Search Results - "Lindeman, Sergey V."

Regioselectivity in the Scholl Reaction: Mono and Double [7]Helicenes by Hossain, Mohammad Mosharraf, Thakur, Khushabu, Talipov, Marat R, Lindeman, Sergey V, Mirzaei, Saber, Rathore, Rajendra

“…We employed the density functionaly theory (DFT)-predicted regioselectivity of the intramolecular Scholl reaction in phenanthrene and dibenzo­[g,p]­chrysene…”
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Reversible Dioxygen Binding to Co(II) Complexes with Noninnocent Ligands by Kumar, Praveen, Devkota, Laxmi, Casey, Maximilian C., Fischer, Anne A., Lindeman, Sergey V., Fiedler, Adam T.

“…A series of mononuclear Co­(II) complexes with noninnocent (redox-active) ligands are prepared that exhibit metal–ligand cooperativity during the reversible…”
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Design, Synthesis, Electronic Properties, and X-ray Structural Characterization of Various Modified Electron-Rich Calixarene Derivatives and Their Conversion to Stable Cation Radical Salts by Rathore, Rajendra, Lindeman, Sergey V, Abdelwahed, Sameh H

“…We have designed and synthesized electron-rich calixarene derivatives, which undergo reversible electrochemical oxidation in a well-accessible potential range…”
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Spectroscopic and Magnetic Studies of Co(II) Scorpionate Complexes: Is There a Halide Effect on Magnetic Anisotropy? by Devkota, Laxmi, SantaLucia, Daniel J., Wheaton, Amelia M., Pienkos, Alexander J., Lindeman, Sergey V., Krzystek, J., Ozerov, Mykhaylo, Berry, John F., Telser, Joshua, Fiedler, Adam T.

“…The observation of single-molecule magnetism in transition-metal complexes relies on the phenomenon of zero-field splitting (ZFS), which arises from the…”
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Assembly, Structure, and Reactivity of Cu4S and Cu3S Models for the Nitrous Oxide Reductase Active Site, CuZ by Johnson, Brittany J, Lindeman, Sergey V, Mankad, Neal P

“…Bridging diphosphine ligands were used to facilitate the assembly of copper clusters with single sulfur atom bridges that model the structure of the CuZ*…”
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Silver(I) and Copper(I) Complexes of Semi‐Bulky Nitrogen‐Confused C‐Scorpionates by Wang, Denan, Jahan, Fathiya, Meise, Kristen J., Lindeman, Sergey V., Gardinier, James R.

“…Two new sterically demanding nitrogen‐confused C‐scorpionate ligands with a bis(3,5‐diisopropylpyrazol‐1‐yl)methyl group bound to the 3‐ position of a normal…”
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Reaction Chemistry of Silver(I) Trifluoromethanesulfonate Complexes of Nitrogen-Confused C‑Scorpionates by Gardinier, James R, Meise, Kristin J, Jahan, Fathiya, Lindeman, Sergey V

“…Two new C-scorpionate ligands with a bis­(3,5-dimethylpyrazol-1-yl)­methyl group bound to the 3 position of either an N-tosyl (TsL*) or an N–H pyrazole (HL*)…”
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A Cu4S model for the nitrous oxide reductase active sites supported only by nitrogen ligands by Johnson, Brittany J, Antholine, William E, Lindeman, Sergey V, Mankad, Neal P

“…To model the (His)7Cu4Sn (n = 1 or 2) active sites of nitrous oxide reductase, the first Cu4(μ4-S) cluster supported only by nitrogen donors has been prepared…”
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Selective Isomer Formation and Crystallization-Directed Magnetic Behavior in Nitrogen-Confused C‑Scorpionate Complexes of Fe(O3SCF3)2 by Gardinier, James R, Meise, Kristin J, Jahan, Fathiya, Wang, Denan, Lindeman, Sergey V

“…The complex [Fe­(HL*)2]­(OTf)2, 1, where HL* = bis­(3,5-dimethylpyrazol-1-yl)­(3-1H-pyrazole)­methane, was prepared in order to compare its magnetic properties…”
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A Synthetic Model of the Putative Fe(II)-Iminobenzosemiquinonate Intermediate in the Catalytic Cycle of o-Aminophenol Dioxygenases by Bittner, Michael M, Lindeman, Sergey V, Fiedler, Adam T

