Search Results - "Kubas, Gregory J"
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Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules
Published in Proceedings of the National Academy of Sciences - PNAS (24-04-2007)“…The binding of a dihydrogen molecule (H₂) to a transition metal center in an organometallic complex was a major discovery because it changed the way chemists…”
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Activation of dihydrogen and coordination of molecular H2 on transition metals
Published in Journal of organometallic chemistry (01-02-2014)“…Fifty years ago, when this journal was founded, organometallic chemists could not have imagined that common small molecules such as dinitrogen and especially…”
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Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding
Published in Journal of organometallic chemistry (15-10-2001)“…There is a marvelous analogy between the metal–olefin π bonding model first brought to light by Dewar 50 years ago and that of σ-bond coordination discovered…”
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Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases
Published in Organometallics (08-11-2010)“…Relatively recent developments in metalloenzyme and organometallic chemistry have targeted a growing link between these outwardly incongruous fields, giving…”
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Breaking the H₂ Marriage and Reuniting the Couple
Published in Science (American Association for the Advancement of Science) (17-11-2006)“…A nonmetal compound enables the reversible splitting of dihydrogen. Related compounds may find use in chemical transformations and in hydrogen activation or…”
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Catalytic processes involving dihydrogen complexes and other sigma-bond complexes
Published in Catalysis letters (01-10-2005)“…The discovery of dihydrogen complexes, LnM(H2), pointed to direct transfer of hydrogen from coordinated H2 ligands to substrates as an operable pathway in…”
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The Art and Beauty of Inorganic Synthesis on the Path to Discovery: Transition Metal Coordination and Activation of Sulfur Dioxide and Dihydrogen
Published in Comments on modern chemistry. Part A, Comments on inorganic chemistry (03-05-2012)“…Transition metal compounds often possess spectacular gem-like colors and crystallinity that have attracted quite a few individuals to careers in chemistry…”
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Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
Published in Chemical reviews (01-04-2001)“…The goal of the "Opportunities for Catalysis Research in Carbon Management" workshop was to review within the context of greenhouse gas/carbon issues the…”
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Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage
Published in Chemical reviews (01-10-2007)Get full text
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Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage
Published in Chemical reviews (01-10-2007)“…The principles of dyhydrogen binding and reactivity on transition metals are explored. The need for further research in the capability of dihydrogen molecules…”
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Iron(II) and Ruthenium(II) Complexes Containing Bidentate, Tied-Back Diphosphonite Ligands. X-ray Structure of cis-FeMe2[(−OCH2CEt2CH2O−)PCH2CH2P(−OCH2CEt2CH2O−)]2
Published in Organometallics (28-05-2001)“…trans-RuCl2(PP)2 (2) and cis-FeCl2(PP)2 (4) have been synthesized by the reaction of the diphosphonite 1,2-bis((2,2-diethyl-1,3-propanedioxy)phosphino)ethane…”
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Molecular hydrogen complexes of the transition metals. 4. Preparation and characterization of M(CO)3(PR3)2(.eta.2-H2) (M = molybdenum, tungsten) and evidence for equilibrium dissociation of the H-H bond to give MH2(CO)3(PR3)2
Published in Journal of the American Chemical Society (01-10-1986)Get full text
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C−H Activation and C−C Coupling of Arenes by Cationic Pt(II) Complexes
Published in Journal of the American Chemical Society (23-10-2002)“…The synthesis and characterization of cationic platinum complexes of the type [(R2PC2H4PR2)PtMe(OEt2)]BArF (R = Cy, Et) are reported. These electrophilic…”
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Theoretical Investigation of the Binding of Small Molecules and the Intramolecular Agostic Interaction at Tungsten Centers with Carbonyl and Phosphine Ligands
Published in The journal of physical chemistry. B (21-06-2007)“…The factors controlling both the binding of small molecules to several tungsten complexes and agostic bonding in the W(CO)3(PCy3)2 complex have been examined…”
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Hydrogen activation on organometallic complexes and H 2 production, utilization, and storage for future energy
Published in Journal of organometallic chemistry (01-08-2009)“…This perspective article serves to highlight the contributions to this special volume of Journal of Organometallic Chemistry entitled “Organometallics for…”
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Molecular and Electronic Structure of Platinum Bis(N-arylamino)phosphenium Complexes including [Pt(phosphane)(phosphenium)(N-heterocyclic carbene)]
Published in Angewandte Chemie International Edition (02-04-2004)“…Give and take: A cationic N‐heterocyclic carbene (NHC)–phosphenium adduct is prepared (see picture; orange=P, lilac=N, gray=C, white=H). On reaction with…”
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Chemical Transformations and Facile Disproportionation of Sulfur Dioxide on Transition Metal Complexes
Published in Accounts of chemical research (01-07-1994)Get full text
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Hydrogen activation on organometallic complexes and H2 production, utilization, and storage for future energy
Published in Journal of organometallic chemistry (01-08-2009)Get full text
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Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals
Published in Accounts of chemical research (01-03-1988)Get full text
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