Search Results - "Li, Run‐Han"
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Bridging the Homogeneous and Heterogeneous Catalysis by Supramolecular Metal‐Organic Cages with Varied Packing Modes
Published in Advanced materials (Weinheim) (01-04-2024)“…Integrating the advantages of homogeneous and heterogeneous catalysis has proved to be an optimal strategy for developing catalytic systems with high…”
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Different Protonic Species Affecting Proton Conductivity in Hollow Spherelike Polyoxometalates
Published in ACS applied materials & interfaces (20-02-2019)“…Polyoxometalates (POMs), which possess strong acidity and chemical stability, are promising solid proton conductors and potential candidates for proton…”
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3
Molecular oxidation-reduction junctions for artificial photosynthetic overall reaction
Published in Proceedings of the National Academy of Sciences - PNAS (04-10-2022)“…Constructing redox semiconductor heterojunction photocatalysts is the most effective and important means to complete the artificial photosynthetic overall…”
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In situ Construction of Single‐Atom Electronic Bridge on COF to Enhance Photocatalytic H2 Production
Published in Angewandte Chemie International Edition (04-11-2024)“…Photocatalytic hydrogen production is one of the most valuable technologies in the future energy system. Here, we designed a metal‐covalent organic frameworks…”
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5
Photocatalytic aerobic oxidation of C(sp3)-H bonds
Published in Nature communications (15-01-2024)“…In modern industries, the aerobic oxidation of C(sp 3 )-H bonds to achieve the value-added conversion of hydrocarbons requires high temperatures and pressures,…”
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Springboard Role for Iridium Photocatalyst: Theoretical Insight of C(sp3)−N Cross‐Coupling by Photoredox‐Mediated Iridium/Copper Dual Catalysis versus Single‐Copper Catalysis
Published in ChemCatChem (22-03-2022)“…Photoredox‐mediated dual metal catalysis has been considered as a more efficient method for cross‐coupling reactions than single metal catalysis, however, the…”
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Investigation of the Enhanced Lithium Battery Storage in a Polyoxometalate Model: From Solid Spheres to Hollow Balls
Published in Small methods (13-11-2018)“…Materials with hollow structures are generally considered more conducive to lithium‐ion storage than solid materials, but there is no suitable crystal model…”
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Calix[4]arene-Functionalized Titanium-Oxo Compounds for Perceiving Differences in Catalytic Reactivity Between Mono- and Multimetallic Sites
Published in Journal of the American Chemical Society (26-07-2023)“…While the difference in catalytic reactivity between mono- and multimetallic sites is often attributed to more than just the number of active sites, still few…”
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Revealing the roles of the dual active-sites on a polyoxometalate-based metal–organic framework in catalyzing Knoevenagel condensations
Published in Applied surface science (01-05-2024)“…The polyoxometalate-based metal–organic frameworks have successfully achieved efficiency catalysis of the Knoevenagel condensation reactions under solvent-free…”
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10
In situ Construction of Single-Atom Electronic Bridge on COF to Enhance Photocatalytic H 2 Production
Published in Angewandte Chemie International Edition (04-11-2024)“…Photocatalytic hydrogen production is one of the most valuable technologies in the future energy system. Here, we designed a metal-covalent organic frameworks…”
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11
Photocatalytic C(sp3)–O/N Cross-Couplings by NaI–PPh3/CuBr Cooperative Catalysis: Computational Design and Experimental Verification
Published in ACS catalysis (04-06-2021)“…Photocatalytic coupling reactions have developed rapidly in the field of organic synthesis. However, highly efficient, broad-spectrum, low-cost, and…”
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12
Unraveling photocatalytic electron transfer mechanism in polyoxometalate-encapsulated metal-organic frameworks for high-efficient CO2 reduction reaction
Published in Applied catalysis. B, Environmental (05-12-2022)“…Unraveling the fundamental electron transfer mechanism is vital to deeply understand the heterogeneous photocatalysis process so as to develop new efficient…”
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13
Superiority of Iridium Photocatalyst and Role of Quinuclidine in Selective α‑C(sp3)–H Alkylation: Theoretical Insights
Published in Journal of organic chemistry (01-01-2021)“…Recent experimental work reported that visible-light photoredox catalysis coupled with primary sulfonamides and electron-deficient alkenes could efficiently…”
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14
Solid-Liquid-Gas Three-Phase Indirect Electrolysis Enabled by Affinity Auxiliary Imparted Covalent Organic Frameworks
Published in Angewandte Chemie International Edition (23-09-2024)“…The design of efficient heterogenous redox mediators with favorable affinity to substrate and electrolyte are much desired yet still challenging for the…”
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15
Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters
Published in Chinese chemical letters (01-05-2024)“…The fascinating chemical structure and broad application prospect of Keggin-type polyoxometalates (POMs) have attracted many chemists to explore and discover…”
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Theoretical study on the photocyclization reactivity mechanism in a diarylethene derivative with multicolour fluorescence modulation
Published in Journal of photochemistry and photobiology. A, Chemistry. (01-02-2021)“…We studied the photocyclization reaction mechanism and photophysical processes of one diarylethylene derivative Spiro-DAE in theory. Results show that the…”
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17
In situ Construction of Single‐Atom Electronic Bridge on COF to Enhance Photocatalytic H2 Production
Published in Angewandte Chemie (04-11-2024)“…Photocatalytic hydrogen production is one of the most valuable technologies in the future energy system. Here, we designed a metal‐covalent organic frameworks…”
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18
Insight into the Mechanism of CO 2 Chemical Fixation into Epoxides by Windmill-Shaped Polyoxovanadate and n -Bu 4 NX (X = Br, I)
Published in Inorganic chemistry (29-07-2024)“…Carbon dioxide (CO ) coupled with epoxide to generate cyclic carbonate stands out in carbon neutrality due to its 100% atom utilization. In this work, the…”
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19
Insight into the Mechanism of CO2 Chemical Fixation into Epoxides by Windmill-Shaped Polyoxovanadate and n‑Bu4NX (X = Br, I)
Published in Inorganic chemistry (29-07-2024)“…Carbon dioxide (CO2) coupled with epoxide to generate cyclic carbonate stands out in carbon neutrality due to its 100% atom utilization. In this work, the…”
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3D Covalent Organic Frameworks with 16-Connectivity for Photocatalytic C(sp3)–C(sp2) Cross-Coupling
Published in Journal of the American Chemical Society (18-09-2024)“…The connectivity (valency) of building blocks for constructing 3D covalent organic frameworks (COFs) has long been limited to 4, 6, 8, and 12. Developing a…”
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