Search Results - "Li, Guigen"
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Catalytic C–H Arylation of Aliphatic Aldehydes Enabled by a Transient Ligand
Published in Journal of the American Chemical Society (05-10-2016)“…The direct arylation of aliphatic aldehydes has been established via Pd-catalyzed sp3 C–H bond functionalization in the presence of 3-aminopropanoic acids as…”
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2
Chemical‐Reductant‐Free Electrochemical Deuteration Reaction using Deuterium Oxide
Published in Angewandte Chemie International Edition (10-08-2020)“…We report a method for the electrochemical deuteration of α,β‐unsaturated carbonyl compounds under catalyst‐ and external‐reductant‐free conditions, with…”
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3
Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis
Published in Angewandte Chemie International Edition (22-03-2021)“…Arylation of carbonyls, one of the most common approaches toward alcohols, has received tremendous attention, as alcohols are important feedstocks and building…”
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4
Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source
Published in Angewandte Chemie International Edition (14-05-2018)“…The first direct aziridination of triaryl‐substituted alkenes was achieved by means of an electrochemical process that could extend to multisubstituted…”
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5
N‐Atom Deletion in Nitrogen Heterocycles
Published in Angewandte Chemie International Edition (13-09-2021)“…Excising the nitrogen in secondary amines, and coupling the two residual fragments is a skeletal editing strategy that can be used to construct molecules with…”
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6
N-Phosphonyl/phosphinyl imines and group-assisted purification (GAP) chemistry/technology
Published in Organic & biomolecular chemistry (14-02-2015)“…The development of environmentally benign, operationally simple, and economically viable synthetic methodologies has been a great challenge in organic…”
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7
Copper-Catalyzed Asymmetric Borylacylation of Styrene and Indene Derivatives
Published in Journal of organic chemistry (19-03-2021)“…The enantioselective copper-catalyzed borylacylation of aryl olefins with acyl chlorides and bis-(pinacolato)diboron is reported. This three-component…”
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8
Cobalt(II)-Catalyzed Stereoselective Olefin Isomerization: Facile Access to Acyclic Trisubstituted Alkenes
Published in Journal of the American Chemical Society (13-05-2020)“…Stereoselective synthesis of trisubstituted alkenes is a long-standing challenge in organic chemistry, due to the small energy differences between E and Z…”
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9
Metal‐to‐Ligand Ratio‐Dependent Chemodivergent Asymmetric Synthesis
Published in Angewandte Chemie International Edition (11-10-2021)“…Chemodivergent asymmetric synthesis was achieved by tuning the metal‐to‐ligand ratio in an organometallic catalytic system. Using N‐(aroyloxy)phthalimide as…”
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10
Synthesis of dienes from pyrrolidines using skeletal modification
Published in Nature communications (11-11-2023)“…Saturated N-heterocyclic pyrrolidines are common in natural products, medicinal compounds and agrochemicals. However, reconstruction of their skeletal…”
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11
Catalytic Dual 1,1-H-Abstraction/Insertion for Domino Spirocyclizations
Published in Journal of the American Chemical Society (22-07-2015)“…A catalytic domino spirocyclization of 1,7-enynes with simple cycloalkanes and cyclo-1,3-dicarbonyls has been established via multiple C–C bond formations from…”
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12
Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)H Bond Thiolation of Cycloalkanes
Published in Advanced synthesis & catalysis (11-08-2014)“…A concise thiolation of the C(sp3)H bond of cycloalkanes with diaryl disulfides in the presence of the oxidant di‐tert‐butyl peroxide (DTBP) has been…”
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13
Cobalt-Catalyzed Decarboxylative C–H (Hetero)Arylation for the Synthesis of Arylheteroarenes and Unsymmetrical Biheteroaryls
Published in Organic letters (20-10-2017)“…A cobalt-catalyzed decarboxylative cross-coupling reaction of (hetero)aryl carboxylic acids with benzothiazoles or benzoxazoles is reported. This represents a…”
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14
Four-Component Domino Reaction Leading to Multifunctionalized Quinazolines
Published in Journal of the American Chemical Society (26-08-2009)“…A new four-component domino reaction has been discovered. The reaction is easy to perform simply by mixing four common reactants and K2CO3 in ethylene glycol…”
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15
Molecular Design of Fused-Ring Phenazine Derivatives for Long-Cycling Alkaline Redox Flow Batteries
Published in ACS energy letters (14-02-2020)“…The utilization of redox-active organic species in aqueous redox flow batteries holds great promise for large-scale and sustainable energy storage. Herein, we…”
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16
Difluoroalkylation/C–H Annulation Cascade Reaction Induced by Visible-Light Photoredox Catalysis
Published in Journal of organic chemistry (21-10-2016)“…We report the first example of difluoroalkylation/C–H annulation cascade reactions of cyclopropyl olefins induced by visible-light photoredox catalysis…”
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17
A new cascade halosulfonylation of 1,7-enynes toward 3,4-dihydroquinolin-2(1H)-ones via sulfonyl radical-triggered addition/6-exo-dig cyclization
Published in Chemical communications (Cambridge, England) (31-01-2016)“…A new cascade three-component halosulfonylation of 1,7-enynes for efficient synthesis of densely functionalized 3,4-dihydroquinolin-2(1H)-ones has been…”
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18
Hantzsch Ester as a Photosensitizer for the Visible-Light-Induced Debromination of Vicinal Dibromo Compounds
Published in Chemistry : a European journal (04-07-2016)“…The debromination of vicinal dibromo compounds to generate alkenes usually requires harsh reaction conditions and the addition of catalysts. Just recently the…”
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Photocatalytic Multicomponent Annulation of Amide-Anchored 1,7-Diynes Enabled by Deconstruction of Bromotrichloromethane
Published in Molecules (Basel, Switzerland) (08-02-2024)“…We present the first example of visible-light-mediated multicomponent annulation of 1,7-diynes by taking advantage of quadruple cleavage olf carbon-halogen…”
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20
Catalytic Diazosulfonylation of Enynals toward Diazoindenes via Oxidative Radical-Triggered 5-exo-trig Carbocyclizations
Published in Organic letters (15-04-2016)“…Catalytic diazosulfonylation of enynals with arylsulfonyl hydrazides has been established by using tert-butyl hydroperoxide (TBHP) as the oxidant with…”
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