Search Results - "Krajewski, Sebastian M"
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1
Redox-Switchable Allosteric Effects in Molecular Clusters
Published in JACS Au (24-01-2022)“…We demonstrate that allosteric effects and redox state changes can be harnessed to create a switch that selectively and reversibly regulates the coordination…”
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2
Caught in the Act of Substitution: Interadsorbate Effects on an Atomically Precise Fe/Co/Se Nanocluster
Published in ACS central science (26-06-2024)“…Directing groups guide substitution patterns in organic synthetic schemes, but little is known about pathways to control reactivity patterns, such as…”
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3
Synthesis and Single Crystal X‑ray Diffraction Structure of an Indium Arsenide Nanocluster
Published in ACS central science (27-03-2024)“…The discovery of magic-sized clusters as intermediates in the synthesis of colloidal quantum dots has allowed for insight into formation pathways and provided…”
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4
Metal–Support Interactions in Molecular Single-Site Cluster Catalysts
Published in Journal of the American Chemical Society (12-10-2022)“…This study provides atomistic insights into the interface between a single-site catalyst and a transition metal chalcogenide support and reveals that peak…”
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5
Exploring Charge Redistribution at the Cu/Co6Se8 Interface
Published in Inorganic chemistry (28-10-2024)“…This study investigates the electronic interactions and charge redistribution at the dopant–support interface using a Cu/Co6Se8 cluster construct…”
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6
Exploring Charge Redistribution at the Cu/Co 6 Se 8 Interface
Published in Inorganic chemistry (28-10-2024)“…This study investigates the electronic interactions and charge redistribution at the dopant-support interface using a Cu/Co Se cluster construct. Specifically,…”
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7
Ligand Steric Profile Tunes the Reactivity of Indium Phosphide Clusters
Published in Journal of the American Chemical Society (07-02-2024)“…Indium phosphide quantum dots have become an industrially relevant material for solid-state lighting and wide color gamut displays. The synthesis of indium…”
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8
Copper(II) as a Platform for Probing the Steric Demand of Bulky β‑Diketonates
Published in Inorganic chemistry (06-01-2020)“…The synthesis and characterization of a series of copper bis(β-diketonate) complexes, functionalized with sterically hindered o-biphenyl and m-terphenyl…”
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Synthesis of Sterically Hindered β‑Diketones via Condensation of Acid Chlorides with Enolates
Published in Journal of organic chemistry (07-06-2019)“…Bulky β-diketones have rarely exceeded dipivaloylmethane (DPM) in steric demand, largely due to synthetic limitations of the Claisen condensation. This work…”
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10
Group 4 Organometallics Supported by Sterically Hindered β‐Diketonates
Published in European journal of inorganic chemistry (29-05-2020)“…The synthesis, characterization, and reactivity of group 4 organometallics supported by β‐diketonates is reported. Sterically hindered β‐diketonates, such as…”
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11
Mono-β-diketonate Metal Complexes of the First Transition Series
Published in Inorganic chemistry (20-11-2024)“…Mono-β-diketonate compounds have been fleetingly observed in base metal catalyzed reactions, which are of current interest as alternatives to precious metal…”
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12
Synthesis, reactivity, and crystallography of a sterically hindered acyl triflate
Published in Tetrahedron (13-08-2021)“…2,6-Dimesitylbenzoyl triflate (1) has been prepared from the corresponding acid chloride, and its structure and reactivity with some small molecules is…”
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