Search Results - "LICINI, Giulia"

Concentration-Independent Stereodynamic g‑Probe for Chiroptical Enantiomeric Excess Determination by Zardi, Paolo, Wurst, Klaus, Licini, Giulia, Zonta, Cristiano

“…Enantiomeric excess (ee) determination is crucial in many aspects of science, from synthesis to materials. Within this subject, coupling molecular sensors with…”
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Determination of Amino Acid Enantiopurity and Absolute Configuration: Synergism between Configurationally Labile Metal-Based Receptors and Dynamic Covalent Interactions by Scaramuzzo, Francesca A., Licini, Giulia, Zonta, Cristiano

“…Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly…”
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Efficient Vanadium‐Catalyzed Aerobic C−C Bond Oxidative Cleavage of Vicinal Diols by Amadio, Emanuele, González‐Fabra, Joan, Carraro, Davide, Denis, William, Gjoka, Blerina, Zonta, Cristiano, Bartik, Kristin, Cavani, Fabrizio, Solmi, Stefania, Bo, Carles, Licini, Giulia

“…The aerobic oxidative C−C bond cleavage of vicinal diols catalyzed by vanadium amino triphenolates is described. Our results show that C−C bond cleavage can be…”
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Mixed Multimetallic tris(2‐pyridylmethyl)amine Based Complexes: Synthesis and Chiroptical Properties by Carmo dos Santos, Nadia Alessandra, Badetti, Elena, Begato, Federico, Wurst, Klaus, Licini, Giulia, Zonta, Cristiano

“…Continuous intensification of reaction screening methodologies has required the development of novel high‐throughput analytical technologies. This urge…”
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Tuning the reactivity and efficiency of copper catalysts for atom transfer radical polymerization by synthetic modification of tris(2-methylpyridyl)amine by Carmo dos Santos, Nadia Alessandra, Lorandi, Francesca, Badetti, Elena, Wurst, Klaus, Isse, Abdirisak Ahmed, Gennaro, Armando, Licini, Giulia, Zonta, Cristiano

“…Copper complexes bearing ligands based on tris(2-methylpyridyl)amine (TPMA) are leading catalysts in atom transfer radical polymerization (ATRP). In recent…”
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C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models by MBA, Miriam, PONTINI, Marta, LOVAT, Silvia, ZONTA, Cristiano, BERNARDINELLI, Gerald, KÜNDIG, Peter E., LICINI, Giulia

“…The C 3 vanadium(V) amine triphenolate complex 1f has been characterized as a structural and functional model of vanadium haloperoxidases. The complex…”
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The medicinal and catalytic potential of model complexes of vanadate-dependent haloperoxidases by Rehder, Dieter, Santoni, Gabriella, Licini, Giulia M, Schulzke, Carola, Meier, Beate

“…Vanadium(V) complexes predominantly of composition VO( O 3 N), modeling the active center of vanadate-dependent haloperoxidases, are investigated with respect…”
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Periodic Trends and Fluxionality Effects on Transition Metal Catalyzed Sulfoxidation by Garay-Ruiz, Diego, Zonta, Cristiano, Lovat, Silvia, Sanz Azcona, Fátima, González-Fabra, Joan, Bo, Carles, Licini, Giulia

“…Despite the extended interest in d0 metal complexes as catalysts for peroxide activation and eventual oxygen transfer processes, there are still gaps in the…”
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Iridium-mediated Bond Activation and Water Oxidation as an Exemplary Case of CARISMA, A European Network for the Development of Catalytic Routines for Small Molecule Activation by Giulia Licini, Martin Albrecht

“…CARISMA is a currently running COST Action that pools leading European experts in computational and experimental chemistry to foster synergies for developing…”
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Mononuclear Iron(III) Complexes as Functional Models of Catechol Oxidases and Catalases by Badetti, Elena, Gjoka, Blerina, Nagy, Eszter Márta, Bernardinelli, Gérald, Kündig, Peter E., Zonta, Cristiano, Licini, Giulia

“…Mononuclear amino triphenolate iron(III) complexes have been synthesized and characterized (UV/Vis spectroscopy, cyclic voltammetry, ESI‐MS, 1H NMR…”
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Enantiopure Ti(IV) amino triphenolate complexes as NMR chiral solvating agents by Zonta, Cristiano, Kolarovic, Andrej, Mba, Miriam, Pontini, Marta, KÜndig, E. Peter, Licini, Giulia

“…Enantiopure Ti(IV) complexes bearing pseudo‐C3 amino triphenolate ligands have been synthesized and characterized. The complexes bearing ortho phenyl groups…”
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Computational Analysis of Enantioselective Pd-Catalyzed α‑Arylation of Ketones by Orlandi, Manuel, Licini, Giulia

“…The direct α-arylation of carbonyl compounds emerged over the last two decades as a straightforward method for the formation of C­(sp3)–C­(sp2) bonds…”
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Nucleophilicity Prediction via Multivariate Linear Regression Analysis by Orlandi, Manuel, Escudero-Casao, Margarita, Licini, Giulia

“…The concept of nucleophilicity is at the basis of most transformations in chemistry. Understanding and predicting the relative reactivity of different…”
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Enantioselective α‑Arylation of Ketones via a Novel Cu(I)–Bis(phosphine) Dioxide Catalytic System by Escudero-Casao, Margarita, Licini, Giulia, Orlandi, Manuel

“…A novel catalytic system based on copper­(I) and chiral bis­(phosphine) dioxides is described. This allows the arylation of silyl enol ethers to access…”
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Exploiting Chirality in Confined Nanospaces by Begato, Federico, Licini, Giulia, Zonta, Cristiano

“…Spatial organization using confinement has been of great interest since the early ages of supramolecular chemistry. Application such as sensing, catalysis and…”
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Programmed guest confinement via hierarchical cage to cage transformations by Begato, Federico, Licini, Giulia, Zonta, Cristiano

“…Taking inspiration from Nature, where (bio)molecular geometry variations are exploited to tune a large variety of functions, supramolecular chemistry has…”
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Catalytic Asymmetric Conjugate Reduction by Lonardi, Giovanni, Parolin, Riccardo, Licini, Giulia, Orlandi, Manuel

“…Enantioselective reduction reactions are privileged transformations for the construction of trisubstituted stereogenic centers. While these include established…”
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Combining Imine Condensation Chemistry with [3,3] Diaza‐Cope Rearrangement for One‐Step Formation of Hydrolytically Stable Chiral Architectures by Begato, Federico, Penasa, Roberto, Wurst, Klaus, Licini, Giulia, Zonta, Cristiano

“…Dynamic covalent chemistry (DCC) has, in recent years, provided valuable tools to synthesize molecular architectures of increasing complexity. We have also…”
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Programmed guest confinement hierarchical cage to cage transformations by Begato, Federico, Licini, Giulia, Zonta, Cristiano

“…Taking inspiration from Nature, where (bio)molecular geometry variations are exploited to tune a large variety of functions, supramolecular chemistry has…”
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Tris(2-pyridylmethyl)amines as emerging scaffold in supramolecular chemistry by Bravin, Carlo, Badetti, Elena, Licini, Giulia, Zonta, Cristiano

“…•TPMA, or TPA, complexes have increasing applications in supramolecular chemistry.•Biological sensing related to Zinc or hypoxia has been performed using this…”
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