Search Results - "Komatsu, Koichi"
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Professor Tetsuo Nozoe and My Tropylium Ion Chemistry
Published in Chemical record (01-02-2015)“…Needless to say, the discovery of hinokitiol with its “unconventional” aromaticity by Professor Tetsuo Nozoe is one of the most important achievements in…”
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2
Perineal Approach, the Closest Approach to the Pelvic Floor, in Perineal Hernia Repair After Abdominoperineal Resection
Published in Diseases of the colon & rectum (01-09-2022)Get full text
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3
Synthesis and Properties of Endohedral C60 Encapsulating Molecular Hydrogen
Published in Journal of the American Chemical Society (21-06-2006)“…We report the details of our study to synthesize a new endohedral fullerene, H2@C60, in more than 100 mg quantities by closure of the 13-membered ring orifice…”
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Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2
Published in Journal of the American Chemical Society (26-11-2008)“…New endohedral fullerene C70 encapsulating one and two H2 molecule(s) has been synthesized by organic reactions, the so-called “molecular surgery” method, and…”
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5
Encapsulation and Dynamic Behavior of Two H2 Molecules in an Open-Cage C70
Published in Journal of the American Chemical Society (28-05-2008)“…An open-cage C70 derivative having a 13-membered ring opening (2) was synthesized by a three-step reaction; thermal reaction of C70 with a pyridazine…”
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6
Electrochemistry of the self-assembled monolayers of dyads consisting of tripod-shaped trithiol and bithiophene on gold
Published in Molecules (Basel, Switzerland) (24-09-2014)“…Self-assembled monolayers (SAMs) of tripod-shaped trithiols, consisting of an adamantane core with three CH2SH legs and a bithiophene group, were prepared on a…”
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7
Near- and Mid-IR Gas-Phase Absorption Spectra of H2@C60 +‑He
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-10-2018)“…Near- and mid-IR absorption spectra of endohedral H2@C60 + have been measured using He-tagging. The samples have been prepared using a “molecular surgery”…”
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Synthesis, Structure, and Properties of Novel Open-Cage Fullerenes Having Heteroatom(s) on the Rim of the Orifice
Published in Chemistry : a European journal (04-04-2003)“…A thermal liquid‐phase reaction of fullerene C60 with 3‐(2‐pyridyl)‐5,6‐diphenyl‐1,2,4‐triazine afforded aza‐open‐cage fullerene derivative 5 having an…”
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The Spin Chemistry and Magnetic Resonance of H2@C60. From the Pauli Principle to Trapping a Long Lived Nuclear Excited Spin State inside a Buckyball
Published in Accounts of chemical research (16-02-2010)“…One of the early triumphs of quantum mechanics was Heisenberg’s prediction, based on the Pauli principle and wave function symmetry arguments, that the…”
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10
Epitaxial Supramolecular Assembly of Fullerenes Formed by Using a Coronene Template on a Au(111) Surface in Solution
Published in Journal of the American Chemical Society (11-04-2007)“…Characteristic properties of the coronene layer formed on Au(111) for the epitaxial growth of various fullerenes are described. The electrochemical behavior of…”
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11
Magnetic circular dichroism of an unaromatic planar [8]annulene
Published in Journal of physical organic chemistry (01-08-2018)“…An overview of magnetic circular dichroism (MCD) spectroscopy of π‐electron systems derived from a 4N‐electron perimeter is provided, with emphasis on the…”
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12
Positive Heterotropic Cooperativity for Selective Guest Binding via Electronic Communications through a Fused Zinc Porphyrin Array
Published in Journal of the American Chemical Society (28-09-2005)“…Upon binding with C60 and diamines, such as 4,4‘-bipyridine (bpy) and N,N,N‘,N‘-tetramethylhexane-1,6-diamine (TMHDA), cyclic host 1 possessing two…”
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13
Recognition of hydrogen isotopomers by an open-cage fullerene
Published in Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences (13-09-2013)“…We present our study on the recognition of hydrogen isotopes by an open-cage fullerene through determination of binding affinity of isotopes H2/HD/D2 with the…”
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14
Demonstration of a Chemical Transformation Inside a Fullerene. The Reversible Conversion of the Allotropes of H2@C60
Published in Journal of the American Chemical Society (13-08-2008)“…The interconversion of the two allotropes of the hydrogen molecule (para-H2 and ortho-H2) incarcerated inside the fullerene C60 is reported (oH2@C60 and…”
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A New Route to an Endohedral Fullerene by Way of σ-Framework Transformations
Published in Chemistry letters (05-07-2005)“…The molecular surgical approach has been shown to be applicable to preparation of an endohedral fullerene. Thus, an orifice large enough to insert an atom or…”
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Mechanochemical Synthesis of a Novel C60 Dimer Connected by a Silicon Bridge and a Single Bond
Published in Organic letters (21-03-2002)“…A novel C60 dimer connected by a silicon bridge and a single bond was synthesized by the mechanochemical solid-state reaction employing a high-speed vibration…”
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Distance-Dependent para-H2→ortho-H2 Conversion in H2@C60 Derivatives Covalently Linked to a Nitroxide Radical
Published in The journal of physical chemistry letters (07-04-2011)“…The ortho-H2→para-H2 conversion in a series of H2@C60 derivatives covalently linked to a nitroxide radical has been investigated. The resulting conversion…”
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Synthesis, Isomer Count, and Nuclear Spin Relaxation of H2O@Open-C60 Nitroxide Derivatives
Published in Organic letters (03-08-2012)“…H2O@C60 derivatives covalently linked to a nitroxide radical were synthesized. The 1H NMR of the guest H2O revealed the formation of many isomers with broad…”
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Mechanochemical Synthesis and Characterization of the Fullerene Dimer C120
Published in Journal of organic chemistry (11-12-1998)“…The bulk synthesis of the [2 + 2] dimer of fullerene C60 was achieved by the solid-state mechanochemical reaction of C60 with KCN by the use of a high-speed…”
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20
A Magnetic Switch for Spin-Catalyzed Interconversion of Nuclear Spin Isomers
Published in Journal of the American Chemical Society (31-03-2010)“…The interconversion of ortho-hydrogen (oH2) and para-hydrogen (pH2), the two nuclear spin isomers of dihydrogen, requires a paramagnetic spin catalyst such as…”
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