Search Results - "Kyoon Park, Jin"
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Divergent C–H Annulation for Multifused N‐Heterocycles: Regio‐ and Stereospecific Cyclizations of N‐Alkynylindoles
Published in Angewandte Chemie International Edition (16-10-2017)“…N‐Alkynylindoles were divergently cyclized for the synthesis of multifused N‐heterocycles. An ortho‐aryl palladium species was added to the α position of an…”
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Regiodivergent Synthesis of 1,3‐ and 1,4‐Enynes through Kinetically Favored Hydropalladation and Ligand‐Enforced Carbopalladation
Published in Angewandte Chemie International Edition (26-07-2018)“…Pd‐catalyzed hydroalkynylations were developed that involve ligand‐enabled regiodivergent addition of an alkyne to an allenamide, giving branched and linear…”
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3
Regiodivergent Trifluoromethanesulfonic Acid‐Promoted Cycloisomerizations of Ynenamines to Fused Indoles
Published in Advanced synthesis & catalysis (01-04-2019)“…Trifluoromethanesulfonic acid (TfOH)‐mediated cycloisomerizations were controlled through the choice of the electron‐withdrawing functional group at C3 of…”
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4
Chemoselective Coupling of π‐Systems to Access Metallated 1,4‐ or 1,5‐Skipped Dienes in Multicomponent Reactions
Published in Chemistry : a European journal (09-12-2022)“…Integrating distinct unsaturated C−C systems while simultaneously installing metallic groups has been significantly challenging to execute in a multicomponent…”
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5
An Overview of Water‐Mediated Alkyne Functionalization by Neighboring Group Participation of Carbonyl Groups
Published in Advanced synthesis & catalysis (18-11-2020)“…Reviewed herein, the progress employing the assistance of a neighboring carbonyl group for alkyne functionalization reactions that are mediated by water…”
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6
Metal Nanozyme with Ester Hydrolysis Activity in the Presence of Ammonia‐Borane and Its Use in a Sensitive Immunosensor
Published in Angewandte Chemie International Edition (07-12-2020)“…Metal nanoparticle surfaces are used for peroxidase‐ and oxidase‐like nanozymes but not for esterase‐like nanozymes. It is challenging to obtain rapid…”
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7
Room-Temperature Transition-Metal-Free One-Pot Synthesis of 3‑Aryl Imidazo[1,2‑a]pyridines via Iodo-hemiaminal Intermediate
Published in Journal of organic chemistry (03-04-2015)“…A mild and efficient one-pot synthesis of 3-aryl imidazo[1,2-a]pyridines in up to 88% yield was developed. An adduct was formed after the simple mixing of…”
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8
A Modular Synthesis of 4-Aminoquinolines and [1,3] N-to-C Rearrangement to Quinolin-4-ylmethanesulfonamides
Published in Organic letters (04-08-2017)“…A copper-catalyzed regiocontrolled three-component reaction afforded diversified 4-aminoquinolines using nitriles, diaryliodoniums, and ynamides. The…”
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9
Recycling Chiral Imidazolidin-4-one Catalyst for Asymmetric Diels-Alder Reactions: Screening of Various Ionic Liquids
Published in Advanced synthesis & catalysis (01-01-2004)“…Various imidazolium ionic liquids such as [Bmim]PF6, [Bmim]SbF6, [Bmim]OTf and [Bmim]BF4 were screened for recycling an organic catalyst…”
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10
Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes
Published in Organic letters (21-09-2012)“…The catalytic regioselective hydroboration of propargylic alcohols and ethers was investigated using NHC-CuCl. We observe that different NHC-CuCl complexes…”
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Chemoselective Nitro Reduction Using Nitrogen‐Doped Carbon‐Encapsulated Ni Catalyst and Y‐Type Packed Bed Column for Continuous Flow Reaction
Published in Advanced synthesis & catalysis (04-07-2023)“…Selective reduction of nitro‐containing arenes and heteroarenes was achieved in 5 minutes at room temperature utilizing inexpensive NaBH4 as a hydrogen source…”
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12
Stereoconvergent Synthesis of Chiral Allylboronates from an E/Z Mixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst
Published in Journal of the American Chemical Society (02-03-2011)“…We present a 6-NHC−Cu(I) complex that provides α-substituted allylboronates using allylic aryl ether substrates. The method was discovered by comparison of the…”
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13
Iterative Asymmetric Allylic Substitutions: syn- and anti-1,2-Diols through Catalyst Control
Published in Angewandte Chemie International Edition (12-03-2012)“…A copper‐catalyzed asymmetric allylic boronation (AAB) gives access to syn‐ and anti‐1,2‐diols. The method facilitates an iterative strategy for the…”
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14
Rapid and Sensitive Electrochemical Detection of Carbaryl Based on Enzyme Inhibition and Thiocholine Oxidation Mediated by a Ruthenium(III) Complex
Published in Electroanalysis (New York, N.Y.) (01-02-2017)“…In the electrochemical detection method for pesticides that measures their inhibitory effects on acetylcholinesterases (AChEs), the direct electrooxidation of…”
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15
Highly Chemoselective Esterification from O‐Aminoallylation of Carboxylic Acids: Metal‐ and Reagent‐Free Hydrocarboxylation of Allenamides
Published in Chemistry : a European journal (02-11-2020)“…Metal‐free hydrocarboxylation of allenamides with various functionalized carboxylic acids were achieved with complete regio‐ and stereocontrol (>49:1). This…”
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Development of Structurally Diverse N-Heterocyclic Carbene Ligands via Palladium-Copper-Catalyzed Decarboxylative Arylation of Pyrazolo[1,5-a]pyridine-3-carboxylic Acid
Published in Advanced synthesis & catalysis (18-08-2016)“…A series of fused non‐classical normal N‐heterocyclic carbenes, Pyrpy‐NHC precursors derived from pyrazolo[1,5‐a]pyridines, has been prepared using…”
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17
An ultrasensitive and incubation-free electrochemical immunosensor using a gold-nanocatalyst label mediating outer-sphere-reaction-philic and inner-sphere-reaction-philic species
Published in Chemical communications (Cambridge, England) (30-04-2016)“…This communication reports a new nanocatalytic scheme based on the facts that the redox reaction between a highly outer-sphere-reaction-philic (OSR-philic)…”
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Continuous Synthesis and Use of N‑Heterocyclic Carbene Copper(I) Complexes from Insoluble Cu2O
Published in Organic letters (01-03-2013)“…It is demonstrated that homogeneous N-heterocyclic carbene–copper(I)-chloride complexes can be prepared continuously by flowing NHC precursors through a packed…”
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19
Palladium-Catalyzed Direct Arylations of 1,2-Azolo[1,5-a]pyridines using Copper(I) Chloride as a Lewis Acid Activator and the Synthesis of 2,6-Disubstituted Pyridines
Published in Advanced synthesis & catalysis (14-12-2015)“…A direct method for the arylation of 1,2‐azolo[1,5‐a]pyridines has been developed. In the process, the fused pyridines react with aryl halides in the presence…”
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20
N-benzyl-N-methyldecan-1-amine and its derivative mitigate 2,4- dinitrobenzenesulfonic acid-induced colitis and collagen-induced rheumatoid arthritis
Published in Frontiers in pharmacology (2023)“…As our previous study revealed that -benzyl- -methyldecan-1-amine (BMDA), a new molecule originated from , exhibits anti-neoplastic activities, we herein…”
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