Search Results - "Leith, Gabrielle A."
-
1
Photophysics Modulation in Photoswitchable Metal–Organic Frameworks
Published in Chemical reviews (26-08-2020)“…In this Review, we showcase the upsurge in the development and fundamental photophysical studies of more than 100 metal–organic frameworks (MOFs) as versatile…”
Get full text
Journal Article -
2
Dynamically Controlled Electronic Behavior of Stimuli‐Responsive Materials: Exploring Dimensionality and Connectivity
Published in Advanced energy materials (01-01-2022)“…Materials with dynamically controlled electronic structures (i.e., upon external stimuli) are at the forefront of the renewable energy sector with applications…”
Get full text
Journal Article -
3
Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal–Organic Frameworks
Published in Journal of the American Chemical Society (07-09-2022)“…Comparison of defect-controlled leaching-kinetics modulation of metal–organic frameworks (MOFs) and porous functionalized silica-based materials was performed…”
Get full text
Journal Article -
4
Heterometallic Metal–Organic Frameworks (MOFs): The Advent of Improving the Energy Landscape
Published in ACS energy letters (09-08-2019)“…In this Perspective, we highlight how recent studies of heterometallic metal–organic frameworks (MOFs) could lead to advances to the energy landscape. The…”
Get full text
Journal Article -
5
"Broken-hearted" carbon bowl via electron shuttle reaction: energetics and electron coupling
Published in Chemical science (Cambridge) (08-04-2021)“…Unprecedented one-step C[double bond, length as m-dash]C bond cleavage leading to opening of the buckybowl (π-bowl), that could provide access to carbon-rich…”
Get full text
Journal Article -
6
Beyond structural motifs: the frontier of actinide-containing metal-organic frameworks
Published in Chemical science (Cambridge) (02-06-2021)“…In this perspective, we feature recent advances in the field of actinide-containing metal-organic frameworks (An-MOFs) with a main focus on their electronic,…”
Get full text
Journal Article -
7
Keeping COFs in the loop
Published in Nature chemistry (01-05-2022)“…The rational synthesis of organic nanotubes and their hierarchical architectures has remained challenging. Now, one-dimensional hollow covalent organic…”
Get full text
Journal Article -
8
Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Published in Angewandte Chemie (International ed.) (06-04-2021)“…Acquiring fundamental knowledge of properties of actinide‐based materials is a necessary step to create new possibilities for addressing the current challenges…”
Get full text
Journal Article -
9
Let the light be a guide: Chromophore communication in metal-organic frameworks
Published in Nano research (01-02-2021)“…The photonic characteristics of chromophore-containing metal-organic frameworks (MOFs) have led to extensive photophysical studies in an effort to capitalize…”
Get full text
Journal Article -
10
Stimuli-Modulated Metal Oxidation States in Photochromic MOFs
Published in Journal of the American Chemical Society (16-03-2022)“…Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching between two discrete linker photoisomers via an external stimulus was probed…”
Get full text
Journal Article -
11
Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”
Published in Journal of the American Chemical Society (24-07-2019)“…Thermodynamic studies of actinide-containing metal–organic frameworks (An-MOFs), reported herein for the first time, are a step toward addressing challenges…”
Get full text
Journal Article -
12
A Metal‐Organic Framework (MOF)‐Based Multifunctional Cargo Vehicle for Reactive‐Gas Delivery and Catalysis
Published in Angewandte Chemie (International ed.) (14-03-2022)“…The efficient delivery of reactive and toxic gaseous reagents to organic reactions was studied using metal‐organic frameworks (MOFs). The simultaneous cargo…”
Get full text
Journal Article -
13
Confinement-Driven Photophysics in Cages, Covalent−Organic Frameworks, Metal–Organic Frameworks, and DNA
Published in Journal of the American Chemical Society (11-03-2020)“…Photophysics tunability through alteration of framework aperture (metal–organic framework (MOF) = variable; guest = constant) was probed for the first time in…”
Get full text
Journal Article -
14
Confinement‐Driven Photophysics in Hydrazone‐Based Hierarchical Materials
Published in Angewandte Chemie International Edition (09-01-2023)“…Confinement‐imposed photophysics was probed for novel stimuli‐responsive hydrazone‐based compounds demonstrating a conceptual difference in their behavior…”
Get full text
Journal Article -
15
f‐block MOFs: A Pathway to Heterometallic Transuranics
Published in Angewandte Chemie International Edition (26-01-2023)“…A novel series of heterometallic f‐block‐frameworks including the first examples of transuranic heterometallic 238U/239Pu‐metal–organic frameworks (MOFs) and a…”
Get full text
Journal Article -
16
Photoresponsive frameworks: energy transfer in the spotlight
Published in Faraday discussions (15-10-2021)“…In this paper, spiropyran-containing metal- and covalent-organic frameworks (MOFs and COFs, respectively) are probed as platforms for fostering photochromic…”
Get more information
Journal Article -
17
“Boarding-Up”: Radiation Damage and Radionuclide Leaching Kinetics in Linker-Capped Metal–Organic Frameworks
Published in Inorganic chemistry (06-01-2020)“…For the first time, we report the ability to control radionuclide species release kinetics in metal–organic frameworks (MOFs) as a function of postsynthetic…”
Get full text
Journal Article -
18
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
Published in Angewandte Chemie International Edition (06-04-2020)“…The effect of donor (D)–acceptor (A) alignment on the materials electronic structure was probed for the first time using novel purely organic porous…”
Get full text
Journal Article -
19
Stack the Bowls: Tailoring the Electronic Structure of Corannulene‐Integrated Crystalline Materials
Published in Angewandte Chemie International Edition (27-08-2018)“…We report the first examples of purely organic donor–acceptor materials with integrated π‐bowls (πBs) that combine not only crystallinity and high surface…”
Get full text
Journal Article -
20
Frontispiece: Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Published in Angewandte Chemie International Edition (06-04-2021)“…Graphene The on‐surface synthesis of nitrogen‐doped Kagome graphene is reported by Rémy Pawlak, Shi‐Xia Liu, Ernst Meyer et al. in their Communication on page…”
Get full text
Journal Article