Search Results - "Kumar Lahiri, Goutam"
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Unconventional Mixed-Valent Complexes of Ruthenium and Osmium
Published in Angewandte Chemie International Edition (01-01-2007)“…Recent developments have helped to extend the repertoire of mixed‐valent ruthenium and osmium complexes beyond conventional systems. This extension has been…”
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Transition Metals and Transition Metals/Lewis Acid Cooperative Catalysis for Directing Group Assisted para-C–H Functionalization
Published in Chemistry letters (05-11-2020)“…In the past few decades, synthetic organic chemistry has been invigorated with the development of transition metal catalyzed directing group assisted…”
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The coordination potential of indigo, anthraquinone and related redox-active dyes
Published in Coordination chemistry reviews (15-08-2019)“…[Display omitted] •Metal coordination affects the redox behavior of dye chromophores.•Electron transfer sites may involve the metal and/or the dye…”
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Metal-coordinated azoaromatics: Strategies for sequential azo-reduction, isomerization and application potential
Published in Coordination chemistry reviews (15-01-2023)“…[Display omitted] •Redox non-innocence of metalated azoheteroarenes.•Varying strategies for the sequential azo reductions including its scission.•Catalytic…”
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Azo Appended Modified Lawsone Derived Ru‐Systems with Multi‐Redox Entities. Competitive Electronic Form and the Question of Azo Reduction
Published in Chemistry : a European journal (21-04-2023)“…The article dealt with the ruthenium complexes of redox active azo appended modified lawsone L1− (HL1:…”
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Bond Activations Assisted by Redox Active Ligand Scaffolds
Published in European journal of inorganic chemistry (07-04-2020)“…Redox active ligands are an integral part of many biological events and significant natural processes. Transformations assisted by such ligands gather the…”
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Dioxygen Activation by Redox‐Active Bis(aldimine) Ligand Bridged Diruthenium Complex Possessing Singlet Ground State
Published in Chemistry : a European journal (11-11-2022)“…The unexplored ‘actor’ behavior of redox‐active bis(aldimine) congener, p‐phenylene‐bis(picoline)aldimine (L1), towards dioxygen activation and subsequent…”
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Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4− Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species
Published in Chemistry : a European journal (13-07-2009)“…New tris(ferrocenylcopper) compounds [(μ3‐dqp){Cu(dppf)}3][X]3 (dppf=1,1′‐bis(diphenylphosphinoferrocene), dqp=hexamethyl‐, hexachloro‐ or un‐substituted…”
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Nickel-Catalyzed Deamidative Step-Down Reduction of Amides to Aromatic Hydrocarbons
Published in ACS catalysis (06-01-2017)“…To date, cleavage of the C−N bond in aromatic amides has been achieved in molecules with a distorted constitutional framework around the nitrogen atom. In this…”
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Energy-efficient CO2/CO interconversion by homogeneous copper-based molecular catalysts
Published in Nature communications (27-10-2023)“…Facile conversion of CO 2 to commercially viable carbon feedstocks offer a unique way to adopt a net-zero carbon scenario. Synthetic CO 2 -reducing catalysts…”
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Expanding chemical space by para-C−H arylation of arenes
Published in Nature communications (08-07-2022)“…Biaryl scaffolds are privileged templates used in the discovery and design of therapeutics with high affinity and specificity for a broad range of protein…”
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The Electron-Rich {Ru(acac)2} Directed Varying Configuration of the Deprotonated Indigo and Evidence for Its Bidirectional Noninnocence
Published in Inorganic chemistry (01-02-2016)“…This article highlights the hitherto unexplored varying binding modes of the deprotonated natural dye indigo (H2L) and its bidirectional noninnocent potential…”
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Ruthenium‐Catalyzed Aerobic Oxidation of Amines
Published in Chemistry, an Asian journal (04-09-2018)“…Amine oxidation is one of the fundamental reactions in organic synthesis as it leads to a variety of value‐added products such as oximes, nitriles, imines, and…”
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Ruthenium‐Mediated Distal C−H Activation
Published in Chemistry, an Asian journal (04-09-2018)“…Addressing remote C−H functionalization is a prominent challenge in the field of homogeneous catalysis. The past two decades have accounted for major…”
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Ruthenium Derivatives of in Situ Generated Redox-Active 1,2-Dinitrosobenzene and 2‑Nitrosoanilido. Diverse Structural and Electronic Forms
Published in Inorganic chemistry (19-12-2016)“…The article describes one-pot synthesis and structural elucidation of tc-[RuII(pap)2(L•–)]ClO4 [1]ClO4 and tc-[RuII(pap)2(L′–)]ClO4 [2]ClO4, which were…”
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Mixed valency in ligand-bridged diruthenium frameworks: divergences and perspectives
Published in RSC advances (01-01-2018)“…The present review article illustrates the mixed valence aspects of ligand-bridged symmetric and unsymmetric diruthenium complexes beyond the textbook example…”
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Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes
Published in Inorganic chemistry (21-03-2016)“…Complexes of singly or doubly deprotonated indigo (H2Ind) with one or two [Ru(pap)2]2+ fragments (pap = 2-phenylazopyridine) have been characterized…”
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Structural and Electronic Diversity as a Function of Metal Ions and Co‐ligands in Deprotonated Epindolidione Bridged Diruthenium and Diosmium Set‐up
Published in European journal of inorganic chemistry (12-02-2024)“…The article dealt with the structurally validated L2− (H2L=epindolidione=5,11‐dihydroquinolino[3,2‐b]quinoline‐6,12‐dione, a heteroatom‐modified tetracene and…”
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Electronic structure alternatives in nitrosylruthenium complexes
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2010)“…Coordination compounds [Ru(NO)L(n)] containing an electro-active metal and potentially non-innocent ligands NO (and L) can have ground state electronic…”
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Author Correction: Expanding chemical space by para-C−H arylation of arenes
Published in Nature communications (25-08-2022)Get full text
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