Search Results - "Kwak, Kyuju"
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Electrochemistry of Atomically Precise Metal Nanoclusters
Published in Accounts of chemical research (15-01-2019)“…Thiolate-protected metal nanoparticles containing a few to few hundred metal atoms are interesting materials exhibiting unique physicochemical properties. They…”
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Ultrabright Luminescence from Gold Nanoclusters: Rigidifying the Au(I)–Thiolate Shell
Published in Journal of the American Chemical Society (01-07-2015)“…Luminescent nanomaterials have captured the imagination of scientists for a long time and offer great promise for applications in organic/inorganic…”
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3
A molecule-like PtAu24(SC6H13)18 nanocluster as an electrocatalyst for hydrogen production
Published in Nature communications (10-03-2017)“…The theoretically predicted volcano plot for hydrogen production shows the best catalyst as the one that ensures that the hydrogen binding step is…”
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4
Interconversion between Superatomic 6‑Electron and 8‑Electron Configurations of M@Au24(SR)18 Clusters (M = Pd, Pt)
Published in Journal of the American Chemical Society (26-08-2015)“…The exceptional stability of thiolate-protected Au25 clusters, [Au25(SR)18]−, arises from the closure of superatomic electron shells, leading to a…”
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5
Energy Gap Law for Exciton Dynamics in Gold Cluster Molecules
Published in The journal of physical chemistry letters (05-10-2017)“…The energy gap law relates the nonradiative decay rate to the energy gap separating the ground and excited states. Here we report that the energy gap law can…”
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6
Ionic Liquid of a Gold Nanocluster: A Versatile Matrix for Electrochemical Biosensors
Published in ACS nano (28-01-2014)“…Ionic liquids are room-temperature molten salts that are increasingly used in electrochemical devices, such as batteries, fuel cells, and sensors, where their…”
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Effects of Metal-Doping on Hydrogen Evolution Reaction Catalyzed by MAu24 and M2Au36 Nanoclusters (M = Pt, Pd)
Published in ACS applied materials & interfaces (26-12-2018)“…This paper describes the effects of doped metals on hydrogen evolution reaction (HER) electrocatalyzed by atomically controlled MAu24 and M2Au36 nanoclusters,…”
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Over a 15.9% Solar-to-CO Conversion from Dilute CO2 Streams Catalyzed by Gold Nanoclusters Exhibiting a High CO2 Binding Affinity
Published in ACS energy letters (13-03-2020)“…Development of efficient and selective electrocatalysts is a key challenge to achieve an industry-relevant electrochemical CO2 reduction reaction (CO2RR) to…”
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Temperature-Dependent Absorption and Ultrafast Exciton Relaxation Dynamics in MAu24(SR)18 Clusters (M = Pt, Hg): Role of the Central Metal Atom
Published in Journal of physical chemistry. C (13-10-2016)“…Temperature-dependent and ultrafast transient absorption measurements were carried out to probe the optical properties and exciton relaxation dynamics in…”
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10
Electrochemical Sensing Using Quantum-Sized Gold Nanoparticles
Published in Analytical chemistry (Washington) (01-05-2011)“…This paper describes the electrocatalytic activity of quantum-sized thiolate protected Au25 nanoparticles and their use in electrochemical sensing. The Au25…”
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Electrochemical Characterization of Water-Soluble Au25 Nanoclusters Enabled by Phase-Transfer Reaction
Published in The journal of physical chemistry letters (06-09-2012)“…We report the synthesis and electrochemical characterization of a new water-soluble Au25 cluster protected with (3-mercaptopropyl)sulfonate. The presence of…”
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Efficient Oxygen Reduction Electrocatalysts Based on Gold Nanocluster-Graphene Composites
Published in ChemElectroChem (01-08-2016)“…This paper describes the preparation and electrocatalytic activity of nanocomposites composed of reduced graphene oxide and Au25 clusters. Well‐defined…”
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13
Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control
Published in Chemical communications (Cambridge, England) (01-01-2013)“…Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through…”
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14
Electrochemical Characterization of Water-Soluble Au 25 Nanoclusters Enabled by Phase-Transfer Reaction
Published in The journal of physical chemistry letters (06-09-2012)Get full text
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15
Directional Electron Transfer in Chromophore-Labeled Quantum-Sized Au25 Clusters: Au25 as an Electron Donor
Published in The journal of physical chemistry letters (06-05-2010)“…Novel Au25(C6S)17PyS clusters (pyrene-functionalized Au25 clusters) showing interesting electrochemical and optical properties are synthesized and…”
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Effects of Metal-Doping on Hydrogen Evolution Reaction Catalyzed by MAu 24 and M 2 Au 36 Nanoclusters (M = Pt, Pd)
Published in ACS applied materials & interfaces (26-12-2018)“…This paper describes the effects of doped metals on hydrogen evolution reaction (HER) electrocatalyzed by atomically controlled MAu and M Au nanoclusters,…”
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17
Evaluation of the electrochemical stability, interfacial reaction, and molecular behavior of ether-functionalized pyrrolidinium as novel electrolyte for lithium metal battery by quantum and molecular dynamics simulations
Published in Applied surface science (30-10-2022)“…[Display omitted] •Providing a basis for the design and functionalization of potential ionic liquids using pyrrolidinium for lithium metal…”
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Dopant-Dependent Electronic Structures Observed for M2Au36(SC6H13)24 Clusters (M = Pt, Pd)
Published in The journal of physical chemistry letters (01-03-2018)“…Heteroatom doping is a powerful means to tune the optical and electronic properties of gold clusters at the atomic level. We herein report that doping a Au38…”
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19
Ultrafast Electron Dynamics in Thiolate-Protected Plasmonic Gold Clusters: Size and Ligand Effect
Published in Journal of physical chemistry. C (30-05-2019)“…The influence of passivating ligands on electron–phonon relaxation dynamics of the smallest-sized gold clusters was studied using ultrafast transient…”
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Selective determination of dopamine using quantum-sized gold nanoparticles protected with charge selective ligands
Published in Nanoscale (21-07-2012)“…We report here the selective determination of dopamine (DA) using quantum-sized gold nanoparticles coated with charge selective ligands. Glutathione protected…”
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