Search Results - "Leech, Matthew C"
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1
Electrosynthesis Using Carboxylic Acid Derivatives: New Tricks for Old Reactions
Published in Accounts of chemical research (21-01-2020)“…Conspectus Electrosynthetic organic chemistry is an old discipline that takes its root in Faraday’s seminal works. The field has a rich history and is in the…”
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2
A practical guide to electrosynthesis
Published in Nature reviews. Chemistry (01-04-2022)“…Organic electrosynthesis is an old and rich discipline. By exploiting the cheapest and greenest source of electrons, electricity itself, electrolysis has been…”
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3
Room-Temperature Cu(II) Radical-Triggered Alkyne C–H Activation
Published in JACS Au (22-11-2021)“…A dimeric Cu(II) complex [Cu(II)2L2(μ2-Cl)Cl] (1) built from an asymmetric tridentate ligand…”
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4
Electrosynthesis of Stabilized Diazo Compounds from Hydrazones
Published in Organic letters (01-07-2022)“…An electrochemical synthesis of diazo compounds from hydrazones in yields as high as 99% was performed. This method was elaborated as a useful synthetic method…”
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5
eFluorination of Activated Alcohols Using Collidinium Tetrafluoroborate
Published in Organic letters (12-04-2024)“…Tertiary C–F bonds are important structural designs; however, they suffer from challenging synthesis. Current methodologies use corrosive amine-HF salts or…”
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6
Ligand dynamics and reactivity of a non-innocent homoleptic iron complex (N,N)2Fe stabilized by phen-type ligands
Published in Journal of organometallic chemistry (15-10-2023)“…•A low-valent non-innocent iron complex supported by phen-type ligands efficiently promotes reductive coupling of heteroaryl halides;•High efficiency of this…”
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7
Electrochemical Isothiocyanation of Primary Amines
Published in Organic letters (24-02-2023)“…Isothiocyanates are ubiquitous building blocks used across the fields. Nevertheless, their classical syntheses very often rely on the use of toxic and…”
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8
Economical, Green, and Safe Route Towards Substituted Lactones by Anodic Generation of Oxycarbonyl Radicals
Published in Angewandte Chemie International Edition (04-11-2019)“…A new electrochemical methodology has been developed for the generation of oxycarbonyl radicals under mild and green conditions from readily available…”
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9
eHydrogenation: Hydrogen‐free Electrochemical Hydrogenation
Published in Angewandte Chemie International Edition (18-09-2023)“…Hydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various…”
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10
eFluorination Using Cheap and Readily Available Tetrafluoroborate Salts
Published in Organic letters (10-03-2023)“…A practical electrochemical method for the rapid, safer, and mild synthesis of tertiary hindered alkyl fluorides from carboxylic acids has been developed…”
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11
Anodic Oxidation of Aminotetrazoles: A Mild and Safe Route to Isocyanides
Published in Organic letters (17-12-2021)“…A new electrochemical method for the preparation of isocyanides from easily accessible aminotetrazole derivatives has been developed, which tolerates an…”
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12
Anodic Oxidation of Dithiane Carboxylic Acids: A Rapid and Mild Way to Access Functionalized Orthoesters
Published in Organic letters (15-05-2020)“…A new electrochemical methodology has been developed for the preparation of a wide variety of functionalized orthoesters under mild and green conditions from…”
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13
Supporting-Electrolyte-Free Anodic Oxidation of Oxamic Acids into Isocyanates: An Expedient Way to Access Ureas, Carbamates, and Thiocarbamates
Published in Organic process research & development (17-12-2021)“…We report a new electrochemical supporting-electrolyte-free method for synthesizing ureas, carbamates, and thiocarbamates via the oxidation of oxamic acids…”
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14
Structural and Electronic Control of the Bidentate 1‐(2‐pyridyl)benzotriazole Ligand in Copper Chemistry with Application to Catalysis in the A3 Coupling Reaction
Published in Chemistry : a European journal (01-03-2021)“…The hybrid bidentate 1‐(2‐pyridyl)benzotriazole (pyb) ligand was introduced into 3d transition metal catalysis. Specifically, [CuII(OTf)2(pyb)2]⋅2 CH3CN (1)…”
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15
Structural and Electronic Control of the Bidentate 1-(2-pyridyl)benzotriazole Ligand in Copper Chemistry with Application to Catalysis in the A 3 Coupling Reaction
Published in Chemistry : a European journal (01-03-2021)“…The hybrid bidentate 1-(2-pyridyl)benzotriazole (pyb) ligand was introduced into 3d transition metal catalysis. Specifically, [Cu (OTf) (pyb) ]⋅2 CH CN (1)…”
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16
eCyanation Using 5‑Aminotetrazole As a Safer Electrophilic and Nucleophilic Cyanide Source
Published in JACS Au (25-11-2024)“…An electrochemical method for carrying out safer cyanation reactions is reported. The use of 5-aminotetrazole as a cyanide source enabled the successful…”
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17
eHydrogenation: Hydrogen‐free Electrochemical Hydrogenation
Published in Angewandte Chemie (18-09-2023)“…Hydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various…”
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Journal Article -
18
Economical, Green, and Safe Route Towards Substituted Lactones by Anodic Generation of Oxycarbonyl Radicals
Published in Angewandte Chemie (04-11-2019)“…A new electrochemical methodology has been developed for the generation of oxycarbonyl radicals under mild and green conditions from readily available…”
Get full text
Journal Article -
19
eHydrogenation: Electrochemical Hydrogen-free hydrogenation
Published in Angewandte Chemie International Edition (04-08-2023)“…Hydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various…”
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