Search Results - "Krishnan, V.V."
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Ensemble characterization of an intrinsically disordered FG‐Nup peptide and its F>A mutant in DMSO‐d6
Published in Biopolymers (01-11-2017)“…Intrinsically disordered proteins (IDP) lack a well‐defined 3D‐structure under physiological conditions, yet, the inherent disorder represented by an ensemble…”
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Optimal strategy for time-limited sequential search
Published in Computers in biology and medicine (01-07-2007)“…Abstract An optimal strategy is developed for maximizing the expected benefit in time limited sequential search processes with very low candidate encounter…”
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Corrigendum to “Kinetics and thermodynamics of oxidation mediated reaction in l-cysteine and its methyl and ethyl esters in dimethyl sulfoxide-d6 by NMR spectroscopy” [Journal of Molecular Structure volume (2017) 196–200]
Published in Journal of molecular structure (05-01-2024)Get full text
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Age-dependent changes in behavioural plasticity: insights from Bayesian models of development
Published in Animal behaviour (01-04-2017)“…Recent models of sensitive periods and age-dependent changes in plasticity are based on the premise that animals use Bayesian-like processes to update…”
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Oxidative Dehydrogenation of 1-Butene over Manganese Oxide Octahedral Molecular Sieves
Published in Journal of catalysis (10-06-1999)“…Steady state kinetic studies of the oxidative dehydrogenation of 1-butene to 1,3-butadiene have been carried out on manganese oxide octahedral molecular sieve…”
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Radiation damping in modern NMR experiments: progress and challenges
Published in Progress in nuclear magnetic resonance spectroscopy (01-01-2013)Get full text
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Role of solvent dielectric constant on the enthalpy-entropy compensation in the hindered amide bond rotation
Published in Chemical physics letters (01-04-2022)“…[Display omitted] •Thermodynamics of partial-double bond rotation.•Enthalpy-entropy compensation in multiple solvents.•Experimental validation using dynamic…”
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Targeted 19F-tags to detect amino acids in complex mixtures using NMR spectroscopy
Published in Journal of fluorine chemistry (01-02-2023)“…•Fluorine-19 tags to Amino acids.•Reaction kinetics of modification.•Mixture analysis and metabolomics. Nuclear magnetic resonance spectroscopy of fluorine-19…”
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Targeted F19-tags to detect amino acids in complex mixtures using NMR spectroscopy
Published in Journal of fluorine chemistry (31-12-2022)“…Nuclear magnetic resonance spectroscopy of fluorine-19 nucleus ( F 19 -NMR) emerges as a powerful tool because of the high sensitivity due to its high natural…”
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Enzyme kinetics by real-time quantitative NMR (qNMR) spectroscopy with progress curve analysis
Published in Analytical biochemistry (01-12-2022)“…This review article summarizes how the experimental data obtained using quantitative nuclear magnetic resonance (qNMR) spectroscopy can be combined with…”
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Kinetics and thermodynamics of oxidation mediated reaction in l-cysteine and its methyl and ethyl esters in dimethyl sulfoxide-d6 by NMR spectroscopy
Published in Journal of molecular structure (05-03-2017)“…l-Cysteine (L-Cys), l-Cysteine methyl ester (L-CysME) or l-Cysteine ethyl ester (L-CysEE), when dissolved in dimethyl sulfoxide, undergoes an oxidation…”
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Restricted amide rotation with steric hindrance induced multiple conformations
Published in Chemical physics letters (01-12-2017)“…[Display omitted] •Steric induced alteration of restricted amide rotation.•Adaptation of pair of sub-populations of conformers.•Experimental validation by 2D…”
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Marmoset Fine B Cell and T Cell Epitope Specificities Mapped onto a Homology Model of the Extracellular Domain of Human Myelin Oligodendrocyte Glycoprotein
Published in Neurobiology of disease (01-03-2002)“…Aberrant association of autoantibodies with myelin oligodendrocyte glycoprotein (MOG), an integral membrane protein of the central nervous system (CNS) myelin,…”
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NMR based real-time enzyme kinetics on estimating the inhibitory effect of sucralose in the enzymatic conversion of sucrose
Published in Biophysical chemistry (01-01-2021)“…Sucralose, one of the popular non-caloric artificial sweeteners, has been known to influence the enzymatic conversion of sucrose to glucose and fructose by…”
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Enzymatic conversion of sucrose to glucose and its anomerization by quantitative NMR spectroscopy: Application of a simple consecutive reaction rates approach
Published in Journal of molecular structure (05-02-2018)“…The anomerization of carbohydrates is an essential process that determines the relative stabilization of stereoisomers in an aqueous solution. In a typical…”
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Unexpected change in NOE with increasing temperature: Crosstalk between chemical exchange and cross relaxation in a NiN2S2 complex
Published in Chemical physics letters (01-01-2019)“…[Display omitted] •Unexpected increase in nuclear Overhauser effect (NOE) enhancement between spins with increasing temperature.•Explanation of the observation…”
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On the Differential Roles of Mg2+, Zn2+, and Cu2+ in the Equilibrium of β-N-Methyl-Amino-L-Alanine (BMAA) and its Carbamates
Published in Neurotoxicity research (01-02-2021)“…β-N-methyl-amino-L-alanine (BMAA) in the presence of bicarbonate (HCO 3 − ) undergoes structural modifications generating two carbamate species, α-carbamate…”
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Chemistry and Chemical Equilibrium Dynamics of BMAA and Its Carbamate Adducts
Published in Neurotoxicity research (01-01-2018)“…Beta-N-methylamino-L-alanine (BMAA) has been demonstrated to contribute to the onset of the ALS/Parkinsonism-dementia complex (ALS/PDC) and is implicated in…”
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Characterization of protein secondary structure from NMR chemical shifts
Published in Progress in nuclear magnetic resonance spectroscopy (05-04-2009)Get full text
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