Search Results - "Langerman, Michiel"

Fast Oxygen Reduction Catalyzed by a Copper(II) Tris(2‐pyridylmethyl)amine Complex through a Stepwise Mechanism by Langerman, Michiel, Hetterscheid, Dennis G. H.

“…Catalytic pathways for the reduction of dioxygen can either lead to the formation of water or peroxide as the reaction product. We demonstrate that the…”
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Synthesis and Avidin Binding of Ruthenium Complexes Functionalized with a Light‐Cleavable Free Biotin Moiety by Siewert, Bianka, Langerman, Michiel, Pannwitz, Andrea, Bonnet, Sylvestre

“…In this work the synthesis, photochemistry, and streptavidin interaction of new [Ru(tpy)(bpy)(SRR′)](PF6)2 complexes where the R′ group contains a free biotin…”
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Cover Feature: Mechanistic Study of the Activation and the Electrocatalytic Reduction of Hydrogen Peroxide by Cu‐tmpa in Neutral Aqueous Solution (15/2021) by Langerman, Michiel, Hetterscheid, Dennis G. H.

“…The Cover Feature shows an artist impression of the electrochemical reduction of hydrogen peroxide with Cu(tmpa). More information can be found in the Article…”
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Synthesis and Avidin Binding of Ruthenium Complexes Functionalized with a Light‐Cleavable Free Biotin Moiety by Siewert, Bianka, Langerman, Michiel, Pannwitz, Andrea, Bonnet, Sylvestre

“…Invited for the cover of this issue is the group of Sylvestre Bonnet from Leiden University, The Netherlands. The cover image shows the attachment of a free…”
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Dioxygen Reduction in Acetonitrile with Copper Pyridylalkylamine Complexes: The Influence of Acid Strength on the Catalytic Performance by Langerman, Michiel, Dorth, Micha, Hetterscheid, Dennis G. H.

“…The pyridylalkylamine copper complex [Cu(tmpa)(L)]2+ has previously been proposed to reduce dioxygen via a dinuclear resting state, based on experiments in…”
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Scaling Relation between the Reduction Potential of Copper Catalysts and the Turnover Frequency for the Oxygen and Hydrogen Peroxide Reduction Reactions by Langerman, Michiel, van Langevelde, Phebe H, van de Vijver, Johannes J, Siegler, Maxime A, Hetterscheid, Dennis G H

“…Changes in the electronic structure of copper complexes can have a remarkable impact on the catalytic rates, selectivity, and overpotential of electrocatalytic…”
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Front Cover: Synthesis and Avidin Binding of Ruthenium Complexes Functionalized with a Light‐Cleavable Free Biotin Moiety (Eur. J. Inorg. Chem. 37/2018) by Siewert, Bianka, Langerman, Michiel, Pannwitz, Andrea, Bonnet, Sylvestre

“…The Front Cover shows a streptavidin molecule functionalized with a light‐sensitive Ru–polypyridyl complex via a bis‐biotin ligand. One biotin is free and…”
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Mechanistic Study of the Activation and the Electrocatalytic Reduction of Hydrogen Peroxide by Cu‐tmpa in Neutral Aqueous Solution by Langerman, Michiel, Hetterscheid, Dennis G. H.

“…Hydrogen peroxide plays an important role as an intermediate and product in the reduction of dioxygen by copper enzymes and mononuclear copper complexes. The…”
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Fast Oxygen Reduction Catalyzed by a Copper(II) Tris(2‐pyridylmethyl)amine Complex through a Stepwise Mechanism by Langerman, Michiel, Hetterscheid, Dennis G. H.

“…Catalytic pathways for the reduction of dioxygen can either lead to the formation of water or peroxide as the reaction product. We demonstrate that the…”
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