Search Results - "Lalayan, S. S."
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Alkene Polymerization with Catalysts Containing Ionic Complexes [2L·M@dibenzo-18-crown-6]+[TiCl5·L]–(L = CH3CN, M = Li+, K+)
Published in Polymer science. Series B (01-02-2024)“…The polymerization of ethylene and propylene and the copolymerization of ethylene with 1-octene with novel type of post-metallocene catalysts containing ionic…”
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Strengthening Polypropylene with Ultra-High-Molecular-Weight Polydecene
Published in Polymer science. Series D, Glues and sealing materials (2024)“…The structure and mechanical properties of heterophase compositions based on isotactic polypropylene and ultra-high-molecular-weight polydecene have been…”
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New Cocatalyst for Alkene Polymerization Reactions with Transition Metal Catalysts
Published in Russian journal of physical chemistry. B (01-09-2019)“…The effect of a cocatalyst in alkene homo- and copolymerizations with transition metal catalysts of different types was studied. The results of studies of…”
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Using neural networks for non-invasive determination of glycated hemoglobin levels, illustrated by the application of an innovative portable glucometer in clinical practice
Published in Digital diagnostics (03-07-2024)“…BACKGROUND: In the last decade, there has been a significant increase in interest in non-invasive monitoring of blood glucose levels [1]. This is driven by the…”
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Polymerization of linear higher α-olefins with a modified Ziegler catalyst
Published in Polymer science. Series B (2014)“…The polymerization of hexene-1, octene-1 and decene-1 with a modified Ziegler catalyst based on the product of interaction of TiCl 4 , Et 2 AlCl, and n -Bu 2 O…”
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The role of alkoxysilanes in propylene polymerization catalysis. A study of model Ti(Oi‐C3H7)4‐Al(C2H5)2Cl/Mg(C4H9)2 catalyst system
Published in Polymer international (01-07-2023)“…The article describes the modifying effect of methylcyclohexyldimethoxysilane (CH3)(cyclo‐C6H11)Si(OCH3)2 in propylene polymerization reactions with a…”
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Alkene polymerization reactions with catalysts based on acetylacetonate complexes of vanadium and titanium: effect of cocatalyst
Published in Polymer international (01-03-2022)“…Alkene polymerization reactions were studied with three catalyst systems containing complexes of vanadium and titanium with the acetylacetonate ligand…”
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Ethylene polymerization and copolymerization reactions with Ti(OR)4 – Al2(C2H5)3Cl3/Mg(C4H9)2 catalyst
Published in Polymer international (01-12-2020)“…The ternary Ti(Oiso‐C3H7)4–Al2(C2H5)3Cl3/Mg(C4H9)2 catalyst polymerizes ethylene and copolymerizes it with 1‐hexene but does not polymerize propylene. The…”
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The second life of Ziegler catalyst. Ethylene polymerization reactions with TiCl4–Al[C2H5]2Cl/Mg(C4H9)2 catalyst
Published in Journal of applied polymer science (20-04-2019)“…ABSTRACT The Ziegler catalyst, a combination of TiCl4 and Al(C2H5)2Cl, was widely used since 1950s for the commercial manufacture of linear polyethylene. We…”
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Synthesis of atactic polypropylene: Propylene polymerization reactions with TiCl4–Al(C2H5)2Cl/Mg(C4H9)2 catalyst
Published in Journal of applied polymer science (05-07-2019)“…ABSTRACT The Ziegler catalyst, a combination of TiCl4 and Al(C2H5)2Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C4H9)2…”
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Peculiarities of Ethylene Polymerization Reactions with Bis(imino)pyridyl Complexes of CoCl2 and FeCl2
Published in Chinese journal of polymer science (01-04-2024)“…The article describes ethylene polymerization reactions with transition metal catalysts based on complexes of CoCl 2 and FeCl 2 with an N,N,N -tridentate…”
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Polymers of propylene and higher 1-alkenes produced with post-metallocene complexes containing a saligenin-type ligand
Published in Polymer (Guilford) (14-11-2013)“…Polymerization reactions of propylene and three higher linear 1-alkenes, 1-hexene, 1-octene and 1-decene, were carried out with post-metallocene catalysts…”
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DFT study of the activation of dimethylzirconocenes by aluminium-containing activators
Published in Mendeleev communications (01-09-2010)“…The participation of two and three A≡ Lewis acid sites in the formation of the catalytic particle Cp * 2ZrMe +A − for olefin polymerization reactions…”
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new route to atactic polypropylene: The second life of premetallocene homogeneous polymerization catalyst
Published in Journal of polymer science. Part A, Polymer chemistry (15-09-2015)“…Amorphous atactic polypropylene (PP) with an average molecular weight of 50,000–100,000 is produced by polymerizing propylene with a ternary Ti(Oiso‐Pr)₄ ‐…”
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Polymerization of alkenes with a post‐metallocene catalyst containing a titanium complex with an oxyquinolinyl ligand
Published in Journal of polymer science. Part A, Polymer chemistry (01-06-2017)“…ABSTRACT Polymerization reactions of ethylene, propylene, higher 1‐alkenes (1‐hexene, 1‐octene, 1‐decene, vinyl cyclohexane, 3‐methyl‐1‐butene), and…”
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A novel efficient Ti(O-iso-C3H7)4-based olefin polymerization catalyst system
Published in Polymer science. Series B (01-03-2016)“…The polymerization of ethylene and propylene and the copolymerization of ethylene and hexene-1 with a Ti(O- iso -Pr) 4 –AlR 2 Cl/MgBu 2 catalyst system have…”
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A novel efficient Ti(O-iso-C sub(3)H sub(7)) sub(4)-based olefin polymerization catalyst system
Published in Polymer science. Series B (01-03-2016)“…The polymerization of ethylene and propylene and the copolymerization of ethylene and hexene-1 with a Ti(O-iso-Pr) sub(4)-AlR sub(2)Cl/MgBu sub(2) catalyst…”
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The role of alkoxysilanes in propylene polymerization catalysis. A study of model Ti( O i ‐C 3 H 7 ) 4 ‐Al( C 2 H 5 ) 2 Cl /Mg( C 4 H 9 ) 2 catalyst system
Published in Polymer international (01-07-2023)“…The article describes the modifying effect of methylcyclohexyldimethoxysilane (CH 3 )( cyclo ‐C 6 H 11 )Si(OCH 3 ) 2 in propylene polymerization reactions with…”
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Synthesis of atactic polypropylene: Propylene polymerization reactions with TiCl 4 –Al(C 2 H 5 ) 2 Cl/Mg(C 4 H 9 ) 2 catalyst
Published in Journal of applied polymer science (05-07-2019)“…The Ziegler catalyst, a combination of TiCl 4 and Al(C 2 H 5 ) 2 Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C 4 H 9…”
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