Search Results - "Kuzmina, Lyudmila G."
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1
Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis
Published in Journal of the American Chemical Society (28-01-2009)“…New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition…”
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2
Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3
Published in Inorganic chemistry (02-04-2012)“…The reaction of (ArN=)MoCl2(PMe3)3 (Ar = 2,6-diisopropylphenyl) with L-Selectride gives the hydrido-chloride complex (ArN=)Mo(H)(Cl)(PMe3)3 (2). Complex 2 was…”
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3
Agostic NSi----H···Mo Complexes: From Curiosity to Catalysis
Published in Angewandte Chemie (International ed.) (22-09-2008)“…An uncommon catalyst: The β‐agostic NSiH⋅⋅⋅M complex 1 (Ar=2,6‐diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions…”
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4
An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum
Published in Inorganic chemistry (16-01-2012)“…Carbonyl hydrosilylation catalyzed by (ArN)Mo(H)(SiH2Ph)(PMe3)3 (3) is unusual in that it does not involve the expected Si–O elimination from intermediate…”
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5
Unusual Structure, Fluxionality, and Reaction Mechanism of Carbonyl Hydrosilylation by Silyl Hydride Complex [(ArN)Mo(H)(SiH2Ph)(PMe3)3]
Published in Chemistry : a European journal (24-06-2013)“…The reactions of bis(borohydride) complexes [(RN)Mo(BH4)2(PMe3)2] (4: R=2,6‐Me2C6H3; 5: R=2,6‐iPr2C6H3) with hydrosilanes afford new silyl hydride derivatives…”
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6
Study of Lithium-Extraction Systems Based on Benzo-15-Crown-5 Ether and Alkylimidazolium-Based Ionic Liquid
Published in Molecules (Basel, Switzerland) (17-01-2023)“…The extraction of lithium from aqueous solutions of LiNTf and LiCl salts using benzo-15-crown-5 ether (B15C5) as an extractant in [C8mim][NTf ] ionic liquid…”
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7
Niobium/Rhodium Bimetallic Complexes: Synthesis, Structure, and Catalytic Hydrosilylation of Acetophenone and Benzaldehyde
Published in Organometallics (10-08-2009)“…Reactions of a new imido phosphido complex, Cp2Nb(NBut)(PPh2) (1), with olefin complexes of rhodium afford two types of compounds. With [(μ-Cl)Rh(C2H4)2]2, an…”
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8
Synthesis, Structure and Photochemistry of Dibenzylidenecyclobutanones
Published in Molecules (Basel, Switzerland) (01-11-2022)“…A series of symmetrical dibenzylidene derivatives of cyclobutanone were synthesized with the goal of studying the physicochemical properties of…”
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9
Nonhydride Mechanism of Metal-Catalyzed Hydrosilylation
Published in Journal of the American Chemical Society (04-05-2011)“…A 1:1:1 reaction between complex (Tp)(ArN)Mo(H)(PMe3) (3), silane PhSiD3, and carbonyl substrate established that hydrosilylation catalyzed by 3 is not…”
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10
Oxidative Addition of Disulfides, Alkyl Sulfides, and Diphosphides to an Aluminum(I) Center
Published in Inorganic chemistry (06-09-2016)“…The aluminum(I) compound NacNacAl (1) reacts with diphenyl disulfide and diethyl sulfide to form the respective four-coordinate bis(phenyl sulfide) complex…”
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11
Pseudodimeric Complexes of an (18-Crown-6)stilbene with Styryl Dyes Containing an Ammonioalkyl Group: Synthesis, Structure, and Stereospecific [2 + 2] Cross-Photocycloaddition
Published in Journal of organic chemistry (19-02-2021)“…A new efficient method was proposed for the synthesis of (18-crown-6)stilbene; the structure of the product was confirmed by X-ray diffraction analysis. In…”
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12
Pharmaceutical Cocrystals of Diflunisal and Diclofenac with Theophylline
Published in Molecular pharmaceutics (06-10-2014)“…Pharmaceutical cocrystals of nonsteroidal anti-inflammatory drugs diflunisal (DIF) and diclofenac (DIC) with theophylline (THP) were obtained, and their…”
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13
Synthesis, Structure, and Properties of Supramolecular Photoswitches Based on Ammonioalkyl Derivatives of Crown Ether Styryl Dyes
Published in Journal of organic chemistry (05-12-2014)“…The synthesis of new styryl dyes derived from 4-pyridine and 4-quinoline and having an ammonioalkyl N-substituent and benzocrown ether moieties of different…”
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14
Syntheses and X-ray Diffraction Studies of Half-Sandwich Hydridosilyl Complexes of Ruthenium
Published in Organometallics (14-02-2005)“…The reactions of a series of half-sandwich trihydrides of ruthenium, Cp*(R3P)Ru(H)3 (R3P = Pri 3P, Pri 2MeP, PriMe2P, PhMe2P), with a family of chlorosilanes…”
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15
Imido silyl complexes of molybdenum: synthesis, structure, and unusual H2/silane exchange
Published in Canadian journal of chemistry (2021)“…Reaction of complex (ArN)Mo(H)(Cl)(PMe 3 ) 3 ( 1 ) with BPh 3 and silane H 3 SiPh affords a new silyl complex (ArN)Mo(SiH 2 Ph)(Cl)(PMe 3 ) 2 ( 3 ) that…”
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16
Fenamate Cocrystals with 4,4′-Bipyridine: Structural and Thermodynamic Aspects
Published in Crystal growth & design (07-01-2015)“…Cocrystallization of nonsteroidal anti-inflammatory drug fenamates (N-phenylanthranilic acid (N-PA), niflumic acid0 (NFA), flufenamic acid (FFA), tolfenamic…”
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17
Pseudodimeric complexes of 4-styrylpyridine derivatives: Structure–property relationships and a stereospecific [2+2]-cross-photocycloaddition in solution
Published in Dyes and pigments (01-01-2020)“…The study addresses the spectral and photochemical properties of N-(3-ammoniopropyl)-4-styrylpyridinium diperchlorate and its substituted analogs containing…”
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18
Cp(Pr i 2MeP)FeH2SiR3: Nonclassical Iron Silyl Dihydride
Published in Journal of the American Chemical Society (26-03-2008)“…Reactions of a new borohydride complex 2 with hydrosilanes afford half-sandwich dihydride silyl complexes 3a−f. According to X-ray and DFT evidence complexes 3…”
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19
Structure–Property Relationships of Dibenzylidenecyclohexanones
Published in ACS omega (29-03-2022)“…A series of symmetrical dibenzylidene derivatives of cyclohexanone were synthesized with the goal of studying the physicochemical properties of…”
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20
Supramolecular Dimerization and [2 + 2] Photocycloaddition Reactions of Crown Ether Styryl Dyes Containing a Tethered Ammonium Group: Structure–Property Relationships
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (31-12-2015)“…Molecular self-assembly is an effective strategy for controlling the [2 + 2] photocycloaddition reaction of olefins. The geometrical properties of…”
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