Search Results - "Le Poul, P"
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γ-Methylene chalcogenapyrans and benzopyrans as proaromatic donors in “push–pull” Fischer type carbene complexes: Influences of chalcogen atom and chain length on the electronic and N.L.O. properties of these molecules
Published in Journal of organometallic chemistry (01-11-2005)“…N.L.O. properties of a new class of “push–pull” Fischer type carbene complexes bearing γ-methylene chalcogenapyran and benzopyran nucleus as proaromatic donors…”
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Reactivity of carbanions of Fischer-type carbene complexes with pyrylium salts. Synthesis and characterization of new γ-methylenepyran carbene complexes via an addition–oxidation–deprotonation process
Published in Tetrahedron (09-09-2002)“…The condensation reaction between γ-unsubstituted pyrylium salts and carbanions of Fischer-type carbene complexes allowed the synthesis of new γ-methylenepyran…”
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Synthesis of new highly conjugated bis-(4 H-pyrans) involving electron rich polyene linkage, by Pd° catalytic coupling of γ-methylenepyran Fischer-type carbene complexes
Published in Tetrahedron letters (20-05-2002)“…Self dimerisation of methylenepyran carbene complexes affords bis-pyrans containing electron rich polyene linkage. The cyclic voltammograms of these new donors…”
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Synthesis of new highly conjugated bis-(4H-pyrans) involving electron rich polyene linkage, by Pd degrees catalytic coupling of gamma-methylenepyran Fischer-type carbene complexes
Published in Tetrahedron letters (20-05-2002)“…Self dimerisation of which lenepyran carbene complexes affords bis-pyrans containing electron rich polyene linkage. The cyclic voltammograms of these new…”
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Easy synthesis of heterocyclic carbene complexes by activation of chalcogenopyrones and benzopyrones to pyrylium salts and subsequent addition of carbanion of methoxy(methyl)pentacarbonyltungsten carbene complex
Published in Journal of organometallic chemistry (15-11-2007)“…Methylenechalcogenopyran and benzopyran Fischer carbene complexes are obtained from commercially available chalcogenopyrones and benzopyrones and carbanion of…”
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Selective reactivity of diamino Fischer-type carbene complexes towards 2,6-disubstituted and 2,4,6-trisubstituted pyrylium salts and 2,4,6-trichloro-1,3,5-triazine
Published in Journal of organometallic chemistry (01-08-2007)“…The reaction of alkoxy Fischer-type carbene complexes with diamines gave amino carbenes with pendent NH 2. The free amino group of these complexes which could…”
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Convenient synthesis of dithiafulvene carbene complexes as potential precursors of extended TTF
Published in Tetrahedron letters (11-10-2004)“…[Display omitted] The condensation of α-carbanion of Fischer-type carbene complex with 2-thiomethyl-1,3-dithiolium salts 1 gave new heterocyclic organometallic…”
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Synthesis of electron donor–acceptor polyunsaturated methylenepyran Fischer type carbene complexes: dynamic 1H-NMR study and solvatochromic properties
Published in Journal of organometallic chemistry (01-04-2001)“…Condensation of α and γ methylenepyran aldehydes with the Fischer carbene complexes (CO) 5MC(OCH 3)Me (M=Cr, W) or (CO) 5WC(OCH 3)CHCH–CH 3 in the presence…”
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1,2 and 1,6 Additions of Lithium Reagents to γ-Methylenepyran Fischer-Type Carbene Complexes; Evolution of the 1,2 and 1,6 Adducts to Unsaturated Carbene Complexes Indirectly Stabilized by a Heteroatom, and to Pyranylidene Carbene Complexes
Published in European journal of organic chemistry (01-02-2000)“…1,2 and 1,6 additions of lithium reagents to γ‐methylenepyran Fischer‐type carbene complexes are described. The 1,2 adducts obtained from alkynyllithium…”
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Reactivity of carbanions of Fischer-type carbene complexes with pyrylium salts. Synthesis of new γ-methylenepyran carbene complexes via an addition-oxidation-deprotonation process
Published in Tetrahedron letters (12-02-1998)“…The condensation reaction between γ-unsubstituted pyrylium salts and carbanions of Fischer-type carbene complexes allowed the synthesis of new γ-methylenepyran…”
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Reaction of carbanion of Fischer-type carbene complexes with pyrylium salts. One pot substituted benzophenones formation by subsequent cyclization and double hydrogen β-elimination
Published in Journal of organometallic chemistry (30-10-1997)“…Carbanions of Fischer-type carbene complex react with pyrylium salts. The unstable dienone formed gives substituted benzophenones after ring-closure and…”
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