Search Results - "Kyne, Sara H"

Insights into a Community of Inquiry that emerged during academics' emergency remote university teaching of chemistry in response to concern for students by Reyes, Charisse T., Thompson, Christopher D., Lawrie, Gwendolyn A., Kyne, Sara H.

“…Effective teaching of university chemistry in an online environment not only requires teachers to have specific discipline content knowledge; it also requires…”
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Elucidating Dramatic Ligand Effects on SET Processes: Iron Hydride versus Iron Borohydride Catalyzed Reductive Radical Cyclization of Unsaturated Organic Halides by Kyne, Sara H, Clémancey, Martin, Blondin, Geneviève, Derat, Etienne, Fensterbank, Louis, Jutand, Anny, Lefèvre, Guillaume, Ollivier, Cyril

“…An iron­(II) borohydride complex ([(η1-H3BH)­FeCl­(NCCH3)4]) is employed as the precatalyst in iron-catalyzed radical cyclizations of unsaturated organic…”
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Multiorbital Interactions during Acyl Radical Addition Reactions Involving Imines and Electron-Rich Olefins by Kyne, Sara H, Schiesser, Carl H, Matsubara, Hiroshi

“…Ab initio and DFT calculations reveal that acyl radicals add to imines and electron-rich olefins through simultaneous SOMO → π*, π → SOMO, and HOMO → π*C  O…”
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First determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl by Kyne, Sara H, Lin, Ching Yeh, Ryu, Ilhyong, Coote, Michelle L, Schiesser, Carl H

“…Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the…”
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An ab initio and DFT study of radical addition reactions of imidoyl and thioyl radicals to methanimine by Kyne, Sara H, Schiesser, Carl H, Matsubara, Hiroshi

“…Ab initio and DFT calculations reveal that both imidoyl and thioyl radicals add to the nitrogen end of methanimine through simultaneous SOMO-π*(imine),…”
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The COVID Cohort: Student Transition to University in the Face of a Global Pandemic by Kyne, Sara H, Thompson, Christopher D

“…In 2020, the rapid onset of a pandemic related to the disease known as COVID-19 resulted in a widespread lockdown of societies across the globe. Universities…”
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Dehydrocoupling Polymerization: Poly(silylether) Synthesis by Using an Iron β‐Diketiminate Catalyst by Farcaş‐Johnson, Mirela A., Kyne, Sara H., Webster, Ruth L.

“…We describe the iron‐catalyzed polymerizations of diol and silane monomers to obtain fourteen different poly(silylether) products with number average molecular…”
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Multi-component orbital interactions during oxyacyl radical addition reactions involving imines and electron-rich olefins by Kyne, Sara H, Schiesser, Carl H, Matsubara, Hiroshi

“…Ab initio and DFT calculations reveal that oxyacyl radicals add to imines and electron-rich olefins through simultaneous SOMO-pi*, SOMO-pi and pi*-HOMO…”
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Iron(II)-Catalyzed Activation of Si–N and Si–O Bonds Using Hydroboranes by Farcaş-Johnson, Mirela A., Gasperini, Danila, King, Andrew K., Mohan, Sakshi, Barrett, Adam N., Lau, Samantha, Mahon, Mary F., Sarazin, Yann, Kyne, Sara H., Webster, Ruth L.

“…We report the activation and functionalization of Si–N bonds with pinacol borane catalyzed by a three-coordinate iron­(II) β-diketiminate complex. The…”
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Enhancing Academic Performance and Student Success through Learning Analytics-Based Personalised Feedback Emails in First-Year Chemistry by Kyne, Sara H, Lee, Martin M. H, Reyes, Charisse T

“…Recent developments in digital technologies, including learning analytics are changing educational practices due to the wealth of information available and its…”
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''Every Little Thing That Could Possibly Be Provided Helps'': Analysis of Online First-Year Chemistry Resources Using the Universal Design for Learning Framework by Reyes, Charisse T, Lawrie, Gwendolyn A, Thompson, Christopher D, Kyne, Sara H

“…Rapid advancements in information and communication technologies (ICTs) have afforded numerous variations to traditional chemistry curricula where pedagogical…”
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The Transition to First Year Chemistry: Student, Secondary and Tertiary Educators' Perceptions of Student Preparedness by Leong, Elizabeth, Mercer, Agnes, Danczak, Stephen M, Kyne, Sara H, Thompson, Christopher D

“…Student preparedness is an essential component of transition to university influenced by a broad suite of attributes including academic aptitude, prior…”
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N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals by Kyne, Sara H, Schiesser, Carl H

“…N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies…”
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Use of Monosaccharides in Metal-Catalyzed Coupling Reactions by Kyne, Sara H, Camp, Jason E

“…The addition of monosaccharides to metal-catalyzed coupling reactions can be beneficial in terms of decreasing the time required, chemical waste products and…”
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Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand by Perić, Marko, Kyne, Sara H., Gruden, Maja, Rodić, Marko, Jeremić, Dejan, Stanković, Dalibor M., Brčeski, Ilija

“…In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine…”
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Executing and Rationalizing the Synthesis of a Difluorinated Analogue of a Ring-Expanded Calystegine B2 by Kyne, Sara H, Miles, Jonathan A. L, Percy, Jonathan M, Singh, Kuldip

“…A difluorinated analogue of a ring-expanded calystegine B2 and some N-protected species were prepared via microwave-mediated transannular ring-opening of an…”
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Implementing blended first-year chemistry in a developing country using online resources by Reyes, Charisse Tongson, Kyne, Sara Helen, Lawrie, Gwendolyn Angela, Thompson, Christopher David

“…Decades of rapid development in information and communication technologies (ICTs) have resulted in tremendous global evolution in computer and online…”
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Why is RCM Favoured Over Dimerisation? Predicting and Estimating Thermodynamic Effective Molarities by Solution Experiments and Electronic Structure Calculations by Nelson, David J., Ashworth, Ian W., Hillier, Ian H., Kyne, Sara H., Pandian, Shanthi, Parkinson, John A., Percy, Jonathan M., Rinaudo, Giuseppe, Vincent, Mark A.

“…The thermodynamic effective molarities of a series of simple cycloalkenes, synthesised from α,ω‐dienes by reaction with Grubbs’ second generation precatalyst,…”
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7-Selenabicyclo[2.2.1]heptane by Macdougall, Phoebe E, Aitken, Heather M, Scammells, Peter J, Kavanagh, Yvonne, Kyne, Sara H, Schiesser, Carl H

“…Thermolysis of a benzene solution of N-[4-(p-(methoxybenzyl)seleno)cyclohexanoyl]-N,S-dimethyldithiocarbonate affords the hitherto unknown…”
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Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study by Kyne, Sara H, Aitken, Heather M, Schiesser, Carl H, Lacôte, Emmanuel, Malacria, Max, Ollivier, Cyril, Fensterbank, Louis

“…Ab initio and density functional theory (DFT) calculations predict that intramolecular homolytic substitution by alkyl radicals at the sulfur atom in…”
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