Octathiotetraphosphetanes-Novel class of biologically active phosphorusorganic compounds: Synthesis, structure, properties

Reaction of white phosphorus with elemental sulfur and proton-donating reagents such as thiols and diols in the presence of different amines were studied. Octathiotetraphosphetane ammonium salts, ammonium salts of S,S′-dialkyltetratiophosphoric and O,O′-propylendithiophosphoric acids were obtained f...

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Bibliographic Details
Published in:	Phosphorus, sulfur, and silicon and the related elements Vol. 191; no. 11-12; pp. 1642 - 1643
Main Authors:	Batyeva, E. S., Badeeva, E. K., Sinyashin, O. G., Nizamov, I. S., Frolova, L. V., Rogelj, S., Kurcheva, L. I.
Format:	Journal Article
Language:	English
Published:	Abingdon Taylor & Francis 01-12-2016 Taylor & Francis Ltd
Subjects:	amines diols microwave octathiotetraphosphetanes Phosphorus sulfur
Online Access:	Get full text
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Summary:	Reaction of white phosphorus with elemental sulfur and proton-donating reagents such as thiols and diols in the presence of different amines were studied. Octathiotetraphosphetane ammonium salts, ammonium salts of S,S′-dialkyltetratiophosphoric and O,O′-propylendithiophosphoric acids were obtained from the reactions. Red phosphorus reacted with sulfur and amines in the presence of microwave irradiation to form ammonium octathiotetraphosphetanes in high yields.
ISSN:	1042-6507 1563-5325
DOI:	10.1080/10426507.2016.1223663