Search Results - "Lara‐Sánchez, Agustín"
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1
Screening and Preliminary Biochemical and Biological Studies of [RuCl(p‑cymene)(N,N‑bis(diphenylphosphino)-isopropylamine)][BF4] in Breast Cancer Models
Published in ACS omega (20-08-2019)“…Breast cancer is the second leading cause of cancer death worldwide. Despite progress in drug discovery, identification of the correct population is the…”
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2
Fast Addition of s-Block Organometallic Reagents to CO 2 -Derived Cyclic Carbonates at Room Temperature, Under Air, and in 2-Methyltetrahydrofuran
Published in ChemSusChem (06-05-2021)“…Fast addition of highly polar organometallic reagents (RMgX/RLi) to cyclic carbonates (derived from CO as a sustainable C1 synthon) has been studied in…”
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3
An Unprecedented Hybrid Scorpionate/Cyclopentadienyl Ligand
Published in Journal of the American Chemical Society (11-02-2004)“…An efficient method for the preparation of the first hybrid scorpionate/cyclopentadienyllithium compound as a new class of tridentate ligand is described. This…”
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4
An Efficient and Versatile Lanthanum Heteroscorpionate Catalyst for Carbon Dioxide Fixation into Cyclic Carbonates
Published in ChemSusChem (21-07-2017)“…A new lanthanum heteroscorpionate complex has shown exceptional catalytic activity for the synthesis of cyclic carbonates from epoxides and carbon dioxide…”
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5
Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes
Published in Chemistry : a European journal (26-06-2015)“…New aluminium scorpionate based complexes have been prepared and used for the synthesis of cyclic carbonates from epoxides and carbon dioxide. Bimetallic…”
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6
One‐Component Aluminum(heteroscorpionate) Catalysts for the Formation of Cyclic Carbonates from Epoxides and Carbon Dioxide
Published in ChemSusChem (22-03-2017)“…New neutral and zwitterionic chiral NNO‐donor scorpionate ligands 1 and 2 were designed to obtain new mononuclear and dinuclear NNO‐heteroscorpionate aluminum…”
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7
Base‐Catalyzed Highly Regioselective Synthesis of Bio‐Based Hydroxyurethanes
Published in European journal of organic chemistry (24-06-2024)“…The regioselective synthesis of carbamates from bio‐derived cyclic carbonates and amines by using 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD) as an…”
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8
Amidinate Aluminium Complexes as Catalysts for Carbon Dioxide Fixation into Cyclic Carbonates
Published in ChemCatChem (24-05-2018)“…A series of inexpensive and sustainable amidinate aluminium complexes has been developed as catalysts for the chemical fixation of carbon dioxide into cyclic…”
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9
A Simple and Efficient Synthetic Route to Enantiopure Scorpionate Ligands
Published in European Journal of Inorganic Chemistry (01-02-2006)“…A simple and efficient synthetic route for the preparation of enantiopure scorpionate ligands is described that allows the optimization and rapid access to…”
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Book Review Journal Article -
10
Design of New Bis(1,2,3‐triazol‐1‐yl)methane‐Based Nitrogen Ligands: Synthesis and Coordination Chemistry
Published in Chemistry : a European journal (23-05-2024)“…The reaction between bis(1,2,3‐triazol‐1‐yl)methane derivatives and nBuLi and various aldehydes, yielded novel neutral ligand precursors incorporating alcohol…”
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11
Stereoselective ROP of rac-Lactide Mediated by Enantiopure NNO-Scorpionate Zinc Initiators
Published in Organometallics (14-04-2014)“…The reaction of the enantiopure NNO-scorpionate ligand (R,R)-bpzmmH with [ZnR2] (R = Me, Et, CH2SiMe3) in a 1:2 molar ratio afforded the dinuclear tris-alkyls…”
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12
Fast Addition of s‐Block Organometallic Reagents to CO2‐Derived Cyclic Carbonates at Room Temperature, Under Air, and in 2‐Methyltetrahydrofuran
Published in ChemSusChem (06-05-2021)“…Fast addition of highly polar organometallic reagents (RMgX/RLi) to cyclic carbonates (derived from CO2 as a sustainable C1 synthon) has been studied in…”
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Journal Article -
13
Influence of the Counterion on the Synthesis of Cyclic Carbonates Catalyzed by Bifunctional Aluminum Complexes
Published in Inorganic chemistry (04-03-2019)“…New bifunctional aluminum complexes have been prepared with the aim of studying the effect of a counterion on the synthesis of cyclic carbonates from epoxides…”
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14
Development of Heterobimetallic Al/Mg Complexes for the Very Rapid Ring-Opening Polymerization of Lactides
Published in Inorganic chemistry (18-09-2023)“…The successful architecture of active catalytic species with enhanced efficiencies is critical for the optimal exploitation of sustainable resources in…”
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15
Synthesis of Oxazolidinones from Epoxides and Isocyanates Catalysed by Aluminium Heteroscorpionate Complexes
Published in ChemCatChem (21-06-2016)“…The combination of an aluminium(heteroscorpionate) complex and tetrabutylammonium bromide acts as a highly efficient catalyst system for the synthesis of…”
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16
New Complexes of Niobium(V) and Tantalum(V) with Monoanionic NNO Heteroscorpionate Ligands
Published in European journal of inorganic chemistry (01-01-2004)“…A new synthetic route based on bis(3,5‐dimethylpyrazol‐1‐yl)acetic acid (Hbdmpza) (1) has afforded the alcohol 2,2‐bis(3,5‐dimethylpyrazol‐1‐yl)ethanol…”
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17
Zinc-Catalyzed Cyclization of Alkynyl Derivatives: Substrate Scope and Mechanistic Insights
Published in Inorganic chemistry (29-07-2024)“…Novel alkyl zinc complexes supported by acetamidate/thioacetamidate heteroscorpionate ligands have been successfully synthesized and characterized. These…”
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18
NNC-Scorpionate Zirconium-Based Bicomponent Systems for the Efficient CO2 Fixation into a Variety of Cyclic Carbonates
Published in Inorganic chemistry (08-09-2020)“…Two new derivatives of the bis(3,5-dimethylpyrazol-1-yl)methane modified by introduction of organosilyl groups on the central carbon atom, one of which…”
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19
Controlled Delivery of BET-PROTACs: In Vitro Evaluation of MZ1-Loaded Polymeric Antibody Conjugated Nanoparticles in Breast Cancer
Published in Pharmaceutics (19-10-2020)“…Bromo and extraterminal domain (BET) inhibitors-PROteolysis TArgeting Chimera (BETi-PROTAC) is a new family of compounds that induce proteasomal degradation…”
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20
Bifunctional Aluminum Catalysts for the Chemical Fixation of Carbon Dioxide into Cyclic Carbonates
Published in ACS sustainable chemistry & engineering (02-04-2018)“…Bifunctional aluminum complexes supported by novel zwitterionic NNO-donor scorpionate ligands were found to be efficient bifunctional catalysts for cyclic…”
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