catalyst and conditions: The combination of readily‐prepared pyridylmonooxazolines (pymox) ligands and [CpRu(CH3CN)3][PF6] affords a regio‐ and…”
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Enantioselective CpRu‐Catalyzed Carroll Rearrangement – Ligand and Metal Source Importance
Published in European Journal of Organic Chemistry (01-12-2008)“…The addition of unstabilized carbonyl nucleophiles to unsymmetrical allyl‐metal fragments still represents a challenge to generate stereogenic centers enantio‐…”
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Book Review Journal Article -
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Hexacoordinated phosphates: how to teach old chiral anions new asymmetric tricks
Published in Chemical record (2007)“…Chemical reactions and processes often involve chiral, yet racemic, cationic reagents, intermediates, or products. To afford instead nonracemic or enantiopure…”
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Air- and Microwave-Stable (C₅H₅)Ru Catalysts for Improved Regio- and Enantioselective Carroll Rearrangements
Published in Angewandte Chemie (International ed.) (01-01-2007)“…Reduce, reuse, recycle: Zwitterionic adducts of pyridyl‐containing hexacoordinate phosphorus anions and (C5H5)Ru moieties (see picture) are air‐, moisture‐,…”
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Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
Published in Pure and applied chemistry (01-05-2008)“…The addition of unstabilized carbonyl nucleophiles to allyl-metal fragments still represents a challenge for generating stereoselectively tertiary (and…”
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Synthesis of the fungus metabolite cladosin C
Published in Organic & biomolecular chemistry (20-09-2017)“…Cladosin C is one of the few known enaminotetramic acids, isolated from extracts of the deep sea fungus Cladosporium sphaerospermum. It was synthesised in ten…”
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Modelling of solid solution strengthening in multicomponent alloys
Published in Materials science & engineering. A, Structural materials : properties, microstructure and processing (17-07-2017)“…With increasing industrial interest in high alloyed multicomponent and High Entropy Alloy (HEA) systems the integration of solid solution strengthening in the…”
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High entropy alloy binders in gradient sintered hardmetal
Published in International journal of refractory metals & hard materials (01-02-2018)“…High Entropy Alloys (HEAs) are a new group of multicomponent alloys showing great potential as bulk alloys in many fields, and their high temperature strength…”
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Diffusion modeling in cemented carbides: Solubility assessment for Co, Fe and Ni binder systems
Published in International journal of refractory metals & hard materials (01-11-2017)“…The increasing interest in alternative binder solutions for WC based cemented carbide systems leads to more integration of ICME (Integrated Computational…”
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Development of a Continuous Flow Grignard Reaction to Manufacture a Key Intermediate of Ipatasertib
Published in Organic process research & development (17-05-2024)“…This article outlines the development of a continuous flow process for the manufacture of a key intermediate of the active pharmaceutical ingredient…”
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Alternative Ni-based cemented carbide binder – Hardness characterization by nano-indentation and focused ion beam
Published in International journal of refractory metals & hard materials (01-06-2018)“…The nano-hardness in the alternative 85Ni-15Fe binder phase of WC cemented carbide has been investigated. High-resolution scanning electron microscopy (SEM)…”
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Indentation behavior of highly confined elasto-plastic materials
Published in International journal of solids and structures (01-06-2020)“…The effect of geometric confinement is well-known from hardness measurements of thin films on stiff substrates and has been modeled both phenomenologically and…”
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Synthesis of a Highly Functionalized Quinazoline Organozinc toward KRAS G12C Inhibitor Divarasib (GDC-6036), Enabled through Continuous Flow Chemistry
Published in Organic process research & development (17-05-2024)“…The development of a scalable continuous flow process to synthesize a densely functionalized quinazoline organozinc intermediate toward KRAS G12C inhibitor…”
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Enantioselective Synthesis of Putative Lipiarmycin Aglycon Related to Fidaxomicin/Tiacumicin B
Published in Angewandte Chemie International Edition (02-02-2015)“…An enantioselective synthesis of a putative lipiarmycin aglycon was accomplished and features: 1) Brown′s enantioselective alkoxyallylboration and allylation…”
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Evaluating magnetic properties of composites from model alloys – Application to alternative binder cemented carbides
Published in Scripta materialia (15-07-2019)“…The magnetic properties of 85Ni-15Fe model alloys containing Co, W and C have been studied with the intent to isolate the influence of alloy chemistry on…”
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Modeling confined ductile fracture – A void-growth and coalescence approach
Published in International journal of solids and structures (01-10-2020)“…In a composite material a soft, ductile matrix can be confined by a hard, brittle phase, altering its deformation and fracture behavior. Increasing confinement…”
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A new hardness model for materials design in cemented carbides
Published in International journal of refractory metals & hard materials (01-09-2018)“…The Materials Design approach offers new possibilities towards property-oriented materials development. The performance of cemented carbides is significantly…”
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(Cyclopentadienyl)ruthenium-Catalyzed Regio- and Enantioselective Decarboxylative Allylic Etherification of Allyl Aryl and Alkyl Carbonates
Published in Advanced synthesis & catalysis (17-12-2010)“…(Cyclopentadienyl)tris(acetonitrile)ruthenium hexafluorophosphate {[CpRu(NCMe)3][PF6]} or (cyclopentadienyl)(η6‐naphthalene)ruthenium hexafluorophosphate…”
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