Search Results - "Lan, Xiaocheng"
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Highly Selective Catalysts for the Hydrogenation of Unsaturated Aldehydes: A Review
Published in ACS catalysis (21-02-2020)“…The selective hydrogenation of unsaturated aldehydes (UAL) to saturated aldehydes (SAL) and unsaturated alcohols (UOL) is an important industrial process for…”
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2
Supported Ultrafine NiCo Bimetallic Alloy Nanoparticles Derived from Bimetal–Organic Frameworks: A Highly Active Catalyst for Furfuryl Alcohol Hydrogenation
Published in ACS catalysis (02-03-2018)“…Highly dispersed NiCo bimetallic alloy nanoparticles have been successfully immobilized on the SiO2 frameworks by using heteronuclear metal–organic frameworks…”
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3
Promotion of Inorganic Phosphorus on Rh Catalysts in Styrene Hydroformylation: Geometric and Electronic Effects
Published in ACS catalysis (05-02-2021)“…Rh-based homogeneous catalysts with phosphine ligands are highly active in hydroformylation reactions. Using DFT calculations, we found a similar electronic…”
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4
Synthesis of Pt@MAF-6 as a Steric Effect Catalyst for Selective Hydrogenation of Cinnamaldehyde
Published in Catalysis letters (01-11-2020)“…Pt@MAF-6 was designed as a highly selective catalyst for cinnamaldehyde hydrogenation. The aperture of Pt@MAF-6 acted to sterically confine cinnamaldehyde, and…”
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Synthesis of γ-valerolactone from ethyl levulinate hydrogenation and ethyl 4-hydroxypentanoate lactonization over supported Cu-Ni bimetallic, bifunctional catalysts
Published in Journal of industrial and engineering chemistry (Seoul, Korea) (25-03-2022)“…Biomass-derived ethyl levulinate is highly selectively hydrogenated to a valuable chemical, γ-valerolactone, over supported Cu-Ni bimetallic, bifunctional…”
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Imaging the dynamic influence of functional groups on metal-organic frameworks
Published in Nature communications (10-08-2023)“…Metal-organic frameworks (MOFs) with different functional groups have wide applications, while the understanding of functionalization influences remains…”
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Controlling the selectivity and deactivation of H-ZSM-5 by tuning b-axis channel length for glycerol dehydration to acrolein
Published in Journal of industrial and engineering chemistry (Seoul, Korea) (25-08-2020)“…[Display omitted] •A series of H-ZMS-5 with well controlled b-axis channels of 60–250nm were prepared.•Much better catalytic performance was obtained with…”
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Combined synergetic and steric effects for highly selective hydrogenation of unsaturated aldehyde
Published in Journal of catalysis (01-04-2019)“…[Display omitted] •Highly selective catalysts were designed with synergetic and steric effects.•The selectivity to unsaturated alcohol was enhanced from 4.3%…”
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Selective oxidation of furfural in a bi-phasic system with homogeneous acid catalyst
Published in Catalysis today (01-11-2016)“…[Display omitted] •Furfural was selectively oxidized to 2(5H)-furanone with a yield of 60–62%.•Bi-phasic system using dichloroethane or ethyl acetate as…”
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Experimental study on alkylation of PCl3 for methyl-dichloride phosphine synthesis using mass spectrometry detection
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-09-2024)“…•An online sampling and MS detection method was developed to study the alkylation of PCl3 with CH4.•The addition of chloromethanes significantly enhanced PCl3…”
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11
Intensification of diethyl methylphosphite synthesis based on kinetics study and CFD modeling
Published in AIChE journal (01-01-2024)“…A “pre‐dissolving ammonia” intensification method for continuous production of diethyl methylphosphite (DEMP) was proposed based on kinetics study of methyl…”
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12
Highly Active and Selective Nano H‑ZSM‑5 Catalyst with Short Channels along b‑Axis for Glycerol Dehydration to Acrolein
Published in Industrial & engineering chemistry research (17-07-2019)“…For the sustainability of the biodiesel industry, the selective glycerol dehydration to valuable acrolein using zeolite catalysts is a very important…”
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13
Subsurface Carbon as a Selectivity Promotor to Enhance Catalytic Performance in Acetylene Semihydrogenation
Published in ACS catalysis (20-08-2021)“…For supported metal catalysts, subsurface sites can significantly influence the adsorption and reaction behaviors on surface sites via the electronic effect…”
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14
Hollow and Yolk–Shell Co-N-C@SiO2 Nanoreactors: Controllable Synthesis with High Selectivity and Activity for Nitroarene Hydrogenation
Published in ACS applied materials & interfaces (22-01-2020)“…The use of hollow and yolk–shell nanocomposites is an effective route to enhance catalytic performance. A strategy that allows precise control of the…”
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Metal-modified Ni phosphides: Highly efficient catalysts for the hydrogenation of ethyl levulinate
Published in Catalysis today (01-12-2024)“…The hydrogenation of ethyl levulinate (EL) to γ-valerolactone (GVL) is an important process in biomass conversion to value-added chemicals. However, it remains…”
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16
Metal Phosphide: An Atypical Catalytic Site
Published in ACS catalysis (19-01-2024)“…The studies of metal phosphides (MPs) have flourished in the past decades due to their exceptional catalytic performance in thermo-, electro-, and…”
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Insights into the Bimetallic Effects of a RhCo Catalyst for Ethene Hydroformylation: Experimental and DFT Investigations
Published in Industrial & engineering chemistry research (21-10-2020)“…Rh-based bimetallic catalysts are promising ligand-free heterogeneous catalysts for hydroformylation reactions. It is important to understand the mechanism of…”
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Highly Selective Hydrogenation of Furfural to Cyclopentanone over a NiFe Bimetallic Catalyst in a Methanol/Water Solution with a Solvent Effect
Published in ACS sustainable chemistry & engineering (16-09-2019)“…The aqueous phase hydrogenation of furfural to cyclopentanone over a NiFe bimetallic catalyst was investigated for the efficient utilization of biomass-derived…”
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Highly Efficient Hydrogenation of Nitroarenes by N‑Doped Carbon-Supported Cobalt Single-Atom Catalyst in Ethanol/Water Mixed Solvent
Published in ACS applied materials & interfaces (29-07-2020)“…The cobalt single atoms supported on N-doped carbon (Co SAs/NC) were prepared by the direct pyrolysis of metal–organic framework (MOF) precursor. Compared with…”
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Insights into the Activity Screening and Hydroformylation Kinetics of Rh-Based Bimetallic Phosphides
Published in ACS catalysis (17-12-2021)“…Heterogeneous hydroformylation is of great industrial and economic interest. Here, we proposed a screening strategy to search highly active Rh-based bimetallic…”
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