Search Results - "Krishna, Gamidi Rama"
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Interrupted CuAAC‐Thiolation for the Construction of 1,2,3‐Triazole‐Fused Eight‐Membered Heterocycles from O‐/N‐Propargyl derived Benzyl Thiosulfonates with Organic Azides
Published in Advanced synthesis & catalysis (18-01-2022)“…A copper(I)‐catalyzed interrupted click‐sulfenylation of O‐/N‐propargyl benzyl thiosulfonates with organic azides has been disclosed. The unified…”
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2
K3PO4‐Promoted Cycloannulation of (E)‐β‐Iodovinyl Sulfones with ortho‐Hydroxy‐Chalcones/Cinnamates for the Synthesis of 2,3,4‐Trisubstituted 4H‐Benzopyran Derivatives
Published in Advanced synthesis & catalysis (08-12-2022)“…K3PO4‐mediated cycloannulation of (E)‐β‐iodovinyl sulfones with ortho‐hydroxy chalcones/ortho‐hydroxy cinnamates has been realized to access…”
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3
Total Synthesis of 12,13‐Dibenzyl‐banistenoside B and Analogs
Published in European journal of organic chemistry (19-05-2022)“…Banistenosides A and B possessing a unique “azepino(1,2‐a)tetrahydro‐β‐carboline” carbon framework were isolated from the stem of Banisteriopsis caapi and…”
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Mechanically Flexible Organic Crystals Achieved by Introducing Weak Interactions in Structure: Supramolecular Shape Synthons
Published in Journal of the American Chemical Society (19-10-2016)“…Controlling mechanical properties of ordered organic materials remains a formidable challenge, despite their great potential for high performance mechanical…”
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5
Radical Cascade Cyclization of Unactivated Alkene-Tethered Indoles with Aryldiazonium Salt and Sodium Metabisulfite to Access Azo- and Sulfonylated-2,3-Dihyro‑1H‑pyrrolo[1,2‑a]indoles
Published in Journal of organic chemistry (07-07-2023)“…A method for the construction of heterocyclic scaffold 2,3-dihyro-1H-pyrrolo[1,2-a]indoles via arylsulfonyl radical-triggered cascade cyclization of…”
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6
Metal-Free One-Pot Domino Synthesis of Oxazolidinethione Derivatives of Quaternary Amino Acids from α‑Amino Esters and Aldehydes Using CS2
Published in Journal of organic chemistry (17-05-2024)“…We present a streamlined, metal-free, one-pot domino approach to efficiently synthesize oxazolidinethione derivatives containing substituted quaternary amino…”
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Stereoselective Total Synthesis of (±)-Pleurospiroketals A and B
Published in Journal of organic chemistry (01-10-2021)“…A full account of our efforts toward the stereoselective total synthesis of sesquiterpenoid-derived natural products (±)-pleurospiroketals A and B is…”
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A Photoinduced Multicomponent Regioselective Synthesis of 1,4,5‐Trisubstituted‐1,2,3‐Triazoles: Transition Metal‐, Azide‐ and Oxidant‐Free Protocol
Published in Advanced synthesis & catalysis (20-07-2021)“…A transition metal‐ and azide‐free approach is explored to synthesize 1,4,5‐trisubstituted‐1,2,3‐triazoles under sunlight. The reaction proceeds via C−N and…”
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9
A New 1:1 Drug-Drug Cocrystal of Theophylline and Aspirin: Discovery, Characterization, and Construction of Ternary Phase Diagrams
Published in Crystal growth & design (05-12-2018)“…A new 1:1 drug-drug cocrystal of theophylline (THP) and aspirin (ASP) was successfully prepared by liquid assisted grinding, evaporative crystallization, and…”
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10
Remarkably Distinct Mechanical Flexibility in Three Structurally Similar Semiconducting Organic Crystals Studied by Nanoindentation and Molecular Dynamics
Published in Chemistry of materials (26-02-2019)“…Distinct macroscopic mechanical responses of the three crystals of naphthalene diimide derivatives, 1Me, 1Et, and 1nPr, studied here are very intriguing…”
