Search Results - "López García, José"
-
1
Trapping σ-Alkyl-Palladium(II) Intermediates with Arynes Encompassing Intramolecular C−H Activation: Spirobiaryls through Pd-Catalyzed Cascade Reactions
Published in Angewandte Chemie International Edition (07-11-2016)“…A palladium‐catalyzed cascade reaction based on the trapping of transient alkyl–PdII intermediates with arynes encompassing a C−H activation step has been…”
Get full text
Journal Article -
2
Double Heteroatom Functionalization of Arenes Using Benzyne Three-Component Coupling
Published in Angewandte Chemie International Edition (09-02-2015)“…Arynes participate in three‐component coupling reactions with N, S, P, and Se functionalities to yield 1,2‐heteroatom‐difunctionalized arenes. Using…”
Get full text
Journal Article -
3
Recent Advances on Synthetic Methodology Merging C-H Functionalization and C-C Cleavage
Published in Molecules (Basel, Switzerland) (13-12-2020)“…The functionalization of C-H bonds has become a major thread of research in organic synthesis that can be assessed from different angles, for instance…”
Get full text
Journal Article -
4
Ruthenium-Catalyzed Cascade CH Functionalization of Phenylacetophenones
Published in Angewandte Chemie International Edition (03-02-2014)“…Three orthogonal cascade CH functionalization processes are described, based on ruthenium‐catalyzed CH alkenylation. 1‐Indanones, indeno indenes, and indeno…”
Get full text
Journal Article -
5
Chasing C,C‐Palladacycles
Published in European journal of inorganic chemistry (24-09-2021)“…The different approaches for the synthesis of C,C‐palladacycles are reviewed in this manuscript. These species hold a bidentate ligand that chelates the Pd…”
Get full text
Journal Article -
6
Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N‑(2-Haloaryl)acrylamides
Published in Organometallics (27-11-2017)“…We have studied the possible reaction pathways operating in the Pd-catalyzed remote C–H functionalization of N-(2-haloaryl)acrylamides from an organometallic…”
Get full text
Journal Article -
7
Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study
Published in Chemical science (Cambridge) (2018)“…The mechanism of the palladium-catalyzed spirocyclization of acrylamides has been investigated by density functional theory and experimental studies. The…”
Get full text
Journal Article -
8
Poisson–Boltzmann Description of the Electrical Double Layer Including Ion Size Effects
Published in Langmuir (06-12-2011)“…The electrical double layer is examined using a generalized Poisson–Boltzmann equation that takes into account the finite ion size by modeling the aqueous…”
Get full text
Journal Article -
9
Use of 2‑Bromophenylboronic Esters as Benzyne Precursors in the Pd-Catalyzed Synthesis of Triphenylenes
Published in Organic letters (02-05-2014)“…ortho-Substituted aryl boronates are introduced as aryne precursors for transition-metal-catalyzed transformations. On treatment with t BuOK and Pd(0),…”
Get full text
Journal Article -
10
Arthroscopic findings and long‐term outcomes in 76 sport horses with meniscal injuries (2008–2018)
Published in Veterinary surgery (01-04-2022)“…Objective To report the findings and long‐term outcome of 76 sport horses with meniscal injury. Study design Retrospective case series. Animals Seventy‐six…”
Get full text
Journal Article -
11
Combined Ionic Size and Electrode Spacing Effects on the Differential Capacitance of Confined Electrolytic Cells
Published in Journal of physical chemistry. C (02-06-2022)“…Differential surface capacitance is a powerful analytical tool in electrochemistry being often used in the characterization of electrode–solution interfaces…”
Get full text
Journal Article -
12
Synthesis of Benzofused O- and N‑Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols
Published in Organometallics (14-03-2022)“…We report a Pd-catalyzed route to heterocycles bearing a tetrasubstituted alkene fragment. Our approach merges the intramolecular carbopalladation of tethered…”
Get full text
Journal Article -
13
SST Comparison of AVHRR and MODIS Time Series in the Western Mediterranean Sea
Published in Remote sensing (Basel, Switzerland) (01-07-2020)“…Sea Surface Temperature (SST) is a key parameter for understanding atmospheric and oceanic processes. Since the late 1980s, infrared satellite images have been…”
Get full text
Journal Article -
14
Cranial nuchal bursitis: Challenges and management options
Published in Equine veterinary education (01-05-2023)Get full text
Journal Article -
15
Long‐term prognosis for return to athletic function after interspinous ligament desmotomy for treatment of impinging and overriding dorsal spinous processes in horses: 71 cases (2012–2017)
Published in Veterinary surgery (01-10-2019)“…Objective To determine the long‐term return to performance of horses with impinging and/or overriding dorsal spinous processes (ORDSP) treated with…”
Get full text
Journal Article -
16
Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage
Published in Macromolecules (23-07-2024)“…A new approach to ring-opening polymerization (ROP) based on C(sp3)–C(sp3) bond cleavage is reported. This process is based on the ability of Pd to promote…”
Get full text
Journal Article -
17
Pd-Catalyzed Formal [2 + 2]-Retrocyclization of Cyclobutanols via 2‑Fold Csp3–Csp3 Bond Cleavage
Published in Journal of organic chemistry (04-01-2024)“…In this work, we describe the unexpected 2-fold Csp3–Csp3 bond cleavage suffered by cyclobutanols in the presence of a catalytic amount of Pd(OAc)2 and…”
Get full text
Journal Article -
18
Changes in the constituents of the “Bosque de Agua” of the Sierra Cruces-Ajusco-Chichinautzín, Mexico, an area with payment for environmental services
Published in Environmental earth sciences (01-10-2021)“…The “Bosque de Agua”, to the west and south of Mexico City, which is the fifth largest city in the world, has historically suffered disturbances in forest…”
Get full text
Journal Article -
19
Archaeal overdominance close to life‐limiting conditions in geothermally influenced hypersaline lakes at the Danakil Depression, Ethiopia
Published in Environmental microbiology (01-11-2021)“…Summary The Dallol protovolcanic area on the Danakil Depression (Afar region, Ethiopia) exhibits unique hydrothermal manifestations in hypersaline context,…”
Get full text
Journal Article -
20
Active Microbial Airborne Dispersal and Biomorphs as Confounding Factors for Life Detection in the Cell-Degrading Brines of the Polyextreme Dallol Geothermal Field
Published in mBio (26-04-2022)“…Determining the precise limits of life in polyextreme environments is challenging. Studies along gradients of polyextreme conditions in the Dallol…”
Get full text
Journal Article