Search Results - "Leto, Domenick F"

Ligand-Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster by Nguyen, Thuy-Ai D, Jones, Zachary R, Leto, Domenick F, Wu, Guang, Scott, Susannah L, Hayton, Trevor W

“…The copper hydride nanocluster (NC) [Cu29Cl4H22­(Ph2phen)12]Cl (2; Ph2phen = 4,7-diphenyl-1,10-phenanthroline) was isolated cleanly, and in good yields, by…”
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Spectroscopic and Computational Investigations of a Mononuclear Manganese(IV)-Oxo Complex Reveal Electronic Structure Contributions to Reactivity by Leto, Domenick F, Massie, Allyssa A, Rice, Derek B, Jackson, Timothy A

“…The mononuclear Mn­(IV)-oxo complex [MnIV(O)­(N4py)]2+, where N4py is the pentadentate ligand N,N-bis­(2-pyridylmethyl)-N-bis­(2-pyridyl)­methylamine, has been…”
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Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex by Leto, Domenick F, Ingram, Rena, Day, Victor W, Jackson, Timothy A

“…A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is…”
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Geometric and electronic structure of a peroxomanganese(III) complex supported by a scorpionate ligand by Colmer, Hannah E, Geiger, Robert A, Leto, Domenick F, Wijeratne, Gayan B, Day, Victor W, Jackson, Timothy A

“…A monomeric Mn(II) complex has been prepared with the facially-coordinating Tp(Ph2) ligand, (Tp(Ph2) = hydrotris(3,5-diphenylpyrazol-1-yl)borate). The X-ray…”
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Geometric and Electronic Structures of Peroxomanganese(III) Complexes Supported by Pentadentate Amino-Pyridine and -Imidazole Ligands by Geiger, Robert A, Leto, Domenick F, Chattopadhyay, Swarup, Dorlet, Pierre, Anxolabéhère-Mallart, Elodie, Jackson, Timothy A

“…Three peroxomanganese(III) complexes [MnIII(O2)(mL5 2)]+, [MnIII(O2)(imL5 2)]+, and [MnIII(O2)(N4py)]+ supported by pentadentate ligands (mL5 2 =…”
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Mn K‑Edge X‑ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties by Leto, Domenick F, Jackson, Timothy A

“…Mn K-edge X-ray absorption spectroscopy (XAS) was used to gain insights into the geometric and electronic structures of [MnII(Cl)2­(Me2EBC)],…”
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Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes by Leto, Domenick F., Jackson, Timothy A.

“…Over the past 7 years, there have been a significant number of studies describing the structural and electronic properties, as well as the chemical reactivity,…”
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X-Band Electron Paramagnetic Resonance Comparison of Mononuclear Mn(IV)-oxo and Mn(IV)-hydroxo Complexes and Quantum Chemical Investigation of Mn(IV) Zero-Field Splitting by Leto, Domenick F, Massie, Allyssa A, Colmer, Hannah E, Jackson, Timothy A

“…X-band electron paramagnetic resonance (EPR) spectroscopy was used to probe the ground-state electronic structures of mononuclear Mn(IV) complexes…”
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Reaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species by Leto, Domenick F, Chattopadhyay, Swarup, Day, Victor W, Jackson, Timothy A

“…Herein we describe the chemical reactivity of the mononuclear [Mn(II)(N4py)(OTf)](OTf) (1) complex with hydrogen peroxide and superoxide. Treatment of 1 with…”
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X‑Band Electron Paramagnetic Resonance Comparison of Mononuclear MnIV-oxo and MnIV-hydroxo Complexes and Quantum Chemical Investigation of MnIV Zero-Field Splitting by Leto, Domenick F., Massie, Allyssa A., Colmer, Hannah E., Jackson, Timothy A.

“…X-band electron paramagnetic resonance (EPR) spectroscopy was used to probe the ground-state electronic structures of mononuclear MnIV complexes…”
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Electrochemical formation of Mn(III)-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands by El Ghachtouli, Sanae, Ching, H Y Vincent, Lassalle-Kaiser, Benedikt, Guillot, Régis, Leto, Domenick F, Chattopadhyay, Swarup, Jackson, Timothy A, Dorlet, Pierre, Anxolabéhère-Mallart, Elodie

“…A novel and efficient method for preparing [Mn(III)(O2)(L)](+) complexes using electrochemically generated superoxide is reported, with the reaction probed by…”
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Ligand-Exchange-Induced Growth of an Atomically Precise Cu 29 Nanocluster from a Smaller Cluster by Nguyen, Thuy-Ai D., Jones, Zachary R., Leto, Domenick F., Wu, Guang, Scott, Susannah L., Hayton, Trevor W.

“…Not provided…”
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X-Band Electron Paramagnetic Resonance Comparison of Mononuclear Mn IV -oxo and Mn IV -hydroxo Complexes and Quantum Chemical Investigation of Mn IV Zero-Field Splitting by Leto, Domenick F., Massie, Allyssa A., Colmer, Hannah E., Jackson, Timothy A.

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Biomimetic Peroxo- and Oxo-manganese Complexes: Insights into Structure and Reactivity through Kinetic, Spectroscopic, and Computational Studies by Leto, Domenick F

“…Manganese centers that react with O2 and its reduced derivatives mediate a diverse array of biologically important reactions including the detoxification of…”
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