Search Results - "Krylov, I. B."

Effect of TiO2 modification with fluorine on the physicochemical properties and activity in the photocatalytic oxidation of pollutants in air under UV irradiation by Subbotina, I. R., Barsukov, D. V., Terent’ev, A. O., Krylov, I. B.

“…The influence of the modification of the TiO 2 surface with F − ions on the physicochemical properties of the catalysts and efficiency in the photooxidation of…”
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Solving problems of clustering and classification of cancer diseases based on DNA methylation data by Polovinkin, A. N., Krylov, I. B., Druzhkov, P. N., Ivanchenko, M. V., Meyerov, I. B., Zaikin, A. A., Zolotykh, N. Yu

“…The article deals with the problem of diagnosis of oncological diseases based on the analysis of DNA methylation data using algorithms of cluster analysis and…”
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Synthesis and antimicrobial activity of geminal bis-hydroperoxides by Tropina, V. I, Krivykh, O. V, Sadchikova, N. P, Terent'ev, A. O, Krylov, I. B

“…A series of six new geminal bis-hydroperoxides were synthesized based on cyclic ketones. Experiments in vitro show that the synthesized compounds exhibit…”
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Iminoxyl radicals vs. tert -butylperoxyl radical in competitive oxidative C-O coupling with β-dicarbonyl compounds. Oxime ether formation prevails over Kharasch peroxidation by Krylov, I B, Paveliev, S A, Shumakova, N S, Syroeshkin, M A, Shelimov, B N, Nikishin, G I, Terent'ev, A O

“…Oxidative coupling of oxime and β-dicarbonyl compounds dominates in a β-dicarbonyl compound/oxime/Cu(ii)/ -BuOOH system; in the absence of oxime, oxidative…”
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Oxidative C–O Coupling: Radical and Ionic Pathways of Reaction in Bu4NI/t-BuOOH System by Lopat’eva, E. R., Krylov, I. B., Kuzmin, I. V., Suchkov, S. V., Terent’ev, A. O.

“…The Bu 4 NI/ t- BuOOH oxidative system is widely used in organic synthesis, but mechanistic principles underlying its reactivity are only partially explored…”
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Addition of N-hydroxyphthalimide and atmospheric oxygen to styrenes using tert-butyl hydroperoxide as a radical initiator by Krylov, I. B., Budnikov, A. S., Lastovko, A. V., Ibatov, Y. A., Nikishin, G. I., Terent′ev, A. O.

“…1-Aryl-1-hydroperoxy-2-imidooxyethanes are selectively formed at room temperature from styrenes, N -hydroxyphthalimide, and atmospheric oxygen with the…”
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NIR photoluminescence of ZSM-5 and mordenite zeolites, containing low-valence bismuth exchange cations by Romanov, A.N., Serykh, A.I., Haula, E.V., Shashkin, D.P., Kogan, V.M., Rozhdestvenskaya, N.N., Krylov, I.B., Korchak, V.N.

“…Low valence bismuth cationic centers were introduced into hydrogen forms of ZSM-5 and mordenite zeolites via impregnation of zeolites in aqueous solution of…”
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Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione by Krylov, I. B., Terent’ev, A. O.

“…Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione has been accomplished. This reaction is the first example of oxidative C-O…”
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Oxidative coupling of N-hydroxyphthalimide with toluene by Terent’ev, A. O., Krylov, I. B., Lipatnikov, A. D.

“…Oxidative C-O-coupling of N -hydroxyphthalimide (NHPI) with toluene was studied. The reaction occurred in different organic solvents with a wide range of…”
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Iminoxyl radicals vs. tert-butylperoxyl radical in competitive oxidative C-O coupling with β-dicarbonyl compounds. Oxime ether formation prevails over Kharasch peroxidationElectronic supplementary information (ESI) available: Detailed experimental procedures and characterization of new compounds. See DOI: 10.1039/c7ra13587d by Krylov, I. B, Paveliev, S. A, Shumakova, N. S, Syroeshkin, M. A, Shelimov, B. N, Nikishin, G. I, Terent'ev, A. O

“…Oxidative coupling of oxime and β-dicarbonyl compounds dominates in a β-dicarbonyl compound/oxime/Cu( ii )/ t -BuOOH system; in the absence of oxime, oxidative…”
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Oxidative CO Cross-Coupling of 1,3-Dicarbonyl Compounds and Their Heteroanalogues with N-Substituted Hydroxamic Acids and N-Hydroxyimides by Terent'ev, Alexander O., Krylov, Igor B., Timofeev, Vladimir P., Starikova, Zoya A., Merkulova, Valentina M., Ilovaisky, Alexey I., Nikishin, Gennady I.

“…The oxidative CO cross‐coupling of 1,3‐dicarbonyl compounds and their heteroanalogues, 2‐substituted malononitriles and cyanoacetic esters, with N‐substituted…”
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Synthesis of 1,2,4,5,7,8-hexaoxonanes by iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals by Terent’ev, A. O., Platonov, M. M., Krylov, I. B., Nikishin, G. I.

“…Iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals give, via replacement of two alkoxy groups, the cyclic peroxides,…”
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A new property of geminal bishydroperoxides: Hydrolysis with the removal of hydroperoxide groups to form a ketone by Terent’ev, A. O., Krivykh, O. B., Krylov, I. B., Ogibin, Yu. N., Nikishin, G. I.

“…A new property of geminal bishydroperoxide was discovered: the ability to hydrolyze in acid medium in the presence of hydrogen peroxide with the formation of…”
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