Search Results - "Lapinski, Leszek"
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Near-IR laser generation of a high-energy conformer of L-alanine and the mechanism of its decay in a low-temperature nitrogen matrix
Published in The Journal of chemical physics (28-03-2013)“…Monomers of L-alanine (ALA) were isolated in cryogenic nitrogen matrices at 14 K. Two conformers were identified for the compound trapped from the gas-phase…”
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2
Near-IR-Induced, UV-Induced, and Spontaneous Isomerizations in 5‑Methylcytosine and 5‑Fluorocytosine
Published in The journal of physical chemistry. B (20-03-2014)“…Monomeric 5-methylcytosine (5mCyt) and 5-fluorocytosine (5FCyt) were studied using the matrix-isolation method. In 5mCyt and 5FCyt, the most stable form,…”
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3
UV-Induced Amino → Imino Hydrogen-Atom Transfer in 1‑Methylcytosine
Published in The journal of physical chemistry. B (17-05-2012)“…Monomers of 1-methylcytosine, isolated in low-temperature argon matrixes, were excited with narrowband tunable UV light. Irradiation at λ = 314 nm resulted in…”
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4
Systematic Effect of Benzo-Annelation on Oxo−Hydroxy Tautomerism of Heterocyclic Compounds. Experimental Matrix-Isolation and Theoretical Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-06-2007)“…Oxo−hydroxy tautomerism and phototautomerism of 2-quinolinone, 1-isoquinolinone, 3-hydroxyisoquinoline, 2-quinoxalinone, and 4-quinazolinone were studied using…”
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A Computational Study on the Mechanism of Intramolecular Oxo−Hydroxy Phototautomerism Driven by Repulsive πσ State
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (25-12-2008)“…Potential energy (PE) surfaces of the lowest excited states of the 4(3H)-pyrimidinone/4-hydroxypyrimidine system were investigated with the aid of the CC2 and…”
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6
Infrared spectra of methyl isocyanate isolated in Ar, Xe and N2 matrices
Published in Journal of molecular structure (01-07-2010)Get full text
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7
Infrared spectra and ultraviolet-tunable laser induced photochemistry of matrix-isolated phenol and phenol-d5
Published in The Journal of chemical physics (14-01-2012)“…Monomers of phenol and its ring-perdeuterated isotopologue phenol-d(5) were isolated in argon matrices at 15 K. The infrared (IR) spectra of these species were…”
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Proton-Transfer Processes in Thiourea: UV Induced Thione → Thiol Reaction and Ground State Thiol → Thione Tunneling
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-08-2003)“…Thiourea monomers isolated in a low-temperature argon matrix adopt exclusively the thione tautomeric form. Upon UV (λ > 300 nm) irradiation a photoreaction…”
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9
Thioperoxy Derivative Generated by UV-Induced Transformation of N-Hydroxypyridine-2(1H)-thione Isolated in Low-Temperature Matrixes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-01-2008)“…Photochemical transformations of N-hydroxypyridine-2(1H)-thione and its deuterated isotopologue were studied using the matrix-isolation technique…”
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10
Stability of monomeric indigo in the electronic ground state: An experimental matrix isolation infrared and theoretical study
Published in Dyes and pigments (01-03-2024)Get full text
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11
Hydrogen-atom tunneling in small thioamides: N-methylthiourea, thiobenzamide and 2-cyanothioacetamide
Published in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (15-05-2024)“…[Display omitted] •Thiol tautomers were photogenerated from the thione forms of N-methylthiourea, thiobenzamide and 2-cyanothioacetamide.•The thiol tautomers…”
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12
Distinct class of photoinduced hydrogen-atom-transfer processes: phototautomerizations in molecules with no intramolecular hydrogen bond in the structure
Published in International reviews in physical chemistry (02-01-2022)“…Photoinduced hydrogen-atom-transfer processes presented in this review commonly occur in heterocyclic oxo and thione compounds isolated in low-temperature…”
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13
Photoinduced Long-Distance Hydrogen-Atom Transfer in Molecules with a 7‑Hydroxyquinoline Frame and a Carbaldehyde or Aldoxime Group as the Intramolecular Hydrogen Transporting Crane
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (13-04-2023)“…The photochemical properties of monomeric 7-hydroxyquinoline substituted at position 8 with carbaldehyde or aldoxime groups were studied for the molecules…”
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14
Photochemical Generation of Benzoazetinone by UV Excitation of Matrix-Isolated Precursors: Isatin or Isatoic Anhydride
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-05-2020)“…Benzoazetinone was photochemically generated by UV irradiation of isatin isolated in low-temperature Ar matrixes. Upon UV (λ = 278 nm) excitation of isatin,…”
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15
Photochemical transformations of 4,6-dihydroxypyrimidine and 2-methyl-4,6-dihydroxypyrimidine isolated in low-temperature Ar, Ne and H2 matrices
Published in Chemical physics letters (16-04-2020)“…[Display omitted] •Dihydroxy and oxo-hydroxy tautomeric forms of 4,6-dihydroxypyrimidine and its 2-methylated analog are the most stable structures in the gas…”
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16
UV-Induced Hydrogen-Atom-Transfer Processes in 3‑Thio-1,2,4-triazole Isolated in Ar and H2 Low-Temperature Matrixes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-09-2017)“…The UV-induced thione → thiol phototautomeric reaction has been studied for monomeric 3-thio-1,2,4-triazole (3-ST) isolated in low-temperature Ar and n-H2…”
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17
Effect of a Solid-Hydrogen Environment on UV-Induced Hydrogen-Atom Transfer in Matrix-Isolated Heterocyclic Thione Compounds
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-09-2021)“…To shed more light on the mechanisms of UV-induced hydrogen-atom-transfer processes in heterocyclic molecules, phototautomeric thione → thiol reactions were…”
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18
Phototransformations of 2,3-Diamino-2-Butenedinitrile (DAMN) Monomers Isolated in Low-Temperature Argon Matrix
Published in Photochem (01-06-2022)“…UV-induced transformations were studied for monomers of 2,3-diamino-2-butenedinitrile (DAMN) isolated in argon matrices. Photoinduced hydrogen-atom transfer…”
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19
Near-Infrared Laser-Induced Generation of Three Rare Conformers of Glycolic Acid
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (31-07-2014)“…Structural transformations were induced in conformers of glycolic acid by selective excitation with monochromatic tunable near-infrared laser light. For the…”
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20
Three Conformers of 2‑Furoic Acid: Structure Changes Induced with Near-IR Laser Light
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-02-2015)“…Conformers of 2-furoic acid were studied using the matrix-isolation technique combined with narrow-band near-IR excitations with tunable laser light. Two…”
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