Search Results - "Le Borgne, Guy"

Mechanism of Alkyne Insertion into the Ru−C Bonds of Orthoruthenated Compounds Featuring Similarity of the Ru(II) and Pd(II) Reactions by Ferstl, Wolfgang, Sakodinskaya, Inna K, Beydoun-Sutter, Nohma, Le Borgne, Guy, Pfeffer, Michel, Ryabov, Alexander D

“…The pseudo-first-order rate constants k obs for the reaction between the ring-substituted orthoruthenated N,N-dimethylbenzylamines…”
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Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the Pd-C bonds of cyclopalladated amines followed by subsequent ring closure by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Stepwise insertion of one, two, and three alkyne molecules into the Pd-C bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Formal C-C triple-bond splitting in an organopalladium compound by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Insertion of alkynes into the palladium-carbon bond of palladacycles. Mechanistic information from high-pressure kinetic and x-ray structural data by Ryabov, A. D, Van Eldik, Rudi, Le Borgne, Guy, Pfeffer, Michel

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Reactivity of cyclopalladated compounds. 28. Alkyne reactions with the cyclopalladated 8-methylquinoline ligand. Synthesis of novel heterocyclic compounds with a bridgehead nitrogen by Pfeffer, Michel, Rotteveel, Marc A, Le Borgne, Guy, Fischer, Jean

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Preparation and structure of a mixed niobium(I) isocyanide carbonyl complex with a bent C-N-C linkage [Erratum to document cited in CA115(6):63353f] by Aharonian, Ghazar, Hubert-Pfalzgraf, Liliane G, Zaki, Abdenasser, Le Borgne, Guy

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Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-NMe2C6H4CH(SiMe3)] monoanion. Molecular structure of {2-[1-(S)-(dimethylamino)ethyl]phenyl}[2-(dimethylamino)-α-(trimethylsilyl)benzyl]palladium(II) by MAASSARANI, F, PFEFFER, M, LE BORGNE, G

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Insertion of 3,3-dimethylcyclopropenes into the Pd-C bond of cyclopalladated dimethylbenzylamine, leading to C-C bond cleavage or cyclopropyl ring retention. X-ray crystal and molecular structure of [Pd{C(CO2Me)CMe2CHC6H4CH2NMe2}pyCl] by MAASSARANI, F, PFEFFER, M, LE BORGNE, G, GRANDJEAN, D

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Synthesis and molecular and crystal structure of bis(borane)cyclenphosphorane. First stable compound with a bipyramidally surrounded element having two quaternarized apical nitrogen atoms by DUPART, J.-M, LE BORGNE, G, PACE, S, RIESS, J. G

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Study of the amination reaction of the coordinated cyclopentadienyl ring in (.eta.5-Cp)FeL1L2X derivatives. Crystal and molecular structure of (.eta.5-C5H4NEt2)Fe(CO)[PhP(OEt)2]Br by Brun, Pierre, Vierling, Pierre, Riess, Jean G, Le Borgne, Guy

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A novel olefin bridged dinuclear arylpalladium compound. X-ray crystal structure of [cyclic] [NMe2CH2C6H4Pd-.mu.-{C(CF3):C(CF3)C(CF3):C(CF3)}PdCH(SiMe3)C6H4NMe2] by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Wehman, Erik, Van Koten, Gerard

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Reactivity of cyclopalladated compounds. 23. Formal carbon-carbon triple-bond splitting in an organopalladium compound by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Reaction of cyclopalladated compounds. 15. Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the palladium-carbon bonds of cyclopalladated amines followed by ring closure by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Reaction of cyclopalladated compounds Part 16. Stepwise insertion of one, two, and three alkyne molecules into the palladium-carbon bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy

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Preparation and structure of a mixed niobium(I) isocyanide carbonyl complex with a bent C-N-C linkage by Aharonian, Ghazar, Hubert-Pfalzgraf, Liliane G, Zaki, Abdenasser, Le Borgne, Guy

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Reactivity of cyclopalladated compounds. Part 12. Insertion of 3,3-dimethylcyclopropenes into the palladium-carbon bond of cyclopalladated dimethylbenzylamine, leading to carbon-carbon bond cleavage or cyclopropyl ring retention. X-ray crystal and molecular structure of [cyclic][Pd[C(CO2Me)CMe2CHC6H4CH2NMe2]pyCl] by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Grandjean, Daniel

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Synthesis and molecular and crystal structure of bis(borane)cyclenphosphorane. First stable compound with a bipyramidally surrounded element having two quaternized apical nitrogen atoms by Dupart, Jean-Marc, Le Borgne, Guy, Pace, Simonne, Riess, Jean G.

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Reactivity of cyclopalladated compounds. 13. Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-Me2NC6H4CH(SiMe3)] monoanion. Molecular structure of [2-[1-(S)-(dimethylamino)ethyl]phenyl][2-(dimethylamino)-.alpha.-(trimethylsilyl)benzyl]palladium(II) by Maassarani, Fida, Pfeffer, Michel, Le Borgne, Guy, Jastrzebski, Johann T. B. H, Van Koten, Gerard

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Unexpected formation and molecular structure of a stable dinuclear rhodium compound with a single chloro bridge, [cyclic]-(CO)2ClRh(.mu.-Cl)Rh(CO)[C6H5P(OCMe2CH2)2NH] by Wachter, Joachim, Jeanneaux, Francois, Le Borgne, Guy, Riess, Jean G

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