Search Results - "Lee, Yong‐Min"
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Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen
Published in Chemistry : a European journal (06-04-2018)“…Hydrogen peroxide, which is a green oxidant and fuel, is produced by a two‐electron/two‐proton reduction of dioxygen, two‐electron/two‐proton oxidation of…”
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Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes
Published in Accounts of chemical research (15-04-2014)“…Mononuclear nonheme iron enzymes generate high-valent iron(IV)-oxo intermediates that effect metabolically important oxidative transformations in the catalytic…”
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3
Fuel Production from Seawater and Fuel Cells Using Seawater
Published in ChemSusChem (23-11-2017)“…Seawater is the most abundant resource on our planet and fuel production from seawater has the notable advantage that it would not compete with growing demands…”
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Hydrogen Atom Transfer Reactions of Mononuclear Nonheme Metal–Oxygen Intermediates
Published in Accounts of chemical research (18-09-2018)“…Conspectus Molecular oxygen (O2), the greenest oxidant, is kinetically stable in the oxidation of organic substrates due to its triplet ground state. In…”
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Mechanisms of Two‐Electron versus Four‐Electron Reduction of Dioxygen Catalyzed by Earth‐Abundant Metal Complexes
Published in ChemCatChem (09-01-2018)“…The two‐electron reduction of dioxygen with two protons produces hydrogen peroxide, which is directly used as a liquid fuel in hydrogen peroxide fuel cells,…”
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6
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates
Published in Chemistry : a European journal (01-12-2015)“…Redox‐inactive metal ions and Brønsted acids that function as Lewis acids play pivotal roles in modulating the redox reactivity of metal–oxygen intermediates,…”
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Mechanisms of catalytic reduction of CO2 with heme and nonheme metal complexes
Published in Chemical science (Cambridge) (28-07-2018)“…The catalytic conversion of CO 2 into valuable chemicals and fuels has attracted increasing attention, providing a promising route for mitigating the…”
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8
Photocatalytic Oxygenation Reactions Using Water and Dioxygen
Published in ChemSusChem (06-09-2019)“…Water (H2O) is the most environmentally benign reductant and is oxidized to evolve dioxygen (O2)—the greenest oxidant—in photosystem II. This Minireview…”
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Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes
Published in Coordination chemistry reviews (01-03-2017)“…•Recent advances in the O2-activation by biomimetic complexes are described.•Synthetic and mechanistic developments of O2-activation processes are…”
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10
Crucial Roles of a Pendant Imidazole Ligand of a Cobalt Porphyrin Complex in the Stoichiometric and Catalytic Reduction of Dioxygen
Published in Angewandte Chemie International Edition (22-08-2022)“…A cobalt porphyrin complex with a pendant imidazole base ([(L1)CoII]) is an efficient catalyst for the homogeneous catalytic two‐electron reduction of dioxygen…”
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Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts
Published in Journal of the American Chemical Society (27-01-2016)“…We report a remarkable Brønsted acid effect in the epoxidation of olefins by nonheme manganese catalysts and aqueous hydrogen peroxide. More specifically, a…”
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12
Mechanical Surface Modification of Lithium Metal: Towards Improved Li Metal Anode Performance by Directed Li Plating
Published in Advanced functional materials (11-02-2015)“…The effect of mechanical surface modification on the performance of lithium (Li) metal foil electrodes is systematically investigated. The applied micro‐needle…”
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13
Redox catalysis via photoinduced electron transfer
Published in Chemical science (Cambridge) (26-04-2023)“…This perspective article highlights redox catalysis of organic and inorganic molecules photoinduced electron transfer, which is well exploited for a number of…”
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14
Deuterium kinetic isotope effects as redox mechanistic criterions
Published in Bulletin of the Korean Chemical Society (01-12-2021)“…This account article focuses on deuterium kinetic isotope effects (KIEs) used as criterions to elucidate redox mechanisms including proton‐, hydrogen‐ and…”
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15
Molecular Photocatalytic Water Splitting by Mimicking Photosystems I and II
Published in Journal of the American Chemical Society (19-01-2022)“…In nature, water is oxidized by plastoquinone to evolve O2 and form plastoquinol in Photosystem II (PSII), whereas NADP+ is reduced by plastoquinol to produce…”
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16
Amphoteric reactivity of metal–oxygen complexes in oxidation reactions
Published in Coordination chemistry reviews (15-06-2018)“…•Electrophilic reactivity of metal–oxygen complexes.•Nucleophilic reactivity of metal–oxygen complexes.•Tuning the amphoteric reactivity of metal–oxygen…”
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17
Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)–peroxo complexes
Published in Nature chemistry (01-10-2014)“…Redox-inactive metal ions that function as Lewis acids play pivotal roles in modulating the reactivity of oxygen-containing metal complexes and metalloenzymes,…”
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Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C–H Bond Activation Reactions
Published in Journal of the American Chemical Society (07-08-2019)“…We report that Mn(IV)-oxo porphyrin complexes, MnIV(O)(TMP) (1) and MnIV(O)(TDCPP) (2), are capable of activating the C–H bonds of hydrocarbons, including…”
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Immobilization of Molecular Catalysts for Enhanced Redox Catalysis
Published in ChemCatChem (24-04-2018)“…In the homogenous phase, redox catalysts are often deactivated by bimolecular reactions. For example, the charge‐separated state of photoredox catalysts…”
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Potential risks from UV/H2O2 oxidation and UV photocatalysis: A review of toxic, assimilable, and sensory-unpleasant transformation products
Published in Water research (Oxford) (15-09-2018)“…UV based advanced oxidation processes (UV-AOPs) that efficiently eliminate organic pollutants during water treatment have been the subject of numerous…”
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