Search Results - "Leinonen, Timo"
-
1
Modeling the Stabilization of Surface Defects by Donors in Ziegler–Natta Catalyst Support
Published in Journal of physical chemistry. C (06-03-2014)“…We describe a concept for modeling structural defects in crystalline magnesium dichloride used as a support in the Ziegler–Natta polymerization catalysis. The…”
Get full text
Journal Article -
2
Stabilization of magnesium dichloride surface defects by mono- and bidentate donors
Published in Surface science (01-05-2015)“…We evaluate the stabilization of magnesium dichloride surfaces by mono- and bidentate electron donors typically used in heterogeneous Ziegler–Natta olefin…”
Get full text
Journal Article -
3
A Study of Ziegler-Natta Propylene Polymerization Catalysts by Spectroscopic Methods
Published in Materials (03-05-2017)“…Ziegler-Natta polymerization catalysts were characterized by a complex of surface- and bulk-sensitive methods (DRIFTS, XPS, ESR, and XAS = XANES + EXAFS). A…”
Get full text
Journal Article -
4
Suomen ja Venäjän metsänkäsittelyohjeiden vertailu
Published in Metsätieteen aikakauskirja (01-01-2012)Get full text
Journal Article -
5
Alkylation of titanium tetrachloride on magnesium dichloride in the presence of Lewis bases
Published in Journal of catalysis (01-09-2017)“…[Display omitted] •All relevant catalyst components are included in the periodic calculations.•TiCl4 prefers octahedral coordination on both (104) and (110)…”
Get full text
Journal Article -
6
Modeling Coadsorption of Titanium Tetrachloride and Bidentate Electron Donors on Magnesium Dichloride Support Surfaces
Published in Journal of physical chemistry. C (04-12-2014)“…Coadsorption of titanium tetrachloride and two representative bidentate electron donors on magnesium dichloride surfaces is systematically studied by means of…”
Get full text
Journal Article -
7
Polyethylenimines: Multidentate Electron Donors for Ziegler–Natta Catalysts
Published in Journal of physical chemistry. C (26-10-2017)“…Polyethylenimines, polymers bearing amino functionalities, are studied for the first time as internal electron donors for Ziegler–Natta catalysts. An advantage…”
Get full text
Journal Article -
8
Stabilization of magnesium dichloride surface defects by mono- and bidentate donors
Published in Surface science (01-05-2015)“…We evaluate the stabilization of magnesium dichloride surfaces by mono- and bidentate electron donors typically used in heterogeneous Ziegler-Natta olefin…”
Get full text
Journal Article -
9
Modeling of Substitutional Defects in Magnesium Dichloride Polymerization Catalyst Support
Published in Journal of physical chemistry. C (12-04-2012)“…We evaluate methods and models for the periodic quantum chemical treatment of defects in MgCl2 polymerization catalyst support and demonstrate the…”
Get full text
Journal Article -
10
Microstructure control of magnesium dichloride crystallites by electron donors: The effect of methanol
Published in Journal of molecular catalysis. A, Chemical (04-01-2011)“…The shapes of magnesium dichloride crystallites can be controlled by electron donors, as demonstrated by quantum chemical calculations using methanol as a…”
Get full text
Journal Article -
11
Structural studies on a solid self-supported Ziegler–Natta-type catalyst for propylene polymerization
Published in Journal of molecular catalysis. A, Chemical (14-12-2007)“…The article describes structural studies on a solid MgCl 2-based TiCl 4 Ziegler–Natta catalyst for propylene polymerization prepared via emulsion technique…”
Get full text
Journal Article -
12
Particle growth and fragmentation of solid self-supported Ziegler–Natta-type catalysts in propylene polymerization
Published in Journal of molecular catalysis. A, Chemical (18-08-2009)“…The article describes fragmentation studies on solid Ziegler–Natta-type catalysts prepared via emulsion technique. Propylene gas-phase polymerizations in a…”
Get full text
Journal Article -
13
Complex formation and characterization of MgCl 2/2-(2-ethylhexyloxy)ethanol adduct
Published in Inorganica Chimica Acta (2011)“…Complex formation of MgCl 2 with 2-(2-ethylhexyloxy)ethanol was studied with IR and NMR spectroscopic methods and with molecular modeling in order to find out…”
Get full text
Journal Article -
14
Solid state 13C NMR characterisation study on fourth generation Ziegler–Natta catalysts
Published in Solid state nuclear magnetic resonance (01-05-2012)“…In this study, solid state 13C NMR spectroscopy was utilised to characterize and identify the metal–ester coordination in active fourth generation (phthalate)…”
Get full text
Journal Article -
15
Complex formation and characterization of MgCl2/2-(2-ethylhexyloxy)ethanol adduct
Published in Inorganica Chimica Acta (31-05-2011)Get full text
Journal Article -
16
Forest regeneration in Northern and Northwestern Russia in 1993–2004—Methods, results and development needs
Published in Forest ecology and management (20-03-2008)“…Concern about the sustainability of forestry in Russia has increased, especially among the end-users of forest products in Europe. A key factor in sustainable…”
Get full text
Journal Article -
17
Forest regeneration in Northern and Northwestern Russia in 1993-2004-Methods, results and development needs
Published in Forest ecology and management (2008)Get full text
Journal Article -
18
Mn doping of the Ziegler-Natta PP catalyst support material
Published in Journal of molecular catalysis. A, Chemical (1996)“…Preliminary tests have shown that if MnCl 2 is used as a support material a polypropylene with a low molecular weight is produced. The activity of these…”
Get full text
Journal Article