Search Results - "Kuş, Melih"
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Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: A Diastereoselective Method for the Synthesis of 7‑Hydroxy-2,3,5-trienoates
Published in Journal of organic chemistry (05-06-2015)“…Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured…”
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Iron-Promoted 1,5-Substitution Reaction of Endocyclic Enyne Oxiranes with MeMgBr: A Stereoselective Method for the Synthesis of Exocyclic 2,4,5-Trienol Derivatives
Published in Chemistry an international journal (01-12-2023)“…The iron-promoted 1,5-substitution reaction of endocyclic oxiranes with MeMgBr yields exocyclic 2,4,5-trienols with high diastereomeric ratios of up to 100:0…”
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3
Palladium-catalysed reactions of conjugated enyne oxiranes with organoborons: A diastereoselective method of the synthesis of 2,4,5-trienol derivatives
Published in Tetrahedron (05-07-2018)“…A palladium-catalysed reaction of conjugated enyne oxiranes with organoboron reagents is described. This method allows aryl-substituted vinylallenes containing…”
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4
Palladium-Catalyzed Alkoxycarbonylation of (Z)-2-En-4-yn Carbonates Leading to 2,3,5-Trienoates
Published in Organic letters (18-02-2011)“…Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an…”
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Regio- and Stereoselective Synthesis of 2,3,5-Trienoates by Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Carbonates
Published in Journal of organic chemistry (03-10-2014)“…Palladium-catalyzed carbonylation of 2,4-enyne carbonates in an alcohol and under balloon pressure of CO proceeds through 1,5-substitution to yield…”
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Rhodium-Catalysed Alkoxycarbonylative Cyclisation Reactions of 1,6-Enynes
Published in Advanced synthesis & catalysis (18-04-2011)“…The rhodium‐catalysed carbonylation of 1,6‐enynes possessing an electron‐deficient alkenyl moiety in an alcohol reagent in the presence of a rhodium complex…”
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Iron‐Promoted 1,5‐Substitution (SN2′′) Reactions of Enyne Acetates and Oxiranes with Grignard Reagents
Published in Asian journal of organic chemistry (01-10-2017)“…Acetate derivatives of 2‐en‐4‐yne alcohols 1 and enyne oxiranes 4 regioselectively underwent 1,5‐substitution (SN2′′) reactions with Grignard reagents in the…”
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Rhodium catalyzed reaction of internal alkynes with organoborons under CO atmosphere: a product tunable reaction
Published in Tetrahedron (07-11-2009)“…Alkynes react with organoborons under a CO atmosphere in the presence of a rhodium(I) catalyst to afford mainly 5-aryl-2(5 H)-furanones, α,β-unsaturated…”
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Journal Article -
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Rhodium- and Palladium-Catalyzed 1,5-Substitution Reactions of 2-En-4-yne Acetates and Carbonates with Organoboronic Acids
Published in Journal of organic chemistry (05-08-2011)“…Two methods involving the rhodium-catalyzed reaction of 2-en-4-yne acetates and the palladium-catalyzed reaction of 2-en-4-yne carbonates with organoboronic…”
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Cover Feature: Iron‐Promoted 1,5‐Substitution (SN2′′) Reactions of Enyne Acetates and Oxiranes with Grignard Reagents (Asian J. Org. Chem. 10/2017)
Published in Asian journal of organic chemistry (01-10-2017)“…Iron Age: Iron‐promoted reactions of enyne oxiranes or acetate derivatives of 2‐en‐4‐yne alcohols with Grignard reagents produce (E)‐configured vinylallenes…”
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Rhodium catalysed chemo- and stereoselective arylative and alkenylative cyclisation reactions of unsymmetric diynes containing a terminal alkyne moiety with organoboronic acids
Published in Organic & biomolecular chemistry (01-01-2010)“…Unsymmetric diynes possessing a terminal alkyne moiety reacted with organoboronic acids both chemo- and stereoselectively to afford arylated or alkenylated…”
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Journal Article -
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Transition Metal Catalayzed 1,5-Substitution Reactions of Conjugated Enyne Oxiranes Leading to Allylic Hydroxy Substituted Vinylallenes
Published 01-01-2015“…Transition metal-catalyzed reactions are atom economical and environmentally benign processes, which make them superior to traditional stoichiometric…”
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Dissertation -
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Synthesis of α,β-Unsaturated Ketones by Rhodium-Catalyzed Carbonylative Arylation of Internal Alkynes with Arylboronic Acids
Published 01-01-2009“…α,β-Unsaturated ketones are important key reagents in organic synthesis. They are commonly synthesised through an aldol condensation reaction.Since Hayashi et…”
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Dissertation