Search Results - "Laptash, Natalia M"
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Synthesis, Structural, Magnetic, and Electronic Properties of Cubic CsMnMoO3F3 Oxyfluoride
Published in Journal of physical chemistry. C (10-05-2012)“…A powder sample of CsMnMoO3F3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO3F3 has been refined…”
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2
Mixed-valence hydrated iron fluoridotitanate: Crystal structure and thermal behavior
Published in Journal of fluorine chemistry (01-09-2021)“…•High quality mixed-valence single crystals of hydrated iron hexafluoridotitanate (HITF) were obtained.•Crystal structures of RT and LT modifications of HITF…”
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3
Calorimetric, dilatometric and DTA under pressure studies of the phase transitions in elpasolite (NH4)2KZrF7
Published in Journal of fluorine chemistry (01-07-2020)“…[Display omitted] •Heat capacity and thermal expansion at phase transitions in (NH4)2KZrF7 are studied.•Initial cubic and distorted tetragonal phases show high…”
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4
Ammonium tantalum oxide fluorides: new features of dynamic disorder
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-12-2019)“…Ammonium fluoride salts of seven‐ and eight‐coordinated tantalum were grown in the form of well shaped single crystals at different pH of solutions, and their…”
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5
Investigation of thermal properties and structure of complex fluoride K3ZrF7
Published in Journal of fluorine chemistry (01-01-2021)“…[Display omitted] •Structural change, heat capacity and thermal expansion of fluoride K3ZrF7 are studied.•Structural distortions are mainly associated with the…”
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6
Phase transition in RbCdZrF7: Structure and thermal properties
Published in Journal of fluorine chemistry (01-05-2021)“…[Display omitted] •Second order phase transition Cmcm↔ P21/m at 200 K is far from the tricritical point.•All structural elements are ordered in both…”
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7
Optical and calorimetric studies of K2TaF7
Published in Journal of fluorine chemistry (01-06-2019)“…The phase transition Pnma ↔ P21/c in K2TaF7 is a strong first-order transformation of the “proper” ferroelastic origin. A huge angle of rotation of the optical…”
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8
Fluxional seven‐coordinated fluorido‐ and oxofluoridotantalates
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-12-2019)“…Seven‐coordinated (NH4)2TaF7, Rb2TaF7 and Rb3TaOF6 were synthesized in single‐crystal form and their structures were determined. A monocapped trigonal prism…”
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9
Dinuclear oxofluorometallates as a new structural type of d(0) transition metal oxofluoride compound
Published in Acta crystallographica. Section B, Structural science (01-12-2012)“…Five isomorphous d(0) transition metal oxofluoride compounds A(3)[M(2)O(x)F(11-x)]·(AF)(0.333) (A = K, Rb, NH(4); M = Nb, Mo, W; x = 2, 4) have been…”
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10
Bonding and Structure of Oxofluoroniobate-Based Glasses
Published in Inorganic chemistry (20-05-2013)“…Glasses based on the oxofluoroniobate anion have been characterized by vibrational and solid-state NMR spectroscopy. The mechanism of glass formation in the…”
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11
Influence of the Molecular Groups Ordering on Structural Phase Transitions in (NH4)2WO2F4 Crystal
Published in Crystal growth & design (02-01-2014)“…Phase transitions of the (NH4)2WO2F4 crystal were studied by Raman spectroscopy in the range from 10 to 350 K. The mechanism of two phase transitions at T 1 =…”
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12
Orientational disorder and phase transitions in ammonium oxofluorovanadates, (NH4)3VOF5 and (NH4)3VO2F4
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-12-2017)“…Single crystals of (NH4)3VOF5 and (NH4)3VO2F4 were obtained from aqueous fluoride solutions and phase transitions in these compounds were investigated using…”
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13
Dinuclear oxofluorometallates as a new structural type of d0 transition metal oxofluoride compound
Published in Acta crystallographica. Section B, Structural science (01-12-2012)“…Five isomorphous d0 transition metal oxofluoride compounds A3[M2OxF11 − x]·(AF)0.333 (A = K, Rb, NH4; M = Nb, Mo, W; x = 2, 4) have been synthesized from acid…”
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14
Dynamic orientational disorder in crystals of fluoroelpasolites, structural refinement of (NH4)3AlF6, (NH4)3TiOF5 and Rb2KTiOF5
Published in Acta crystallographica. Section B, Structural science (01-12-2011)“…Room‐temperature crystal structures of triammonium hexafluoroaluminate, (NH4)3AlF6 (I), and triammonium oxopentafluorotitanate, (NH4)3TiOF5 (II), were refined,…”
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15
Orientational disorder and phase transitions in crystals of dioxofluoromolybdate, (NH4)2MoO2F4
Published in Acta crystallographica. Section B, Structural science (01-02-2010)“…Dioxotetrafluoromolybdate, (NH4)2MoO2F4, was synthesized in a single‐crystal form and its structures [(I) at 297 K and (II) at 223 K] were determined by X‐ray…”
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16
Orientational disorder and phase transitions in crystals of (NH4)2NbOF5
Published in Acta crystallographica. Section B, Structural science (01-10-2008)“…Ammonium oxopentafluoroniobate, (NH4)2NbOF5, was synthesized in a single‐crystal form and the structures of its different phases were determined by X‐ray…”
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Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F4
Published in Acta crystallographica. Section B, Structural science (01-12-2008)“…Dioxotetrafluorotungstates (NH4)2WO2F4 [(I) at 297 K and (II) at 133 K] and Rb2WO2F4 (III) were synthesized in a single‐crystal form and their structures were…”
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18
Intermetallic charge transfer in MTiF6·6H2O (M = Mn, Fe, Co, and Ni): A study by X-ray photoelectron spectroscopy
Published in Solid state sciences (01-02-2024)“…The X-ray photoelectron spectra (XPS) of a series of hydrated fluoridotitanates MTiF6∙6H2O (M = Mg, Mn, Fe, Co, Ni) were measured for the first time. The…”
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19
Phase transformation in some hexahydrated metal(II) fluorogermanates and fluorotitanates: Optical and differential scanning calorimetry studies
Published in Journal of fluorine chemistry (01-11-2022)“…•Single crystals of hydrated fluorides CoGeF6∙6H2O, FeGeF6∙6H2O, CoTiF6∙6H2O, ZnTiF6∙6H2O were grown.•Twinning, birefringence and heat capacities indicate a…”
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20
Effect of the size of the central atom on the stability of crystalline phases in solid solutions (NH4)3TixSn1-xF7
Published in Journal of solid state chemistry (01-12-2023)“…The effect of a change in internal pressure as a result of partial substitution of the central atom on the realization and stability of the initial and…”
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