Search Results - "Kornfield, Julia A"
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Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers
Published in Macromolecules (09-06-2009)“…Various macromonomers (MMs) were efficiently synthesized through the copper-catalyzed “click” coupling of a norbornene moiety to the chain end of…”
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Linear Rheological Response of a Series of Densely Branched Brush Polymers
Published in Macromolecules (13-09-2011)“…We have examined the linear rheological responses of a series of well-defined, dense, regularly branched brush polymers. These narrow molecular weight…”
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3
Visible-Light-Initiated Thiol–Acrylate Photopolymerization of Heparin-Based Hydrogels
Published in Biomacromolecules (09-02-2015)“…An in situ heparin-based forming hydrogel that cures under visible-light is formulated using eosin Y as a photoinitiator with triethanolamine as an electron…”
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4
Molecular Basis of the Shish-Kebab Morphology in Polymer Crystallization
Published in Science (American Association for the Advancement of Science) (18-05-2007)“…In the rich and long-standing literature on the flow-induced formation of oriented precursors to polymer crystallization, it is often asserted that the…”
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5
Mechanism for Shish Formation under Shear Flow: An Interpretation from an in Situ Morphological Study
Published in Macromolecules (26-02-2013)“…Isotactic polypropylene has been systematically studied with in situ optical microscopy to obtain a real space view of the morphology evolution of shear…”
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6
When Ends Meet: Circular DNA Stretches Differently in Elongational Flows
Published in Macromolecules (25-08-2015)“…Chain topology has a profound impact on the flow behavior of single macromolecules. For circular polymers, the absence of free ends results in a unique chain…”
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Megasupramolecules for safer, cleaner fuel by end association of long telechelic polymers
Published in Science (American Association for the Advancement of Science) (02-10-2015)“…We used statistical mechanics to design polymers that defy conventional wisdom by self-assembling into "megasupramolecules" (≥5000 kg/mol) at low concentration…”
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8
Tuning the erosion rate of artificial protein hydrogels through control of network topology
Published in Nature materials (01-02-2006)“…Erosion behaviour governs the use of physical hydrogels in biomedical applications ranging from controlled release to cell encapsulation. Genetically…”
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Rheological properties of the vitreous and the role of hyaluronic acid
Published in Journal of biomechanics (01-01-2008)“…Abstract Coordinated rheological and biochemical measurements provide the linear and nonlinear mechanical properties of the vitreous and demonstrate the…”
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10
Cyclic Ruthenium-Alkylidene Catalysts for Ring-Expansion Metathesis Polymerization
Published in Journal of the American Chemical Society (24-09-2008)“…A series of cyclic Ru-alkylidene catalysts have been prepared and evaluated for their efficiency in ring-expansion metathesis polymerization (REMP). The…”
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11
Living Material with Temperature‐Dependent Light Absorption
Published in Advanced science (01-10-2023)“…Abstract Engineered living materials (ELMs) exhibit desirable characteristics of the living component, including growth and repair, and responsiveness to…”
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Ring-Expansion Metathesis Polymerization: Catalyst-Dependent Polymerization Profiles
Published in Journal of the American Chemical Society (25-02-2009)“…Ring-expansion metathesis polymerization (REMP) mediated by recently developed cyclic Ru catalysts has been studied in detail with a focus on the polymer…”
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13
Interaction of Poly L-Lactide and Tungsten Disulfide Nanotubes Studied by In Situ X-ray Scattering during Expansion of PLLA/WS2NT Nanocomposite Tubes
Published in Polymers (27-05-2021)“…In situ synchrotron X-ray scattering was used to reveal the transient microstructure of poly(L-lactide) (PLLA)/tungsten disulfide inorganic nanotubes (WS2NTs)…”
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14
Tube Expansion Deformation Enables In Situ Synchrotron X-ray Scattering Measurements during Extensional Flow-Induced Crystallization of Poly l-Lactide Near the Glass Transition
Published in Polymers (08-03-2018)“…Coronary Heart Disease (CHD) is one of the leading causes of death worldwide, claiming over seven million lives each year. Permanent metal stents, the current…”
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15
Shear-Mediated Crystallization of Isotactic Polypropylene: The Role of Long Chain−Long Chain Overlap
Published in Macromolecules (26-03-2002)“…The role of long chains in shear-mediated crystallization was studied by in situ rheo-optical measurements and ex situ microscopic observations. To elucidate…”
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16
linear rheological responses of wedge‐type polymers
Published in Journal of polymer science. Part B, Polymer physics (01-07-2015)“…The linear rheological responses of a series of specially designed wedge‐type polymers synthesized by the polymerization of large molecular weight monomers…”
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Shear-Enhanced Crystallization in Isotactic Polypropylene. 1. Correspondence between in Situ Rheo-Optics and ex Situ Structure Determination
Published in Macromolecules (02-11-1999)“…The effects of “short term shearing” on the subsequent crystallization of a polydisperse Ziegler−Natta isotactic polypropylene are observed using in situ…”
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Shear-Enhanced Crystallization in Isotactic Polypropylene. In-Situ Synchrotron SAXS and WAXD
Published in Macromolecules (30-11-2004)“…In-situ synchtrotron small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD) are used to follow the isothermal crystallization (lamellar…”
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Recent Advances in Understanding Flow Effects on Polymer Crystallization
Published in Industrial & engineering chemistry research (11-12-2002)“…Molecular aspects of polymer melt rheology play an extremely strong role in governing the processing−structure−property relations of semicrystalline polymers,…”
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Effect of tungsten disulfide nanotubes on crystallization of polylactide under uniaxial deformation and annealing
Published in Functional composite materials (26-01-2021)“…Tungsten disulfide (WS 2 ) nanotubes (NTs) are examined here as a filler for polylactide (PLA) for their ability to accelerate PLA crystallization and for…”
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