Search Results - "Lampland, Nicole L"

Iridium Complexes of CCC-Pincer N-Heterocyclic Carbene Ligands: Synthesis and Catalytic C−H Functionalization by Chianese, Anthony R, Mo, Allen, Lampland, Nicole L, Swartz, Raymond L, Bremer, Paul T

“…A series of four meta-phenylene-bridged bis-benzimidazolium chlorides were synthesized as precursors to rigid, monoanionic, CCC-pincer N-heterocyclic carbene…”
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Magnesium-Catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines by Lampland, Nicole L, Hovey, Megan, Mukherjee, Debabrata, Sadow, Aaron D

“…The first example of a catalytic hydroboration of amides for their deoxygenation to amines is reported. This transformation employs an earth-abundant…”
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Rare Earth and Main Group Metal Poly(hydrosilyl) Compounds by Lampland, Nicole L, Pindwal, Aradhana, Yan, KaKing, Ellern, Arkady, Sadow, Aaron D

“…The potassium poly­(hydrosilyl) compound KSi­(SiHMe2)3, which contains three β-SiH groups, is synthesized by the reaction of Si­(SiHMe2)4 and KOtBu. A…”
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Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters by Lampland, Nicole L, Pindwal, Aradhana, Neal, Steven R, Schlauderaff, Shealyn, Ellern, Arkady, Sadow, Aaron D

“…To MgHB(C F ) ( , To = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters. This magnesium hydridoborate…”
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Piano-Stool Lutetium Amido and Imido Compounds Supported by a Constrained Bis(oxazoline)cyclopentadienyl Ligand by Lampland, Nicole L, Zhu, Jing, Hovey, Megan, Jana, Barun, Ellern, Arkady, Sadow, Aaron D

“…{BoMCptet}­Lu­(CH2Ph)2 (1; BoMCptet = MeC­(OxMe2)2C5Me4; OxMe2 = 4,4-dimethyl-2-oxazoline) was prepared in 95% yield from the reaction of BoMCptetH and…”
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Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations by Eedugurala, Naresh, Hovey, Megan, Ho, Hung-An, Jana, Barun, Lampland, Nicole L, Ellern, Arkady, Sadow, Aaron D

“…A new class of cyclopentadiene-bis­(oxazoline) compounds and their piano-stool-type organometallic complexes have been prepared as catalysts for hydroamination…”
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β-SiH rich zinc silyl compounds: Reductive elimination and β-hydrogen abstraction by Lampland, Nicole L., Ellern, Arkady, Sadow, Aaron D.

“…The two-coordinate compound Zn{Si(SiHMe2)3}2 spontaneously undergoes reductive elimination to produce (Me2HSi)3Si–Si(SiHMe2)3 and metallic zinc. The transient…”
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Magnesium-catalyzed hydrosilylation of α,β-unsaturated estersElectronic supplementary information (ESI) available: General experimental, synthesis and characterization of magnesium compounds and catalysis products. CCDC 1411027. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02435h by Lampland, Nicole L, Pindwal, Aradhana, Neal, Steven R, Schlauderaff, Shealyn, Ellern, Arkady, Sadow, Aaron D

“…To M MgHB(C 6 F 5 ) 3 ( 1 , To M = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters. This magnesium…”
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Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters† †Electronic supplementary information (ESI) available: General experimental, synthesis and characterization of magnesium compounds and catalysis products. CCDC 1411027. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02435h by Lampland, Nicole L., Pindwal, Aradhana, Neal, Steven R., Schlauderaff, Shealyn, Ellern, Arkady, Sadow, Aaron D.

“…A magnesium hydridoborate compound catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters to give silyl ketene acetals. To M MgHB(C 6 F 5 ) 3 ( 1 , To M =…”
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