Search Results - "LAU, Tobias"
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Isolation and Characterization of the Homoleptic Nickel(I) and Nickel(II) Bis‐benzene Sandwich Cations
Published in Angewandte Chemie International Edition (12-12-2022)“…A stable salt of the metalloradical [Ni(C6H6)2]+ hitherto unknown in the condensed phase was synthesized from [Ni(CO)4]+[WCA]− and benzene…”
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Soft X-ray signatures of cationic manganese-oxo systems, including a high-spin manganese(V) complex
Published in Physical chemistry chemical physics : PCCP (09-02-2022)“…Manganese-oxo species catalyze key reactions, including C-H bond activation or dioxygen formation in natural photosynthesis. To better understand relevant…”
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3
Intramolecular hydrogen transfer in DNA induced by site-selective resonant core excitation
Published in Physical chemistry chemical physics : PCCP (30-03-2022)“…We present experimental evidence for soft X-ray induced intramolecular hydrogen transfer in the protonated synthetic tri-oligonucleotide ( UAG) in the…”
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4
Mn12‐Acetate Complexes Studied as Single Molecules
Published in Chemistry : a European journal (10-01-2022)“…The phenomenon of single molecule magnet (SMM) behavior of mixed valent Mn12 coordination clusters of general formula [MnIII8MnIV4O12(RCOO)16(H2O)4] had been…”
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The role of N-terminal pro-brain natriuretic peptide, chromogranin A, and 5-hydroxyindoleacetic acid in screening for carcinoid heart disease
Published in Journal of neuroendocrinology (01-10-2023)“…Carcinoid heart disease (CHD) is a serious complication for patients with neuroendocrine tumors (NETs), and early detection is crucial. We aimed to investigate…”
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The Highest Oxidation State of Rhodium: Rhodium(VII) in [RhO3]
Published in Angewandte Chemie International Edition (19-09-2022)“…Although the highest possible oxidation states of all transition elements are rare, they are not only of fundamental interest but also relevant as potentially…”
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Direct Observation of Charge, Energy, and Hydrogen Transfer between the Backbone and Nucleobases in Isolated DNA Oligonucleotides
Published in Chemistry : a European journal (01-03-2023)“…Understanding how charge and energy, as well as protons and hydrogen atoms, are transferred in molecular systems as a result of an electronic excitation is…”
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Exposing the Oxygen‐Centered Radical Character of the Tetraoxido Ruthenium(VIII) Cation [RuO4]
Published in Chemphyschem (16-11-2023)“…The tetraoxido ruthenium(VIII) radical cation, [RuO4]+, should be a strong oxidizing agent, but has been difficult to produce and investigate so far. In our…”
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Access to the Bis‐benzene Cobalt(I) Sandwich Cation and its Derivatives: Synthons for a “Naked” Cobalt(I) Source?
Published in Angewandte Chemie International Edition (20-07-2018)“…The synthesis and structural characterization of the hitherto unknown parent Co(bz)2+ (bz=benzene) complex and several of its derivatives are described. Their…”
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10
Soft X‐ray Spectroscopy as a Probe for Gas‐Phase Protein Structure: Electron Impact Ionization from Within
Published in Chemistry : a European journal (28-05-2018)“…Preservation of protein conformation upon transfer into the gas phase is key for structure determination of free single molecules, for example using X‐ray…”
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11
The electronic structure and deexcitation pathways of an isolated metalloporphyrin ion resolved by metal L-edge spectroscopy
Published in Chemical science (Cambridge) (03-02-2021)“…The local electronic structure of the metal-active site and the deexcitation pathways of metalloporphyrins are crucial for numerous applications but difficult…”
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Near-Edge Soft X-ray Absorption Mass Spectrometry of Protonated Melittin
Published in Journal of the American Society for Mass Spectrometry (01-11-2018)“…We have investigated the photoionization and photofragmentation yields of gas-phase multiply protonated melittin cations for photon energies at the K-shell…”
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13
Maximum Spin Polarization in Chromium Dimer Cations as Demonstrated by X-ray Magnetic Circular Dichroism Spectroscopy
Published in Angewandte Chemie International Edition (07-04-2015)“…X‐ray magnetic circular dichroism spectroscopy has been used to characterize the electronic structure and magnetic moment of Cr2+. Our results indicate that…”
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Diminished Short- and Long-Term Antibody Response after SARS-CoV-2 Vaccination in Hemodialysis Patients
Published in Vaccines (Basel) (13-04-2022)“…Short-term studies have shown an attenuated immune response in hemodialysis patients after COVID-19-vaccination. The present study examines how antibody…”
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A comparative laboratory study of soft X-ray-induced ionization and fragmentation of five small PAH cations
Published in The European physical journal. D, Atomic, molecular, and optical physics (01-10-2023)“…The interaction between polycyclic aromatic hydrocarbon (PAH) radical cations and X-rays predominantly leads to photofragmentation, a process that strongly…”
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Lifetime of Poly(triaryl amine) Based Organic Field Effect Transistors under Different Environmental Conditions
Published in Japanese Journal of Applied Physics (01-04-2013)“…Characterization of reliability and lifetime is a key issue on the way to commercialization of products based on organic electronics. Prediction of the…”
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Intranasal Vaccination with Recombinant Adeno-Associated Virus Type 5 against Human Papillomavirus Type 16 L1
Published in Journal of Virology (01-03-2006)“…Article Usage Stats Services JVI Citing Articles Google Scholar PubMed Related Content Social Bookmarking CiteULike Delicious Digg Facebook Google+ Mendeley…”
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Magnetic nanodoping: Atomic control of spin states in cobalt doped silver clusters
Published in Physical review research (01-08-2023)“…The interaction of magnetic dopants with delocalized electron states can result in interesting many-body physics. Here, the magnetic properties of neutral and…”
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Abrupt Change from Ionic to Covalent Bonding in Nickel Halides Accompanied by Ligand Field Inversion
Published in Inorganic chemistry (24-06-2024)“…The electronic configuration of transition metal centers and their ligands is crucial for redox reactions in metal catalysis and electrochemistry. We…”
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Electronic Structure of the Complete Series of Gas-Phase Manganese Acetylacetonates by X‑ray Absorption Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (31-08-2023)“…Metal centers in transition metal–ligand complexes occur in a variety of oxidation states causing their redox activity and therefore making them relevant for…”
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