“…The oxidative ring cleavage of aromatic substrates by nonheme Fe dioxygenases is thought to involve formation of a ferrous–(substrate radical) intermediate…”
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Multifunctional heterocyclic scaffolds for hybrid Lewis acid/Lewis base catalysis of carbon–carbon bond formation by Wiedenhoeft, Dennis, Benoit, Adam R., Wu, Yibiao, Porter, Jacob D., Meyle, Elisia, Yeung, Teresa H.W., Huff, Raechel, Lindeman, Sergey V., Dockendorff, Chris

“…Several new classes of hybrid catalysts have been synthesized by tethering heterocyclic metal (Lewis acid) chelating scaffolds to several different amines…”
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Charge Delocalization in Self-Assembled Mixed-Valence Aromatic Cation Radicals by Navale, Tushar S, Thakur, Khushabu, Vyas, Vijay S, Wadumethrige, Shriya H, Shukla, Ruchi, Lindeman, Sergey V, Rathore, Rajendra

“…The spontaneous assembly of aromatic cation radicals (D +• ) with their neutral counterpart (D) affords dimer cation radicals (D 2 +• ). The intermolecular…”
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Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene by Chebny, Vincent J, Dhar, Dwairath, Lindeman, Sergey V, Rathore, Rajendra

“…A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller…”
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Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor by Chebny, Vincent J, Shukla, Ruchi, Lindeman, Sergey V, Rathore, Rajendra

“…The one-electron oxidation of tetramethoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially…”
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Structural Characterization of Quaterphenyl Cation Radical:  X-ray Crystallographic Evidence of Quinoidal Charge Delocalization in Poly-p-phenylene Cation Radicals by Banerjee, Moloy, Lindeman, Sergey V, Rathore, Rajendra

“…Quaterphenyl derivative (QP) containing tert-butyl solubilizing groups at the terminal positions yields a stable cation radical salt that was isolated, and its…”
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Synthesis, Electronic Properties, and X-ray Structural Characterization of Tetrarylbenzo[1,2-b:4,5-b′]difuran Cation Radicals by Shukla, Ruchi, Wadumethrige, Shriya H, Lindeman, Sergey V, Rathore, Rajendra

“…Electroactive tetraarylbenzo[1,2-b:4,5-b′]difuran (BDF) and model diarylbenzofuran derivatives are synthesized and their structures are established by X-ray…”
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A Versatile Synthesis of Electroactive Stilbenoprismands for Effective Binding of Metal Cations by Debroy, Paromita, Lindeman, Sergey V, Rathore, Rajendra

“…A versatile synthesis of a new class of polyaromatic receptors (stilbenoprismands) containing a Δ-shaped cavity similar to that of the π-prismand together with…”
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Isolation and X-ray structural characterization of tetraisopropylpyrene cation radical by Banerjee, Moloy, Vyas, Vijay S, Lindeman, Sergey V, Rathore, Rajendra

“…A practical synthesis of 1,3,6,8-tetraisopropylpyrene and the isolation and X-ray structural characterization of its monomeric cation radical salt are…”
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Electron Transfer Prompted Ejection of a Tightly Bound K+ from the Ethereal Cavity of a Hexaarylbenzene-Based Receptor by Shukla, Ruchi, Lindeman, Sergey V, Rathore, Rajendra

“…Synthesis of a pair of rotamers (9u/9s) of a hexaarylbenzene derivative containing six (cofacially arranged) electroactive 2,5-dimethoxytolyl groups is…”
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Syntheses and Electronic Properties of Rhodium(III) Complexes Bearing a Redox-Active Ligand by Wanniarachchi, Sarath, Liddle, Brendan J, Kizer, Brandon, Hewage, Jeewantha S, Lindeman, Sergey V, Gardinier, James R

“…A series of rhodium(III) complexes of the redox-active ligand, H(L = bis(4-methyl-2-(1H-pyrazol-1-yl)phenyl)amido), was prepared, and the electronic properties…”
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