Search Results - "Li, Cunyao"
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Anti-disturbance control of a piezo-driven micromanipulator with a non-minimum phase
Published in AIP advances (01-03-2023)“…In precision micromanipulation tasks, operation accuracy and anti-disturbance performance of micromanipulators are critical. This paper presents…”
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2
Elucidation of hemilabile-coordination-induced tunable regioselectivity in single-site Rh-catalyzed heterogeneous hydroformylation
Published in Nature communications (14-08-2024)“…Revealing key factors that modulate the regioselectivity in heterogeneous hydroformylation requires identifying and monitoring the dynamic evolution of the…”
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3
Highly Selective Conversion of Syngas to Higher Oxygenates over Tandem Catalysts
Published in ACS catalysis (17-12-2021)“…Selective synthesis of higher oxygenates from syngas is an important but challenging research target, and the present methods for converting syngas into…”
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Highly Efficient Heterogeneous Pd@POPs Catalyst for the N-Formylation of Amine and CO2
Published in Catalysts (01-02-2021)“…Utilization of CO2 for the production of fine chemicals has become a research hotspot for a long time. In order to make use of CO2, we developed a highly…”
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Ionic Liquid/Zn-PPh3 Integrated Porous Organic Polymers Featuring Multifunctional Sites: Highly Active Heterogeneous Catalyst for Cooperative Conversion of CO2 to Cyclic Carbonates
Published in ACS catalysis (02-09-2016)“…A series of ionic liquid (IL), zinc halide (ZnX2), and triphenylphosphine (PPh3) integrated porous organic polymers (POPs) featuring multifunctional sites were…”
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Heterogeneous Rh/CPOL-BP&P(OPh)3 catalysts for hydroformylation of 1-butene: The formation and evolution of the active species
Published in Journal of catalysis (01-12-2018)“…[Display omitted] •A novel porous organic copolymer supported Rh catalyst was put forward.•High efficiency was achieved in heterogeneous hydroformylation of…”
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State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates
Published in ACS sustainable chemistry & engineering (05-06-2017)“…A single-component multifunctional catalyst (denoted as Mg-por/pho@POP) based on a magnesium porphyrin and phosphonium salt-integrated porous organic polymer…”
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Highly efficient porous organic copolymer supported Rh catalysts for heterogeneous hydroformylation of butenes
Published in Applied catalysis. A, General (05-02-2018)“…[Display omitted] •Various Rh/POPs catalysts were evaluated for heterogeneous hydroformylation of 1-butene.•Rh/CPOL-BP&P catalyst shows the highest activity…”
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Atomically Dispersed Zn‐Nx Sites in N‐Doped Carbon for Reductive N‐formylation of Nitroarenes with Formic Acid
Published in ChemCatChem (19-03-2020)“…Replacement of noble metal catalysts with low‐cost, non‐noble heterogeneous catalysts is highly desirable. Herein, we prepared a reactive, inexpensive and…”
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10
Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3
Published in Journal of catalysis (01-09-2017)“…[Display omitted] •A novel doped catalyst model Xantphos doped Rh/POPs-PPh3 was put forward.•High efficiency was achieved in heterogeneous hydroformylation…”
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11
A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts
Published in Frontiers of chemical science and engineering (01-03-2018)“…Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously…”
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12
Precisely design PPh3-based polymer by hybrid coupling of monomers for high efficient hydroformylation
Published in Microporous and mesoporous materials (01-01-2022)“…A series of hybrid coupling porous organic polymers (HC-3vPPh3-POLs) were designed and synthesized through copolymerizing any two of tris(4-vinphenyl)…”
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13
Tuning the framework flexibility and equilibrium of HRh(CO)2P2 active isomers in single-atom Rh/P&N-POPs catalysts for hydroformylation reactions
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-08-2023)“…[Display omitted] •P&N-POPs with diverse framework flexibility were afforded.•The coordination state surrounding single Rh sites were effectively…”
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14
Efficient heterogeneous hydroaminocarbonylation of olefins with ammonium chloride as amino source
Published in Applied catalysis. A, General (25-03-2021)“…Using olefins, ammonium chloride and CO to prepare primary amides straightly is a new stragegy of hydroaminocarbonylation reaction. Heterogeneous Pd@POPs-PPh3…”
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15
Bifunctional Heterogeneous Ru/POP Catalyst Embedded with Alkali for the N‑Formylation of Amine and CO2
Published in ACS sustainable chemistry & engineering (13-04-2020)“…CO2 as a C1 building block for the N-formylation reaction is attracting much attention. In general, the N-formylation reaction requires the participation of…”
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Single Ru–P Site Catalyst Coupling N Sites in a Flexible Polymeric Framework for Efficient CO2 Hydrogenation to Formate
Published in ACS catalysis (02-02-2024)“…Hydrogenation of CO2, an abundant C1 resource, into formate, is one of the most charming utilization routes of CO2. Herein, a series of single Ru–P site…”
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Fabrication of the Microenvironment and Active Structure of Single-Rh-Site Catalysts for Efficient Hydroformylation of Olefins
Published in ACS sustainable chemistry & engineering (28-11-2022)“…To enhance the catalytic performance of single-metal-site catalysts (SMSCs), regulating the interaction between the active site and substrate is crucial but…”
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Single Ru–P Site Catalyst Coupling N Sites in a Flexible Polymeric Framework for Efficient CO 2 Hydrogenation to Formate
Published in ACS catalysis (02-02-2024)Get full text
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Sulfur Poisoning and Self‐Recovery of Single‐Site Rh1/Porous Organic Polymer Catalysts for Olefin Hydroformylation
Published in Angewandte Chemie International Edition (24-07-2023)“…Sulfur poisoning and regeneration are global challenges for metal catalysts even at the ppm level. The sulfur poisoning of single‐metal‐site catalysts and…”
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Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates
Published in RSC advances (01-01-2017)“…A series of cross-linked polymer supported ionic liquids based on quaternary ammonium salts have been prepared using a facile method of radical polymerization…”
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