Search Results - "Kumar, Kaipenchery A"

Evaluation of Binding Selectivities of Caged Crown Ligands toward Heavy Metals by Electrospray Ionization/Quadrupole Ion Trap Mass Spectrometry by Blair, Sheryl M, Brodbelt, Jennifer S, Marchand, Alan P, Kumar, Kaipenchery A, Chong, Hyun-Soon

“…Electrospray ionization (ESI)/quadrupole ion trap mass spectrometry is used to evaluate the heavy metal binding selectivities of five caged crown ethers and…”
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Convenient Acylative Dealkylation of Tertiary Amines by Dave, Paritosh R, Kumar, Kaipenchery A, Duddu, Rajagopal, Axenrod, Theodore, Dai, Rongji, Das, Kajal K, Guan, Xiao-Pei, Sun, Jianguang, Trivedi, Nirupam J, Gilardi, Richard D

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Computational Studies of Inclusion Phenomena and Synthesis of a Novel and Selective Molecular Receptor for 1,4-Disubstituted Benzenes and 4,4‘-Disubstituted Biphenyls by Macias, Alba T, Kumar, Kaipenchery A, Marchand, Alan P, Evanseck, Jeffrey D

“…A new tetracationic molecular receptor has been synthesized and studied by semiempirical molecular orbital theory. This novel macrocycle, 1 4+, derived from…”
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Generation and trapping of a caged cyclopentylidenecarbene by Marchand, Alan P, Kumar, Kaipenchery A, Rajagopal, D, Eckrich, Ralf, Bott, Simon G

“…The reactive intermediate that is produced both (i) via reaction of 8-(dibromomethylene)-pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]unndecane ( 6) with n-BuLi-THF and…”
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Synthesis of an unusual, cage-functionalized molecular cleft by PINKERTON, A. Alan, HARDIE, Michaele J, MARCHAND, Alan P, KUMAR, Kaipenchery A

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Synthesis and alkali metal picrate extraction capabilities of novel cage-functionalized 17-crown-5 and 17-crown-6 ethers by Marchand, Alan P., Kumar, Kaipenchery A., McKim, Artie S., Mlinarié-Majerski, Kata, Kragol, Goran

“…The syntheses of three novel cage-functionalized 17-crown-5 and 17-crown-6 ethers, i.e., 10–12, are reported and the results of alkali metal picrate extraction…”
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Synthesis and alkali metal picrate extraction capabilities of novel, cage-functionalized diazacrown ethers. Effects of host preorganization on avidity and selectivity toward alkali metal picrates in solution by Marchand, Alan P., McKim, Artie S., Kumar, Kaipenchery A.

“…The synthesis of a series of cage-functionalized bis(monoazacrown) ethers and bis(diaza-crown) ethers is described. Alkali metal picrate extraction profiles…”
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Synthesis and alkali metal picrate extraction capabilities of a 4-oxahexacyclo[5.4.1.0 2,6.0 3,10.0 5,9.0 8,11]dodecane-derived cryptand. A new ionophore for selective ion complexation by Marchand, Alan P., Alihodžić, Sulejman, McKim, Artie S., Kumar, Kaipenchery A., Mlinarić-Majerski, Kata, Šumanovae, Tatjana, Bott, Simon G.

“…The synthesis of a novel cage-functionalized cryptand, 5, and the X-ray crystal structure of its 1:1 complex with Na +, i.e. 4, are reported. Host molecule 5…”
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Intermolecular vs. Intramolecular carbene reactions of a cage-functionalized cyclopentylcarbene by Marchand, Alan P., Kumar, Kaipenchery A., Mlinarić-Majerski, Kata, Veljković, Jelena

“…The results of carbene reactions of pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecan-8-ylidene (i.e., PCU-8-ylidene, 9), generated under different conditions by…”
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Evaluation of binding selectivities of caged crown ligands toward heavy metals by electrospray lonization/quadrupole lon trap mass spectrometry by BLAIR, Sheryl M, BRODBELT, Jennifer S, MARCHAND, Alan P, KUMAR, Kaipenchery A, CHONG, Hyun-Soon

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Syntheses of bis- and tetra-crowned clefts and studies of their selectivities in metal ion complexation by Bartsch, Richard A., Eley, Mark D., Marchand, Alan P., Shukla, Rajesh, Kumar, Kaipenchery A., Madhusudhan Reddy, G.

