Search Results - "Kuijpers, Petrus F"
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Nitrene Radical Intermediates in Catalytic Synthesis
Published in Chemistry : a European journal (09-10-2017)“…Nitrene radical complexes are reactive intermediates with discrete spin density at the nitrogen‐atom of the nitrene moiety. These species have become important…”
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Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions
Published in Chemistry : a European journal (22-04-2014)“…A cobalt–porphyrin catalyst encapsulated in a cubic M8L6 cage allows cyclopropanation reactions in aqueous media. The caged‐catalyst shows enhanced activities…”
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Catalytic Synthesis of N‑Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand
Published in Journal of the American Chemical Society (12-04-2017)“…Coordination of FeCl3 to the redox-active pyridine–aminophenol ligand NNO H2 in the presence of base and under aerobic conditions generates FeCl2(NNO ISQ )…”
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Catalytic 1,2-dihydronaphthalene and E -aryl-diene synthesis via Co III -Carbene radical and o -quinodimethane intermediates
Published in Chemical science (Cambridge) (01-12-2017)“…Catalytic synthesis of substituted 1,2-dihydronaphthalenes metalloradical activation of -styryl -tosyl hydrazones (( )-2-(prop-1-en-1-yl)benzene- -tosyl…”
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Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles
Published in Chemistry : a European journal (12-06-2017)“…Cobalt‐porphyrin‐catalysed intramolecular ring‐closing C−H bond amination enables direct synthesis of various N‐heterocycles from aliphatic azides…”
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A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media
Published in ACS catalysis (06-05-2016)“…Encapsulation of a manganese porphyrin in a self-assembled molecular cage allows catalytic epoxidation of various substrates in 1:1 water/acetonitrile…”
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Encapsulation of Metalloporphyrins in a Self-Assembled Cubic M8L6 Cage: A New Molecular Flask for Cobalt-Porphyrin-Catalysed Radical-Type Reactions
Published in Chemistry : a European journal (29-07-2013)“…The synthesis of a new, cubic M8L6 cage is described. This new assembly was characterised by using NMR spectroscopy, DOSY, TGA, MS, and molecular modelling…”
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Frontispiece: Nitrene Radical Intermediates in Catalytic Synthesis
Published in Chemistry : a European journal (09-10-2017)“…Nitrene radical complexes are reactive intermediates with intriguing electronic structures, and are best described as “nitrogen‐centered radicals”. They are…”
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Inside Back Cover: Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles (Chem. Eur. J. 33/2017)
Published in Chemistry : a European journal (12-06-2017)“…A snake bites its own tail in the cobalt‐catalysed activation of aliphatic azides, enabling the direct synthesis of several N‐heterocycles from aliphatic…”
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Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII–Carbene radical and o-quinodimethane intermediates
Published in Chemical science (Cambridge) (01-01-2017)“…Catalytic synthesis of substituted 1,2-dihydronaphthalenes via metalloradical activation of o-styryl N-tosyl hydrazones ((E)-2-(prop-1-en-1-yl)benzene-N-tosyl…”
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Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII-Carbene radical and o-quinodimethane intermediatesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03909c
Published 20-11-2017“…Catalytic synthesis of substituted 1,2-dihydronaphthalenes via metalloradical activation of o -styryl N -tosyl hydrazones (( E )-2-(prop-1-en-1-yl)benzene- N…”
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Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII–Carbene radical and o-quinodimethane intermediates† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03909c
Published in Chemical science (Cambridge) (12-10-2017)“…Catalytic synthesis of substituted 1,2-dihydronaphthalenes via metalloradical activation of o -styryl N -tosyl hydrazones is presented. Substrates with an…”
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Encapsulation of Metalloporphyrins in a Self‐Assembled Cubic M 8 L 6 Cage: A New Molecular Flask for Cobalt–Porphyrin‐Catalysed Radical‐Type Reactions
Published in Chemistry : a European journal (29-07-2013)“…Abstract The synthesis of a new, cubic M 8 L 6 cage is described. This new assembly was characterised by using NMR spectroscopy, DOSY, TGA, MS, and molecular…”
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Encapsulation of Metalloporphyrins in a Self-Assembled Cubic M sub(8)L sub(6) Cage: A New Molecular Flask for Cobalt-Porphyrin-Catalysed Radical-Type Reactions
Published in Chemistry : a European journal (01-07-2013)“…The synthesis of a new, cubic M sub(8)L sub(6) cage is described. This new assembly was characterised by using NMR spectroscopy, DOSY, TGA, MS, and molecular…”
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