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11
Regioselective Synthesis of Benzannulated [5,6]-Oxaspirolactones via Cu(II)-Catalyzed Cycloisomerization of 2‑(5-Hydroxyalkynyl)benzoates
Published in Journal of organic chemistry (15-12-2023)“…Spiroketals and oxaspirolactones are widely found in biologically active natural products, serving as important structural motifs. In this study, we present a…”
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12
Pd‐Catalyzed Annulation of β‐Iodovinyl Sulfones with 2‐Halophenols: A General Route for the Synthesis of 3‐Sulfonyl Benzofuran Derivatives
Published in Advanced synthesis & catalysis (17-03-2020)“…The palladium‐catalyzed annulation between β‐iodovinyl sulfones and 2‐halophenols or 1‐bromo‐2‐naphthol or 2‐bromo‐3‐pyridinol is presented. The annulation…”
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13
Ready Access to Benzannulated [5,5]-Oxaspirolactones Using Au(III)-Catalyzed Cascade Cyclizations
Published in Journal of organic chemistry (04-03-2022)“…This work showcases an unprecedented Au(III)-catalyzed cascade cyclization of 2-(4-hydroxyalkynyl)benzoates to access benzannulated [5,5]-oxaspirolactones…”
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14
Total synthesis and absolute configuration determination of Ktedonoketone, a benzenoid metabolite from Thermophilic bacterium
Published in Tetrahedron letters (19-11-2020)“…[Display omitted] The successful total synthesis of both enantiomers of ktedonoketone allowed us to decipher an unambiguous assignment of absolute…”
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15
Visible‐Light‐Induced Radical Sulfonylative‐Cyclization Cascade of 1,6‐Enynol Derivatives with Sulfinic Acids: A Sustainable Approach for the Synthesis of 2,3‐Disubstituted Benzoheteroles
Published in ChemSusChem (07-10-2024)“…Benzoheteroles are promising structural scaffolds in the realm of medicinal chemistry, but sustainable synthesis of 2,3‐difunctionalized benzoheterole…”
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16
The Relationship of Solid-State Plasticity to Mechanochromic Luminescence in Difluoroboron Avobenzone Polymorphs
Published in Advanced functional materials (20-03-2013)“…In solid‐state mechanochromic luminescence (ML) materials, it remains a challenge to establish the origin of fluorescence color changes upon mechanical action…”
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Design and synthesis of novel quinazolinyl-bisspirooxindoles as potent anti-tubercular agents: an ultrasound-promoted methodology
Published in Molecular diversity (01-06-2023)“…The essential need for the potent anti-tubercular (anti-TB) agents with high selectivity and safety profile prompted us to synthesize a new series of…”
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18
Tuning of α‑Silyl Carbocation Reactivity into Enone Transposition: Application to the Synthesis of Peribysin D, E‑Volkendousin, and E‑Guggulsterone
Published in Organic letters (03-09-2021)“…A reliable method for enone transposition has been developed with the help of silyl group masking. Enantio-switching, substituent shuffling, and Z-selectivity…”
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Origin of Optoelectronic Contradictions in 3,4-Cycloalkyl[c]-chalcogenophenes: A Computational Study
Published in Polymers (01-11-2023)“…The planar morphology of the backbone significantly contributes to the subtle optoelectronic features of π-conjugated polymers. On the other hand, the…”
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20
Organocatalyzed [4 + 2] cycloaddition of α,β-unsaturated ketones and isatylidene malononitrile: accessing spiro[3-arylcyclohexanone]oxindole derivatives
Published in RSC advances (17-01-2024)“…Herein, we developed a series of compounds featuring spiro[3-arylcyclohexanone]oxindoles through Barbas [4 + 2] cycloaddition reactions between isatylidene…”
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