“…A novel “tetra[benzo(18-crown-6)]-crowned cleft” ( 2) and two new “bis[benzo(15-crown-5)]-crowned clefts” ( 3 and 4) have been synthesized. Their respective…”
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Molecular design of lipophilic disalicylic acid compounds with varying spacers for selective lead(II) extraction by Hayashita, Takashi, Higuchi, Takaaki, Sawano, Hyozo, Marchand, Alan P., Kumar, Kaipenchery A., Bott, Simon G., Mlinarić-Majerski, Kata, Šumanovac, Tatjana, Elkarim, Nazar S.A., Hwang, Hong-Sik, Talanova, Galina G., Bartsch, Richard A.

“…Lipophilic disalicylic acids 5,5′-decyl-2,2′-[1,2-ethanediylbis(oxy)]bisbenzoic acid ( 1), 5,5′-decyl-2,2′-[1,3-propanediylbis(oxy)]bisbenzoic acid ( 2),…”
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Acid and base promoted rearrangements of Hexacyclo[11.2.1.0 2,12.0 5,10.0 5.15.0 10,14]hexadeca-6,8-diene-4,11-dione by Marchand, Alan P., Chong, Hyun-Soon, Shukla, Rajesh, Sharma, G.V.M., Kumar, Kaipenchery A., Zope, Umesh R., Bott, Simon G.

“…Hexacyclo[11.2.1.0 2,12.0 5,10.0 5,15.0 10,14]hexadeca-6,8-diene-4,11-dione ( 3) was synthesized via ring-expansion of hexacyclo[10.2.1.0 2,11.0 4,9.0 4,14.0…”
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Novel reduction (Zn-AcOH) of DDHQ esters. A new route to tropone synthesis by Kasturi, Tirumalai R., Palle, Pragnacharyulu V.P., Sattigeri, Jitendra A., Kumar, Kaipenchery A.

“…Zn/acetic acid reaction of DDHQ esters 1 a–d gave the saturated acids 3 a–d and the hydrocarbons 7 a–d. The intermediacy of the aldehydes 10 and 11 in the…”
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Synthesis and thermal rearrangement of pentacyclo[6.5.0.0 4,12.0 5,10.0 9,13]trideca-2,6-diene by Marchand, Alan P., Rajapaksa, Dayananda, Vidyasagar, Vuligonda, Eckrich, Ralf, Kumar, Kaipenchery A.

“…Pentacyclo[6.5.0.0 4,12.0 5,10.0 9,13]trideca-2,6-diene ( 16) has been synthesized in five steps from 1-hydroxyhexacyclo[6.5.0.0 2,6.0 3,11.0 5,10.0…”
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Synthesis, characterization and crystal density modeling of polycarbocyclic oxiranes by Marchand, Alan P., Vidyanand, D., Liu, Zenghui, Kumar, Kaipenchery A., Zaragoza, Florencio, Kathleen Talafuse, L., Bott, Simon G., Watson, William H., Kashyap, Ram P., Ammon, Herman L., Du, Zuyue

“…Polycyclic bis-epoxides 5, 6, and 7 have been synthesized, and their structures established unequivocally via application of single crystal X-ray…”
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Synthesis and structure of a bis(ethynyl)-substituted oxahexacyclic cage ether by BOTT, S. G, MARCHAND, A. P, KUMAR, K. A

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Structure of a deaza dimer of 4-methyl-3H-1,2,4-triazole-3,5(4H)-dione by BOTT, S. G, MARCHAND, A. P, KUMAR, K. A, DONGXIA XING

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Thermodynamic vs. kinetic control in the Diels-Alder cycloaddition of cyclopentadiene to 2,3-dicyano-p-benzoquinone by BOTT, S. G, MARCHAND, A. P, KUMAR, K. A

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Structure of 1-(2'-tosyloxyethoxy)-8-tosyloxy-9,10-anthraquinone by BOTT, S. G, OBREY, S. J, MARCHAND, A. P, KUMAR, K. A

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