Search Results - "Lebeau, Estelle L"
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1
Mechanistic Implications of Proton Transfer Coupled to Electron Transfer
Published in Journal of the American Chemical Society (31-10-2001)“…The kinetics of electron transfer for the reactions cis-[RuIV(bpy)2(py)(O)]2+ + H+ + [OsII(bpy)3]2+ ⇌ cis-[RuIII(bpy)2(py)(OH)]2+ + [OsIII(bpy)3]3+ and…”
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2
Electronic Structure of the Water Oxidation Catalyst cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+, The Blue Dimer
Published in Inorganic chemistry (06-02-2012)“…The first designed molecular catalyst for water oxidation is the “blue dimer”, cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+. Although there is experimental…”
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3
Oxidation of Benzyl Alcohol by a Dioxo Complex of Ruthenium(VI)
Published in Inorganic chemistry (03-05-1999)“…The kinetics and mechanism of reduction of trans-[RuVI(tpy)(O)2(L)]2+ (L is H2O or CH3CN; tpy is 2,2‘:6‘,2‘ ‘-terpyridine) by benzyl alcohol have been studied…”
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4
Synthesis, Characterization, and Laser Flash Photolysis Reactivity of a Carbonmonoxy Heme Complex
Published in Inorganic chemistry (25-08-2003)“…We present here the synthesis, characterization, and flash photolysis study of [(F8TPP)FeII(CO)(THF)] (1) {F8TPP =…”
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5
Water Oxidation by [(tpy)(H2O)2RuIIIORuIII(H2O)2(tpy)]4
Published in Inorganic chemistry (14-12-1998)“…The complex [(tpy)(C2O4)RuIIIORuIII(C2O4)(tpy)]·8H2O (1·8H2O) (tpy is 2,2‘:6‘,2‘‘-terpyridine) has been prepared and characterized by X-ray crystallography and…”
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6
Water Oxidation by [(tpy)(H(2)O)(2)Ru(III)ORu(III)(H(2)O)(2)(tpy)](4+)
Published in Inorganic chemistry (14-12-1998)“…The complex [(tpy)(C(2)O(4))Ru(III)ORu(III)(C(2)O(4))(tpy)].8H(2)O (1.8H(2)O) (tpy is 2,2':6',2"-terpyridine) has been prepared and characterized by X-ray…”
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7
Synthesis and Characterization of Reduced Heme and Heme/Copper Carbonmonoxy Species
Published in Inorganic chemistry (05-05-2003)“…Carbon monoxide readily binds to heme and copper proteins, acting as a competitive inhibitor of dioxygen. As such, CO serves as a probe of protein metal active…”
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8
Lanthanide-Cyclodextrin Complexes as Probes for Elucidating Optical Purity by NMR Spectroscopy
Published in Journal of the American Chemical Society (01-06-1994)“…A multidentate ligand is bonded to cyclodextrins by the reaction of diethylenetriaminepentaacetic dianhydride with 6-mono- and 2-mono(ethylenediamine)…”
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9
Instability of the oxidation catalysts [Os III(tpy)(bpy)(py)] 3+ and [Os III(bpy) 3] 3+ in alkaline solution
Published in Journal of molecular catalysis. A, Chemical (01-04-2004)“…The Os(III) complexes [Os III(tpy)(bpy)(py)] 3+ and [Os III(bpy) 3] 3+ (bpy: 2,2′-bipyridine, py: pyridine, tpy: 2,2′,2′′-terpyridine) are unstable toward…”
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10
Electronic Structure of the Water Oxidation Catalyst cis , cis -[(bpy) 2 (H 2 O)Ru III ORu III (OH 2 )(bpy) 2 ] 4+ , The Blue Dimer
Published in Inorganic chemistry (18-01-2012)“…The first designed molecular catalyst for water oxidation is the “blue dimer”, cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+. Although there is experimental…”
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