Search Results - "Laursen, Siris"
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Catalytic site seeing
Published in Nature chemistry (01-05-2022)“…Understanding how surface structure affects catalyst selectivity is limited by the ability to synthesize atomically precise active-site ensembles. Now, by…”
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Selective and Stable Non-Noble-Metal Intermetallic Compound Catalyst for the Direct Dehydrogenation of Propane to Propylene
Published in Journal of the American Chemical Society (31-10-2018)“…A non-noble intermetallic compound catalyst consisting of Ni3Ga nanoparticles supported on Al2O3 that exhibits high selectivity (∼94%), comparable activity…”
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The Origin of the Special Surface and Catalytic Chemistry of Ga-Rich Ni3Ga in the Direct Dehydrogenation of Ethane
Published in ACS catalysis (01-11-2019)“…Synthesis of kinetically trapped, alumina-supported Ni3Ga nanoparticles with particle surface composition partially controlled by off-stoichiometric Ni:Ga…”
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Controlling Selectivity and Stability in the Hydrocarbon Wet-Reforming Reaction Using Well-Defined Ni + Ga Intermetallic Compound Catalysts
Published in ACS catalysis (21-08-2020)“…In this study, we present the use of compositionally and structurally well-defined, oxide-supported nanoparticle Ni + Ga intermetallic compound (IMC) catalysts…”
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Oxidation catalysis by oxide-supported Au nanostructures: the role of supports and the effect of external conditions
Published in Physical review letters (14-07-2006)“…Oxide-supported Au nanostructures are promising low-temperature oxidation catalysts. It is generally observed that Au supported on reducible oxides is more…”
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Strong Chemical Interactions Between Au and Off-Stoichiometric Defects on TiO2 as a Possible Source of Chemical Activity of Nanosized Au Supported on the Oxide
Published in Journal of physical chemistry. C (23-04-2009)“…The effect of off-stoichiometric point defects (oxygen vacancies or extra oxygen atoms at the metal−oxide interface) on oxide surfaces on the chemical activity…”
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Dynamic hybrid neural network model of an industrial fed-batch fermentation process to produce foreign protein
Published in Computers & chemical engineering (01-01-2007)“…An industrial pharmaceutical company has provided industrial pilot scale fed-batch data from a biological process used to produce a foreign protein from…”
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Proteomes reveal metabolic capabilities of Yarrowia lipolytica for biological upcycling of polyethylene into high-value chemicals
Published in mSystems (21-12-2023)“…Sustainable processes for biological upcycling of plastic wastes in a circular bioeconomy are needed to promote decarbonization and reduce environmental…”
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Partially oxidized gold nanoparticles: A catalytic base-free system for the aerobic homocoupling of alkynes
Published in Journal of catalysis (01-06-2014)“…[Display omitted] •Gold nanoparticles catalyze the aerobic homocoupling of alkynes without added base.•Basic O atoms generated by O2 dissociation assist alkyne…”
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Effect of bulk and surface composition of Ni + Ga intermetallic compound catalysts in propane steam/wet reforming: Origins of nearly ideal experimental product selectivity
Published in Journal of catalysis (01-01-2023)“…[Display omitted] •Fundamental understanding of the control of the fate of atomic H in wet reforming to enhance H2 selectivity.•Fundamental insights into the…”
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Insights into Elevated-Temperature Photocatalytic Reduction of CO2 by H2O
Published in Journal of physical chemistry. C (19-04-2018)“…Photocatalytic reduction of CO2 for the production of synthesis gas, hydrocarbons, alcohols, or aldehydes from only CO2, H2O, and solar radiation may be a…”
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Control of surface reactivity towards unsaturated C C bonds and H over Ni-based intermetallic compounds in semi-hydrogenation of acetylene
Published in Journal of catalysis (01-04-2019)Get full text
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Trends in the Surface and Catalytic Chemistry of Transition-Metal Ceramics in the Deoxygenation of a Woody Biomass Pyrolysis Model Compound
Published in ACS catalysis (05-05-2017)“…The general surface chemical reactivity, surface reaction site nature, and van der Waals dispersion interaction capability of 10 transition metal ceramics were…”
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Controlling the surface chemistry towards unsaturated carbon-carbon bonds over non-oxide transition metal ceramics: Trends in adsorption and distortion energies and adsorbate “activation”
Published in Surface science (01-08-2019)“…•The complicated surface chemistry of TM ceramics may be stemmed from their compositional complexity and flexibility.•An orbital overlap effect were found to…”
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Control of surface reactivity towards unsaturated CC bonds and H over Ni-based intermetallic compounds in semi-hydrogenation of acetylene
Published in Journal of catalysis (01-04-2019)“…[Display omitted] •A special compositional space within intermetallic compound has been identified.•Orbital overlap was a critical parameter in dictating…”
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Insights into Elevated-Temperature Photocatalytic Reduction of CO 2 by H 2 O
Published in Journal of physical chemistry. C (19-04-2018)Get full text
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Control of Selectivity through a New Hydrogen-Transfer Mechanism in Photocatalytic Reduction Reactions: Electronically Relaxed Neutral H and the Role of Electron–Phonon Coupling
Published in The journal of physical chemistry letters (15-08-2019)“…Controlling the fate of hydrogen in photocatalytic synthesis reactions has been an ongoing challenge in CO2 reduction by H2O and nitrogen fixation efforts. Our…”
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The Origin of the Special Surface and Catalytic Chemistry of Ga-Rich Ni 3 Ga in the Direct Dehydrogenation of Ethane
Published in ACS catalysis (01-11-2019)Get full text
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Making C–C Bonds with Gold: Identification of Selective Gold Sites for Homo- and Cross-Coupling Reactions between Iodobenzene and Alkynes
Published in Journal of physical chemistry. C (29-11-2012)“…The nature of the active sites involved in the gold catalyzed Sonogashira cross-coupling reaction between iodobenzene and phenylacetylene, and in the…”
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